• 제목/요약/키워드: Gas-Phase

검색결과 3,253건 처리시간 0.029초

기상반응에 의한 $\beta$-SiC 초미분말 합성시 수소 가스유량과 TMS 농도의 영향 (The Effect of H2 Flow Rate and TMS Concentration on Synthesizing Ultrafine $\beta$-SiC Powder by Vapor Phase Reaction)

  • 유용호;어경훈;소명기
    • 한국세라믹학회지
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    • 제36권8호
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    • pp.853-858
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    • 1999
  • To investigate the effect of H2 flow rate and TMS[Si(CH3)4] concentration on synthesizing ultrafine ${\beta}$-SiC powder by vapor phase reaction the experiment was performed at 1100$^{\circ}C$ of the reaction temperature under the condition of 200-2000 cc/min of H2 gas flow rate and 1-10% of TMS concentration respectively. The shape of ${\beta}$-SiC particles synthesized was spherical and the size of particles decreased and the distribution of particles was more uniform with increasing H2 gas flow rate. In this case Si powders were coexisted with ${\beta}$-SiC Pure and ultrafine ${\beta}$-SiC powders without Si were obtained under the condition of above 2% of TMS concentration and below 1500 cc/min of H2 gas flow rate.

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기상반응에 의한 $Si_3N_4$ 미세분말의 합성 (Synthesis of Ultrafine Silicon Nitride Powders by the Vapor Phase Reaction)

  • 유용호;어경훈;소명기
    • 한국세라믹학회지
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    • 제37권1호
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    • pp.44-49
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    • 2000
  • Silicon nitride powders, were synthesized by the vapor phase reaction using SiH4-NH3 gaseous mixture. The reaction temperature, ratio of NH3 to SiH4 gas and the overall gas quantity were varied. The synthesized powders were characterized using X-ray, TEM, FT-IR and EA. The synthesized silicon nitride powders were in amorphous state, and the average particle size was about 100nm. TEM analysis revealed that the particle size decreased with increasing reaction temperature and gas flow quantity. As-received amorphous powders were annealed in nitrogen atmosphere at 140$0^{\circ}C$ for 2h, then the powders were completely crystallized at 0.2 ratio of NH3 to SiH4.

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Advances in Ion Mobility Spectrometry-Mass Spectrometry (IMS-MS)-Based Techniques for Elucidating Higher-Order Protein Structures

  • Seo, Jongcheol
    • Mass Spectrometry Letters
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    • 제11권4호
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    • pp.65-70
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    • 2020
  • Despite its great success in the field of proteomics, mass spectrometry has limited use for determining structural details of peptides, proteins, and their assemblies. Emerging ion mobility spectrometry-mass spectrometry has enabled us to explore the conformational space of protein ions in the gas phase, and further combinations with the gas-phase ion spectroscopy and the collision-induced unfolding have extended its abilities to elucidating the secondary structure and local details of conformational transitions. This review will provide a brief introduction to the combined approaches of IMS-MS with gas-phase ion infrared spectroscopy or collision-induced unfolding and their most recent results that successfully revealed higher-order structural details.

중·저준위 방사성폐기물 처분시설 폐쇄후 기체이동 (Gas Migration in Low- and Intermediate-Level Waste (LILW) Disposal Facility in Korea)

  • 하재철;이정환;정해룡;김주엽;김주열
    • 방사성폐기물학회지
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    • 제12권4호
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    • pp.267-274
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    • 2014
  • 본 연구에서는 중 저준위방사성폐기물 처분시설(이하 처분시설)에서 발생하는 기체의 이동현상을 예측하기 위한 2차원 수치 모델링을 수행하였다. 또한, 기체 이동 모델링에서 주요 입력변수로 적용되는 사일로 콘크리트의 기체침투압(gas entry pressure)와 기체 투과도(gas permeability)를 실측하여, 모델링 입력변수로 적용하였다. 사일로 콘크리트의 기체침투압(gas entry pressure)와 기체 투과도(gas permeability)는 각각 $0.97{\pm}0.15bar$$2.44{\times}10^{-17}m^2$로 측정되었다. 기체 이동 모델링 결과, 사일로 내부에서 발생하는 수소 기체는 기상으로 이동하지 않고 지하수에 용해되어 지하수와 함께 생태계로 이동하는 것을 알 수 있다. 또한, 폐쇄 후 약 1,000 년 후 부터 사일로 상부부터 수소기체 밀도가 증가하기 시작하는 것으로 예측되었다. 따라서, 사일로 내부에서 발생된 기체는 기상으로 사일로 내부에 축적되지 않으며, 이로 인해 사일로 콘크리트의 내구성에 영향을 미치지 않을 것으로 판단된다.

An approach to the interactive design process using genetic algorithms

  • Okuno, Taku;Kakazu, Yukinori
    • 제어로봇시스템학회:학술대회논문집
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    • 제어로봇시스템학회 1992년도 한국자동제어학술회의논문집(국제학술편); KOEX, Seoul; 19-21 Oct. 1992
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    • pp.281-284
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    • 1992
  • This paper is aiming to apply the Genetic Algorithms (GAs) to the interactive design. For that purpose, the scheme for utilizing the past design processes for the next interactive design process is proposed. In this scheme, the process consists of three phases: the searching phase, the tuning phase and the design phase. The first phase searches the optimal decision sequences for the past design instances by GAs. By the collected sequences, the second phase tunes the criteria of selecting decision sequences for the next design process. By this scheme, the implicit constraints satisfied in the past design can be applied to the next design. Finally, the computer simulations on the simple gear-train design were carried out to show the effectiveness of the scheme.

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상 변화와 인터페이스 이론을 이용한 고에너지물질의 반응연구 (Study of energetic materials using phase change and interface theory)

  • 김기홍;김학준;김형원;여재익
    • 한국추진공학회:학술대회논문집
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    • 한국추진공학회 2008년도 제31회 추계학술대회논문집
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    • pp.60-63
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    • 2008
  • 고에너지 물질의 상변화는 연소과정에서 발생하는 필연적으로 중요한 요소이다. 연소과정에서 발생한 고온, 고압의 가스는 주변의 물질과 상호작용을 통해 복잡한 현상을 일으키게 된다. 본 연구에서는 고에너지 물질의 상변화를 해석을 하기 위한 기초 연구로 상변화 변수를 이용하여, 증기 폭발을 해석하였다.

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A Convective Heat Transfer Correlation for Turbulent Gas-Liquid Two-Phase Flow in Vertical Pipes

  • Kim, Dong-Woo
    • International Journal of Air-Conditioning and Refrigeration
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    • 제9권4호
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    • pp.27-36
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    • 2001
  • A new two-phase non-boiling convective heat transfer correlation for turbulent flow $(Re_{SL}>4000)$ in vertical tubes with different fluid flow patterns and fluid combinations was developed using experimental data available from the literature. The correlation presented herein originates from a careful analysis of the major non-dimensional parameters affecting two-phase heat transfer. This model takes into account the appropriate contributions of both the liquid and gas phases using the respective cross-sectional areas occupied by the two phases. A total of 255 data points from three available studies (which included the four sets of data) were used to determine the curve-fitted constants in the improved correlation. The performance of the new correlation was compared with two-phase correlations from the literature, which were developed for specific fluid combinations.

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저 탄소강의 오스테나이트 질화 시 암모니아 가스첨가 조건변화가 표면층 조직 및 기공변화에 미치는 영향 (Effect of Changes in Condition of Ammonia Gas Addition on the Surface Layer Microstructure and Porosity during Austenitic Nitriding of Low Carbon Steels)

  • 이제원;노용식;성장현;임수근
    • 열처리공학회지
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    • 제32권5호
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    • pp.201-211
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    • 2019
  • Low carbon steel (S20C steel) and SPCC steel sheet have been austenitic nitrided at $700^{\circ}C$ in a closed pit type furnace by changing the flow rate of ammonia gas and heat treating time. When the flow rate of ammonia gas was low, the concentration of residual ammonia appeared low and the hardness value of transformed surface layer was high. The depth of the surface layer, however, was shallow. With increasing the concentration of residual ammonia by raising up the ammonia gas flow, both the depth of the surface layer and the pore depth increased, while the maximum hardness of the surface layer decreased. By introducing a large amount of ammonia gas in a short time, a deep surface layer with minimal pores on the outermost surface was obtained. In this experiment, while maintaining 10~12% of residual ammonia, the flow rate of inlet ammonia gas, 7 liter/min, was introduced at $700^{\circ}C$ for 1 hour. In this condition, the thickness of the surface layer without pores appeared about $60{\mu}m$ in S20C steel and $30{\mu}m$ in SPCC steel plate. Injecting additional methane gas (carburizing gas) to this condition played a deteriorating effect due to promoting the formation of vertical pores in the surface layer. For $1^{st}$ transformed surface layer for S20C steel, maintaining 10~12% residual ammonia condition via austenitic nitriding process resulted in ${\varepsilon}$ phase with relatively high nitrogen concentration (just below 4.23 wt.%N) among the mixed phases of ${\varepsilon}+{\gamma}$. The ${\varepsilon}$ phase was formed a specific orientation perpendicular to the surface. For $2^{nd}$ transformed layer for S20C steel, ${\gamma}$ phase was rather dominant (just above 2.63 wt.%N). For SPCC steel sheet, there appeared three phases, ${\gamma}$, ${\alpha}(M)$ and weak ${\varepsilon}$ phase. The nitrogen concentration would be approximately 2.6 wt.% in these phases condition.