• Ocean and Polar Research
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• 제31권2호
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• pp.189-198
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• 2009

Passive air samplers with polyurethane foam (PUF) disks were employed to determine seasonal gas phase variation of polycyclic aromatic hydrocarbons (PAHs) in ambient air on Anmyeon island from March 2007 to January 2008. Sum of 13 PAHs ranged between $3.5\;ng/m^3$ and $27.6\;ng/m^3$. Total PAHs during the heating season was 6.2 times higher than non-heating season. The dominant PAHs components during sampling periods were low and middle molecular weight PAHs including phenanthrene, fluoranthene, pyrene and chrysene. Gas exchange fluxes of PAHs across the air-water interface of the Yellow Sea were calculated using a modified two-film exchange model. PAHs fluxes ranged from $196\;ng/m^2/d$ net volatilization during summer to $3830\;ng/m^2/d$ net absorption during winter. Passive air sampler provides a convenient and cost-effective tool for measuring averaged gas phase PAHs, which was successfully used for calculation of gas exchange flux of PAHs in the Yellow Sea.

• 대한기계학회논문집
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• 제19권3호
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• pp.858-867
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• 1995

Characteristics of premixed flames in counter-flow system are numerically studied using a detailed chemical reaction mechanism including gas phase radiation. Without radiation effect accounted, low CO and high NO$_{x}$ emission indices are observed, when strain rate decreases, due to increased residence time and higher flame temperature. Higher NO$_{2}$ production has been also observed when two premixed flames are interacting or cold air stream is mixed with burned gas. The rate of NO$_{x}$ production and destruction is dependent upon the diffusional strength of H and OH radicals, the existence of NO and the concentration of HO$_{2}$. For radiating flames, the peak temperature and NO$_{x}$ production rate decreases as the strain rate decreases. At high strain rate, it is found that the effect of radiation on flame is little due to its negligible radiating volume. It is also found that NO$_{x}$ production from the interacting premixed flame is reduced due to reduced temperature resulting from radiation heat loss. It is concluded that the radiation from gas has significant effect of flame structure and on emission characteristics.ristics.

• 대한기계학회논문집B
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• 제27권9호
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• pp.1273-1281
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• 2003

The present study is mainly motivated to investigate the vaporization, auto-ignition, and combustion of liquid fuel spray injected into high pressure environment. The unsteady, multi-dimensional models were used for realistic simulation of spray as well as prediction of accurate ignition delay time. The Separated Flow (SF) model which considers the finite rate of transport between liquid and gas phases was employed to represent the interactions between spray and gas field. Among the SF models, the Discrete Droplet Model (DDM) which simulates the spray using finite number of representative samples of discrete droplets was adopted. The Eulerian-Lagrangian formulation was used to analyze the two-phase interactions. In order to predict an evaporation rate of droplet in high pressure environment, the high pressure vaporization model was applied using thermodynamic equilibrium and phase equilibrium at droplet surface. The high pressure effect as well as high temperature effect was considered in the calculation of liquid and gas properties. In case of vaporization, an interaction between droplets was studied through the simulation of spray. The interaction is shown up differently whether the ambient gas field is at normal pressure or high pressure. Also, the characteristics of spray behavior in high pressure environment were investigated through the comparison with normal ambient pressure case. In both cases, the spray behaviors are simulated through the distributions of temperature and reaction rate in gas field.

• 공업화학
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• 제20권6호
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• pp.646-652
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• 2009

본 연구는 표면에 액체 막이 입혀진 구 입자를 지나는 기체의 흐름이 구 입자에 작용하는 항력을 결정하는 3상계 문제를 다룬다. 기체 흐름의 관성은 무시할 정도로 작으며, 구 입자의 표면에서 액체는 중력에 의해 흐르고 액체 막이 기체 흐름에 영향을 받지 않는 경우를 고려한다. SC (simple cubic), BCC (body centered cubic), FCC (face centered cubic) 각 배열의 구 입자들에 대해 외란 기법(perturbation method)과 멀티폴 전개(multipole expansion) 방법을 이용하여 입자들의 수력학적 상호 작용을 계산하고 궁극적으로 액체 막과 액체의 흐름이 기체 흐름에 미치는 영향을 수치적으로 결정한다. 근사적인 방법으로 액체 막의 효과에 구하고 이를 엄밀한 계산 값들과 비교한 결과, 대체로 일치함을 보인다.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2010년도 제39회 하계학술대회 초록집
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• pp.88-88
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• 2010

We synthesized molybdenum thin films deposited by RF magnetron sputtering and physicochemical analysis was performed. The physical and chemical properties of these films were examined with X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). The obtained film at the oxygen ratio of 0% showed crystallinity of cubic Mo(110) phase. After the oxygen ratio increased more than 5% in the sputter gas, the molybdenum films were formed as an amorphous phase. The thickness of the Mo thin film was drastically decreased from 1000 nm to ca 70 nm after introduction of oxygen in the sputter gas confirmed by spectroscopic ellipsometer (SE) and scanning electron spectroscopy (SEM). The calculated band gap of the film deduced from SE data increased from 3.17 to 3.63 eV by addition of oxygen in the sputter gas. The roughness of the Mo film was examined with atomic force microscopy (AFM) and it was dramatically decreased by introducing of oxygen during sputtering. XPS results revealed that the ratio of metallic Mo species in the film decreased by the contents of Mo(VI) species increased at the ratio of oxygen increased in the sputter gas and fully oxidized at low content of oxygen in the sputter gas.

• Tribology and Lubricants
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• 제37권5호
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• pp.164-171
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• 2021

Ultrasonic sensors show various reception characteristics based on the density of the measurement medium; hence, they are used in various fields to benefit from the characteristics of ultrasonic signals. In this study, the reception characteristics according to the thickness of the first matching layer are compared and analyzed for application to gas tank microleak detection. Accordingly, three types of sensors are manufactured with varying thicknesses of the first matching layer, namely 4.8 mm, 5.1 mm, and 5.5 mm; further, a direct measurement method is used wherein the sensor is attached to the inside of the chamber. Experiments are conducted to observe the phase change due to microleakage, which is the most linear in the sensor with the 4.8 mm thick first matching layer. This is assumed to be the result of stable signal transmission and reception with little phase deviations over time because the first matching layer is closest to the ultrasonic wavelength. The other sensors show nonlinear results with increasing thickness of the first matching layer. Through this study, it is found that appropriately selecting the thickness of the first matching layer of the ultrasonic sensor can greatly influence sensor reliability.

• 한국가스학회지
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• 제21권1호
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• pp.72-79
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• 2017

극한지 천연가스 배관의 운전온도 범위는 가스 공급을 최적화하고 운전동안 극한지 환경에 대한 충격을 최소화하기 위해 기본적으로 제어되어야 한다. 배관에 흐르는 가스의 온도는 Joule-Thomson 효과와 배관과 토양의 열전달에 의존한다. 따라서 본 연구에서는 매설 천연가스 배관의 열전달과 Joule-Thomson 효과를 상세히 고려하였다. 토양온도는 $0{\sim}-20^{\circ}C$, 총괄열전달계수는 $0{\sim}5.5W/m^2K$로 가정하였다. 토양온도와 총괄열전달계수 변화에 따른 배관 길이방향의 가스온도 변화와 압력손실을 동시에 계산하였다. 또한, 본 연구에서는 HYSYS 프로그램을 사용하여 토양온도와 총괄열전달계수에 따른 상변화와 하이드레이트 생성을 예측하였다.

• 센서학회지
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• 제30권3호
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• pp.175-180
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• 2021

In this paper, methods for improving the sensitivity of gas sensors to NO₂ gas are presented. A gas sensor was fabricated based on an SnO₂ nanowire network using the vapor-phase-growth method. In the gas sensor, the Au electrode was replaced with a fluorinedoped tin oxide (FTO) electrode, to achieve high sensitivity at low temperatures and concentrations. The gas sensor with the FTO electrode was more sensitive to NO₂ gas than the sensor with the Au electrode: notably, both sensors were based on typical SnO₂ nanowire network. When the Au electrode was replaced by the FTO electrode, the sensitivity improved, as the contact resistance decreased and the surface-to-volume ratio increased. The morphological features of the fabricated gas sensor were characterized in detail via field-emission scanning electron microscopy and X-ray diffraction analysis.

• Korean Chemical Engineering Research
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• 제49권5호
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• pp.605-610
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• 2011

내경이 0.105 m이고 높이가 2.5 m인 삼상(기체-액체-고체) 유동층에서 상대적으로 큰 기포와 작은 기포의 체류량 특성을 고찰하였다. 기체유속(0.01~0.07 m/s), 액체유속(0.01~0.07 m/s) 그리고 입자크기($0.5{\sim}3.0{\times}10^{-3}m$)가 상대적으로 큰 기포와 작은 기포의 체류량에 미치는 영향을 검토하였다. 삼상 유동층에서 이들 두 종류 기포들의 체류량은 동력학적 기체 유출 방법(Dynamic gas disengagement method)에 의해 측정된 각각 기포들에 의한 압력강하 정보로부터 정압강하법(static pressure drop method)에 의해 산출되었다. 기체조절기에 의해 조절되는 건조되고 여과된 공기와 물 그리고 밀도가 2,500 $kg/m^3$인 유리구슬을 각각 기체, 액체 및 고체유동입자로 사용하였다. 삼상유동층에서 이들 두 종류의 기포, 즉 상대적으로 큰 기포와 작은 기포들은 유동층 탑에 유입되는 기체와 액체의 흐름을 정지시킨 후 경과시간에 따른 탑 내부의 압력강하를 측정함으로써 효과적으로 조사하고 분리할 수 있었다. 이들 두 종류의 기포들은 경과시간에 따라 증가하는 압력강하의 기울기가 서로 매우 다르게 나타났다. 실험결과 상대적으로 큰 기포들의 체류량은 기체의 유속이 증가함에 따라 증가하였으나 액체의 유속이 증가함에 따라서는 감소하였다. 그러나, 이들 큰 기포의 체류량은 유동입자의 크기가 변화함에 따라 국부적인 최소값을 나타내었다. 상대적으로 작은 기포들의 체류량은 기체유속 또는 고체입자의 크기가 증가함에 따라 증가하였으나 액체의 유속이 증가함에 따라서는 약간 감소하였다. 이들 두 종류 기포들의 체류량들은 각각 본 연구의 실험 범위 내에서 조작변수들의 상관식으로 나타낼 수 있었다.

• Ocean and Polar Research
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• 제26권3호
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• pp.515-521
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• 2004

The processes of formation and dissociation of gas hydrates were investigated by monitoring pressure and temperature variations in a pressure cell in order to understand the kinetic behavior of gas hydrate and the controlling factors fur the phase transition of gas hydrate below freezing. Gas hydrates were made kom guest gases ($CH_4,\;CO_2$, and their mixed-gas) and fine ice powder. We found that formation and dissociation speeds of gas hydrates were not controlled by temperature and pressure conditions alone. The results of this study suggested that pressure levels at the formation of mixed-gas hydrate determine the transient equilibrium pressure itself.