• Proceedings of the Korea Air Pollution Research Association Conference
• /
• 2006.04a
• /
• pp.519-522
• /
• 2006

• Proceedings of the Korea Air Pollution Research Association Conference
• /
• 2007.10a
• /
• pp.345-346
• /
• 2007

• Proceedings of the Korea Air Pollution Research Association Conference
• /
• 2009.10a
• /
• pp.130-132
• /
• 2009

• Bulletin of the Korean Chemical Society
• /
• v.29 no.8
• /
• pp.1525-1532
• /
• 2008

An instrument was developed for the simultaneous determination of gas- and aerosol-phase nitrous acid (HONO). Gaseous HONO (HONO(g)) was sampled by a diffusion scrubber and particulate nitrite ($NO_2\;^-$(p)) was collected by a particle growth chamber. The collected samples were analyzed in time-sharing manner, based on the peroxynitrite-induced luminol chemiluminescence. The automated system was found to be sensitive with 13 pptv of detection limit, fast with 4 min. of sampling frequency, and simple and affordable to construct and operate. The system was optimized by adjusting the experimental parameters. The system was applied to the field measurement of gas- and particle-phase HONO during the springtime of 2004 in Gwangju, South Korea. HONO(g) concentrations varied diurnally from 200 pptv around 3 P.M. to 800 pptv at 5 A.M. The variation of $NO_2\;^-$(p) was not significant with the maximum of 240 pptv at 11 P.M. and the minimum of 170 pptv at 4 P.M., not displaying distinct characteristics.

• Journal of Climate Change Research
• /
• v.8 no.1
• /
• pp.63-71
• /
• 2017

It is recognized that tetrafluoromethane ($CF_4$) has a great influence on global warming. The $CF_4$ is known to have a large impact on climate change due to its large global warming index. In this study, a waterjet plasma scrubber (WPS) was designed and manufactured for the $CF_4$ decomposition. The WPS is a novel technology which is combined a gliding arc plasma and water injection at the center of the plasma discharge. This can give an innovative way for $CF_4$ decomposition by achieving larger plasma columnand generating OH radicals. A performance analysis was achieved for the design factors such as waterjet flow rate, total gas flow rate, consumption electric power, and electrode gap. The highest $CF_4$ decomposition and energy efficiencies were 64.8% and 6.43 g/kWh, respectively; Optimal operating conditions were 20 mL/min of waterjet flow rate, 200 L/min total gas flow rate, 5.3 kW consumption electric power, and 4.4 mm electrode gap. As for the 2 stage reactor of the WPS, the $CF_4$ decomposition efficiency improved as the 85.3% while the energy efficiency decreased as the 5.57 g/kWh.

• Clean Technology
• /
• v.17 no.3
• /
• pp.250-258
• /
• 2011

Thermal plasma has been presented for the decomposition of perfluorocompounds (PFCs) which are extensively used in the semiconductor manufacturing and display industry. We developed pilot-scale equipment to investigate the large scale treatment of PFCs and called it a "thermal plasma scrubber". PFCs such as $CF_4$, $C_2F_6$, $SF_6$, and $NF_3$ used in experiments were diluted with $N_2$. There were two different types of experiment setup related to the water spray direction inside the thermal plasma scrubber. The first type was that the water was sprayed directly into the gas outlet located at the exit of the reaction section. The second type was that the water was sprayed on the wall of the quenching section. More effective decomposition took place when the water was sprayed on the quenching section wall. For $C_2F_6$, $SF_6$, and $NF_3$ the maximum destruction and removal efficiency was nearly 100%, and for $CF_4$ was up to 93%.

• Polymer(Korea)
• /
• v.26 no.5
• /
• pp.661-669
• /
• 2002

The purpose of this research is to absorb and remove sulfur dioxide existing in the air by using ion exchange non-woven fabric. So we found out very appropriate condition of anionic exchange fabric scrubber by measuring amount of SO$_2$ adsorption under the atmosphere that concentration, velocity, and humidity was 100∼200 ppm, 0.6∼1.0 m/sec, and 30∼90 RH%, respectively. Ion exchange capacity of ion exchanger showed the maximum value, 3.75 meq/g at pH 4, and adsorption equilibrium time was the maximum value, 30 h when gas velocity was 0.6 m/sec, moreover, at 80$\^{C}$, adsorption equilibrium time tended to decrease more than 10 h. When concentration was 200 ppm, while reaction speed between SO$_2$ and ligand of fibrous ion exchanger was getting faster, adsorption break point had a tendency to get faster as well. In addition, when relative humidity in the scrubber was 90%, adsorption efficiency was 7.6%/h that seemed to be 30% higher than 4.6%/h coming from the condition that relative humidity had been 30%, and it was totally absorbed under 5 wt% NaOH solution in 5 minutes.

• Journal of the Korean Applied Science and Technology
• /
• v.34 no.4
• /
• pp.986-994
• /
• 2017

In this paper, $CO_2$ absorption of scrubber was tested for removal of high concentration $CO_2$. Liquid to gas ratio($18L/m^3$) and Superficial velocity(0.14 m/s) was determined through Lab-scale test. As flow rates increase 1, 2, 3, 4 and $5m^3/min$, $CO_2$ removal efficiency decrease 98.47%, 96.46%, 92.95%, 89.71% and 85.49%. Also, the scrubber operation made energy improvement(5.4%), energy saving(11.5 TOE/year) and greenhouse gases reduction(6.5 TC/year).

• Journal of Environmental Health Sciences
• /
• v.16 no.2
• /
• pp.89-95
• /
• 1990

This study was investigated to the energy recovery by the pyrolysis of waste tyre. the pyrolysis of the waste tyre was made by using the pyrolysis chamber for the gasification and the combustion chamber for the combustion of the pyrolysis gas. In batch system, the amount of waste tyre was put 150kg in the pyrolysis chamber and the proper air flow rate for the stable production of the pyrolysis gas was 0.95Nm$^{3}$ /min. the production time of the pyrolysis gas was stable above 210minutes, and the stable production rate was above 3.8Nm$^{3}$ /min. The production temperature of pyrolysis gas was 170$^{\circ}$C and combustion temperature of pyrolysis gas was 1,000$^{\circ}$C. The combustible component of washing gas in pyrolysis gas of waste tyre was CO, CH$_{4}$, $C_{2}H_{6}$ and $C_{3}H_{8}$, and total amount was 22.7%. Heat value of condensed material was 9,804Kcal/kg. The average concentration of air pollutants between cyclone and scrubber was CO 420.4ppm, SO$_{x}$ 349.8ppm. NO$_{x}$ 68.Sppm, HCl 24.4ppm and Dust 240.0g / Nm$^{3}$, respectively.

• Proceedings of the KSME Conference
• /
• 2004.11a
• /
• pp.1629-1633
• /
• 2004

Liquid is commonly introduced as transversal jets in venturi scrubber which is one of the gas cleaning equipments. The jet dynamics such as penetration and breakup is of fundamental importance to the dust-collection efficiency. We have developed a model that can numerically simulate the breakup of the liquid jet in crossflow. This simulation consists of models on liquid column, jet surface breakup, column fracture and secondary droplet breakup. These models have been embedded in the KIVA3-V code. We have calculated such parameters as the jet penetration, jet trajectory, droplet size, velocity field and the volume flux distribution. The results are compared with the experimental data in this paper.