• 한국가스학회지
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• 제27권2호
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• pp.7-15
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• 2023

전기식 액중형 펌프 (electrical submersible pump, ESP)는 인공채유 (artificial lift) 기법 중 적용성과 운영 효율이 높아 전 세계 생산정에서 운영되고 있다. 저류층에서 ESP 운영 시 온도·압력, 가스·오일비, 유량 등의 변수는 ESP 성능에 영향을 미치는 요소로서, 특히 생산유체 내 자유 가스 (free gas)는 ESP의 수명 및 운영 효율을 감소시키는 주요 요인에 해당한다. 이에 본 연구에서는 ESP 성능에 영향을 미치는 변수를 정량적으로 분석하고자 현장 운영조건에서 ESP 성능실험과 손상모사 실험이 가능한 환형 유동 시스템 (flow loop system) 을 개발하였다. 개발 장치는 ESP와 튜빙 (tubing)을 하나의 시스템으로 연동시켜 ESP의 고장 및 원인 진단, 튜빙의 누출 특성을 파악할 수 있는 일체형 시스템에 해당한다. 본 연구에서는 ESP 성능 평가와 관련된 단상 유체 (single phase)와 2상 유체 (two phase) 실험을 통해 ESP를 안정적으로 운영하기 위한 유동 조건을 규명하였다. 도출된 결과값은 ESP 고장 예측 및 진단 프로그램 개발을 위한 기본 자료를 제공하며, ESP 운영을 위한 최적 운영 조건 및 고장 진단을 위한 실시간 모니터링에 활용할 수 있을 것으로 판단된다.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2011년도 춘계학술대회 초록집
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• pp.147.1-147.1
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• 2011

지식경제부 가스 하이드레이트 개발사업의 일환으로 동해 울릉분지 가스 하이드레이트 2차 시추(Ulleung Basin Gas Hydrate Drilling Expedition: UBGH2)가 2010년 7월 8일부터 9월 30일까지 D/V Fugro Synergy를 이용하여 수행되었다. UBGH2 수행을 위해 선정된 13개 site에서 약 1개월 동안 Schlumberger사의 장비를 이용 Logging-While-Drilling/Measurement-While-Drilling(LWD/MWD) 자료를 취득하였다. LWD/MWD 자료는 선상에서 분석되었으며, 이 결과는 coring 및 borehole plan 수립을 위하여 활용되었다. Coring Phase 동안 10개 site의 18개 hole로부터 퇴적물 코어 시료를 채취하고 선상에서 퇴적학, 지구화학, 생지화학, 물리적 특성 등 각종 분석과 측정 작업을 수행하였다. 약 2개월에 걸쳐 수행된 coring phase 동안에 2개 site에서 FAOL(Fugro Alluvial Offshore Limited)사의 장비를 이용 Wireline Logging/Vertical Seismic Profile(WL/VSP) 자료도 취득하였다. LWD/MWD phase와 coring phase 동안 12개 site에서 무인잠수정(remotely operated vehicle: ROV)를 이용하여 퇴적물 시료 채취, 해저면 관찰, 용존메탄 측정 등의 작업을 수행하였으며, 선상에서 취득된 이들 자료를 분석하였다. Coring을 수행한 모든 site에서 가스 하이드레이트 부존을 확인하였으며, 다양한 산상의 가스 하이드레이트 실물을 회수하고 분석하였다.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2000년도 추계학술대회논문집B
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• pp.136-141
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• 2000

A study of counter-current two-phase flow in narrow rectangular channels has been performed. Two-phase flow regimes were experimentally studied in 760 mm long and 100 mm wide test sections with 2.0 and 3.0mm gaps. The resulting data have been compared to previous transition models. For the transition from bubbly to slug flow the superficial velocity of gas increased as the gap width increased. The comparison of experimental data to the transition model developed by Taitel and Barnea showed relatively good agreement for the bubbly-to-slug transition in the case of 2mm gap width. For the criteria of Mishima and Ishii to be applicable to the slug-to-churn transition the distribution parameter should be well defined for narrow channels. Even though the gap width of narrow channels increased the superficial gas velocity did not change for the transition form chum to annular flow regime. For the chum-to-annular transition the model of Taitel and Barnea showed discrepancies with experimental data, especially in the channel with larger gap.

• 한국수소및신에너지학회논문집
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• 제15권2호
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• pp.119-128
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• 2004

DME(Dimethyl Ether) was directly produced from the synthesis gas using the slurry phase reactor. The catalyst for DME production prepared two types (A type; Cu:Zn:Al=57:33:10, B type; Cu:Zn:Al=40:45:15, molar ratio). It was evaluated for the effect of the reaction medium oil using the small size slurry phase reactor. DME production yield and the methanol selectivity decreased in the order: n-hexadecane oil> mineral oil> therminol oil. The long-term test of DME production was carried out using A and B type catalyst, and n-hexadecane oil and mineral oil, respectively. It was confirmed that the use of A type for the catalyst and n-hexadecane for the reaction medium oil was very useful for the viewpoint of the DME production form the synthesis gas.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2014년도 제46회 동계 정기학술대회 초록집
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• pp.248.2-248.2
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• 2014

In this study, the optical properties and structural characteristics of gallium nitride (GaN) thin films prepared by radio frequency (RF) magnetron sputtering were investigated. Auger electron and X-ray photoelectron spectra showed that the deposited films consisted mainly of gallium and nitrogen. The presence of oxygen was also observed. The optical bandgap of the GaN films was measured to be approximately 3.31 eV. The value of the refractive index of the GaN films was found to be 2.36 at a wavelength of 633 nm. X-ray diffraction data revealed that the crystalline phase of the deposited GaN films changed from wurtzite to zinc-blende phase upon decreasing the sputtering gas pressure. Along with the phase change, a strong dependence of the microstructure of the GaN films on the sputtering gas pressure was also observed. The microstructure of the GaN films changed from a voided columnar structure having a rough surface to an extremely condensed structure with a very smooth surface morphology as the sputtering gas pressure was reduced. The relationship between the phase and microstructure changes in the GaN films will be discussed.

• 한국분무공학회지
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• 제20권1호
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• pp.35-42
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• 2015

This study is to investigate the spray behavior of DME-LPG blended fuels in common rail injection system for diesel engines. The visualization experiment was performed to analyze the macroscopic spray behavior of test fuels. In addition, the experiment using BOS(Background Oriented Schlieren) method is performed to compare liquid phase and gas phase. The test fuels are injected in high pressure chamber. The ambient pressure of high pressure chamber was formed by nitrogen gas. Spray tip penetration, spray cone angle and spray area were measured using high speed camera. SMD(Sauter Mean Diameter) and spray particle velocity were measured using the PDPA(Phase Doppler Particle Analyzer) system to analyze the microscopic properties of test fuels. The results of this experiment showed that spray tip penetration, spray cone angle and spray area of DME-LPG fuels are similar to those of DME fuel. When compared to results of experiment using BOS, significant differences of spray tip penetrations, spray cone angle and spray area are showed because of gas phase. The results of experiment using BOS method showed higher values. SMD of DME-LPG blended fuels is smaller than that of DME fuel. Velocity of DME-LPG blended fuels is faster than that of DME fuel.

• EDISON SW 활용 경진대회 논문집
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• 제4회(2015년)
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• pp.151-155
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• 2015

The molecular interactions between the nucleic acid bases and water molecules are important in organism. Despite Adenine-Thymine Hoogsteen base pair and Guanine-Cytosine Watson-Crick base pair have been demonstrated to be most stable in a gas phase, the effect of water on the stability of these base pairs remains elusive. Here we report the structural and thermodynamic characteristics on possible Adenine-Thymine and Guanine-Cytosine base pairs in a gas phase as well as in an aqueous phase by using quantum mechanical method and statistical mechanical calculations. First, we optimized the direct base-pair interaction energies of four Adenine-Thymine base pairs (Hoogsteen base pair, reverse Hoogsteen base pair, Watson-Crick base pair, and reverse Watson-Crick base pair) and three Guanine-Cytosine base pairs (GC1 base pair, GC2 base pair, and Watson Crick base pair) in a gas phase at the $B3LYP/6-31+G^{**}$ level. Then, the effect of solvent was quantified by the electronic reorganization energy and the solvation free energy by statistical mechanical calculations. Thereby, we discuss the effect of water on the stability of Adenine-Thymine and Guanine-Cytosine base pairs, and argue why Adenine-Thymine Watson-Crick base pair and Guanine-Cytosine Watson-Crick base pair are most stable in an aqueous environment.

• 설비공학논문집
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• 제27권2호
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• pp.75-80
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• 2015

The effect of inlet mixer geometries on the two-phase flow patterns in square micro-channel with $600{\times}600{\mu}m$ was investigated experimentally in this paper. The 4 different mixer configurations based on the Y, Impacting, and two T types (gas and liquid inlets were switched) were used. The test fluids were nitrogen and water. The liquid and gas superficial velocities were 0.01~10 m/s and 0.1~100 m/s, respectively. Several distinctive flow patterns, namely, annular, slug-annular, slug, slug-bubbly, bubbly, and churn flow could be seen. The flow pattern maps for each mixer were suggested, and it can be concluded that two-phase flow patterns are not very sensitive to the mixer geometries. But the mixing behaviors of gas and liquid for each mixer were different for slug and bubbly flow. Thus, the characteristics of slug and bubble for each case were not same.

• Bulletin of the Korean Chemical Society
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• 제27권2호
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• pp.231-236
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• 2006

A novel sample pretreatment technique, headspace hanging drop liquid phase microextraction (HS-LPME) was studied and applied to the determination of flavors from solid clove buds by gas chromatography-mass spectrometry (GC-MS). Several parameters affecting on HS-LPME such as organic solvent drop volume, extraction time, extraction temperature and phase ratio were investigated. 1-Octanol was selected as the extracting solvent, drop size was fixed to 0.6 $\mu$L. 60 min extraction time at 25 ${^{\circ}C}$ was chosen. HS-LPME has the good efficiency demonstrated by the higher partition equilibrium constant ($K_{lh}$) values and concentration factor (CF) values. The limits of detection (LOD) were 1.5-3.2 ng. The amounts of eugenol, $\beta$-caryophyllene and eugenol acetate from the clove bud sample were 1.90 mg/g, 1.47 mg/g and 7.0 mg/g, respectively. This hanging drop based method is a simple, fast and easy sample enrichment technique using minimal solvent. HSLPME is an alternative sample preparation method for the analysis of volatile aroma compounds by GC-MS.

• 한국분말재료학회지
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• 제11권2호
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• pp.124-129
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• 2004

Nanosized WC and WC-Co powders were synthesised by chemical vapor condensation(CVC) process using the pyrolysis of tungsten hexacarbonyl(W(CO)$_6$) and cobalt octacarbonyl(Co$_2$(CO)$_8$). The microstructural changes and phase evolution of the CVC powders during post heat-treatment were studied using the XRD, FE-SEM, TEM, and ICP-MS. CVC powders were consisted of the loosely agglomerated sub-stoichimetric WC$_{1-x}$ and the long-chain Co nanopowders. The sub-stochiometric CVC WC and WC-Co powders were carburized using the mixture gas of CH$_4$-H$_2$ in the temperature range of 730-85$0^{\circ}C$. Carbon content of CVC powder controlled by the gas phase carburization at 85$0^{\circ}C$ was well matched with the theoretical carbon sioichiometry of WC, 6.13 wt％. During the gas phase carburization, the particle size of WC increased from 20 nm to 40 nm and the long chain structure of Co powders disappeared.