• 제목/요약/키워드: Gas release

검색결과 662건 처리시간 0.022초

Discovery of a New Mechanism to Release Complex Molecules from Icy Grain Mantles around Young Stellar Objects

  • Hoang, Thiem;Tram, Le Ngoc
    • 천문학회보
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    • 제44권1호
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    • pp.70.4-70.4
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    • 2019
  • Complex organic molecules (COMs) are increasingly observed in the environs of young stellar objects (YSOs), including hot cores/corinos around high-mass/low-mass protostars and protoplanetary disks. It is widely believed that COMs are first formed in the ice mantle of dust grains and subsequently released to the gas by thermal sublimation at high temperatures (T>100 K) in strong stellar radiation fields. In this paper, we report a new mechanism that can desorb COMs from icy grain mantles at low temperatures (T<100K), which is termed rotational desorption. The rotational desorption process of COMs comprises two stages: (1) ice mantles on suprathermally rotating grains spun-up by radiative torques (RATs) are first disrupted into small fragments by centrifugal stress, and (2) COMs and water ice then evaporate rapidly from the tiny fragments (i.e., radius a <1nm) due to thermal spikes or enhanced thermal sublimation due to increased grain temperature for larger fragments (a>1 nm). We discuss the implications of rotational desorption for releasing COMs and water ice in the inner region of protostellar envelopes (hot cores and corinos), photodissociation regions, and protoplanetary disks (PPDs). In shocked regions of stellar outflows, we find that nanoparticles can be spun-up to suprathermal rotation due to supersonic drift of neutral gas, such that centrifugal force can be sufficient to directly eject some molecules from the grain surface, provided that nanoparticles are made of strong material. Finally, we find that large aggregates (a~ 1-100 micron) exposed to strong stellar radiations can be disrupted into individual icy grains via RAdiative Torque Disruption (RATD) mechanism, which is followed by rotational desorption of ice mantles and evaporation of COMs. In the RATD picture, we expect some correlation between the enhancement of COMs and the depletion of large dust grains in not very dense regions of YSOs.

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Assessment of INSPYRE-extended fuel performance codes against the SUPERFACT-1 fast reactor irradiation experiment

  • L. Luzzi;T. Barani;B. Boer;A. Del Nevo;M. Lainet;S. Lemehov;A. Magni;V. Marelle;B. Michel;D. Pizzocri;A. Schubert;P. Van Uffelen;M. Bertolus
    • Nuclear Engineering and Technology
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    • 제55권3호
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    • pp.884-894
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    • 2023
  • Design and safety assessment of fuel pins for application in innovative Generation IV fast reactors calls for a dedicated nuclear fuel modelling and for the extension of the fuel performance code capabilities to the envisaged materials and irradiation conditions. In the INSPYRE Project, comprehensive and physics-based models for the thermal-mechanical properties of U-Pu mixed-oxide (MOX) fuels and for fission gas behaviour were developed and implemented in the European fuel performance codes GERMINAL, MACROS and TRANSURANUS. As a follow-up to the assessment of the reference code versions ("pre-INSPYRE", NET 53 (2021) 3367-3378), this work presents the integral validation and benchmark of the code versions extended in INSPYRE ("post-INSPYRE") against two pins from the SUPERFACT-1 fast reactor irradiation experiment. The post-INSPYRE simulation results are compared to the available integral and local data from post-irradiation examinations, and benchmarked on the evolution during irradiation of quantities of engineering interest (e.g., fuel central temperature, fission gas release). The comparison with the pre-INSPYRE results is reported to evaluate the impact of the novel models on the predicted pin performance. The outcome represents a step forward towards the description of fuel behaviour in fast reactor irradiation conditions, and allows the identification of the main remaining gaps.

포도의 Chlorine Dioxide Gas 훈증처리 및 저장방법에 관한 연구 (Effects of Chlorine dioxide ($ClO_{2}$) Gas Treatment on Postharvest Quality of Grapes)

  • 장은하;정대성;최종욱
    • 한국식품저장유통학회지
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    • 제14권1호
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    • pp.1-7
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    • 2007
  • 농산물의 미생물학적 안전성에 대한 요구가 증대되면서 미생물에 의한 농산물의 오염 및 균의 발생을 최소화하기 위해 이산화염소($ClO_{2}$) 가스를 이용한 포도저장 실험을 수행하였다. 실험 결과 중량감소율은 상온, 저온저장 모두 20 ppm+Ny/PE/L-LDPE 처리구가 가장 적었고 가용성 고형물 함량은 상온, 저온저장 모두 무처리구가 다른 포장구에 비해 높은 값을 나타내었으며 20 ppm+Ny/PE/L-LDPE 처리구는 감소했다. 적정산도 값은 상온, 저온저장 중 모든 포장구에서 감소하는 경향을 나타내었으며 Anthocyanin 함량은 상온저장에서는 모든 포장구에서 저장 14일까지 증가하다가 저장 21일에 급격히 감소했으며 저온저장에서는 저장 10주까지 모든 포장구간이 초기보다 증가하는 경향을 나타내었다. 총균수 값은 상온저장 시 $ClO_{2}$ gas처리 및 silica gel pad 처리구가 총균수 억제효과를 나타내었고 저온저장에서는 $ClO_{2}$ gas를 처리한 20 ppm+Ny/PE/L-LDPE와 40 ppm포장구에서 총균수 억제효과를 나타내어 저온보다 상온에서 $ClO_{2}$ gas의 효과가 더 크게 작용하는 것으로 나타났다.

$Zn[BH_4]_2$ 분말의 합성과 열분해 특성 (Synthesis and thermal decomposition of $Zn[BH_4]_2$)

  • 전은;조영환
    • 한국수소및신에너지학회논문집
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    • 제16권3호
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    • pp.262-268
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    • 2005
  • [ $Zn(BH_4)_2$ ](8.4 wt% theoretical hydrogen storage capacity powders have been successfully synthesized by mechanochemical reaction from mixtures of $ZnCl_2$ and $NaBH_4$ powders in a 1:2 molar ratio in different times. $$ZnCl_2+2NaBH_4{\rightarrow}Zn(BH_4)_2+2NaCl$$ (1) $Zn(BH_4)_2$ powders were characterized by X-ray diffractometry(XRD), and Furier Transform Infrared spectrometry(FT-IR). The thermal stabilities of $Zn(BH_4)_2$ powders were studied by Differential scanning calorimetry(DSC), Thermogravimetry analysis(TGA), and Mass spectrometry(MS). $Zn(BH_4)_2$ can be tested for hydrogen evolution without further purification. The reaction to yield hydrogen is irreversible, the other products being compounds of Zn, and borane. $Zn(BH_4)_2$ thermally decomposes to release borane and hydrogen gas between about 85 and 150$^{\circ}C$.

가솔린 직분사식 불꽃점화기관에서 연료 분사 방향이 혼합기 형성에 미치는 영향에 관한 수치적 연구 (Numerical Study on the Effect of Injection Direction on Mixture Formation Characteristics in DISI Gasoline Engine)

  • 김태훈;박성욱
    • 한국연소학회:학술대회논문집
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    • 한국연소학회 2014년도 제49회 KOSCO SYMPOSIUM 초록집
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    • pp.101-102
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    • 2014
  • Rising oil price and environmental problems are causing automotive industry to increase fuel efficiency. Improved fuel efficiency in gasoline engine was made possible by development of DISI gasoline engine. Since fuel is injected inside cylinder directly, in-cylinder temperature can be reduced than multi-port injection engine and this leads to increased compression ratio. However, engine performance is largely dependent on mixture formation process due to in-cylinder fuel injection. Especially for spray guided and air guided DISI gasoline engine, injection direction is important factor to mixture preparation. It is because interaction between intake flow and spray affect fuel-air mixture. Hence, in this study, mixture formation characteristics were analyzed by varying injection direction using KIVA 3V release2 code. Residual gas was considered for assuming combustion. Therefore, initial condition for in-cylinder temperature was set equal to the end state of exhaust stroke of combustion cycle. Since angle between intake air flow direction and spray direction affects fluid flow and evaporation field, mixture distribution was affected by fuel injection direction dominantly.

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예혼합 연소기에서의 화염 전달 함수 측정 (Flame Transfer Function Measurement in a Premixed Combustor)

  • 김대식;김기태;전승배;이종근
    • 한국연소학회지
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    • 제13권2호
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    • pp.1-6
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    • 2008
  • An experimental study of the flame response in a turbulent premixed combustor has been conducted with room temperature, atmospheric pressure inlet conditions using premixed natural gas. The fuel is premixed with the air upstream of a choked inlet to avoid equivalence ratio fluctuations. Therefore the observed flame response is only the result of the imposed velocity fluctuations, which are produced using a variable speed siren. Measurements are made of the velocity fluctuation in the nozzle using hot wire anemometry and of the heat release fluctuation in the combustor using chemiluminescence emission. The results are analyzed to determine the phase and gain of the flame transfer function as a function of the modulation frequency. Of particular interest is the effect of flame structure on the flame response predictions and measurements. The results show that both the gain and the phase of flame transfer function are closely associated with the flame length and structure, which is dependent upon the upstream flow perturbation as well as equivalence ratio in the current study.

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Local Environmental Effects on AGN Activities

  • Kim, Jaemin;Yi, Sukyoung K.
    • 천문학회보
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    • 제38권2호
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    • pp.44.2-44.2
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    • 2013
  • The local environmental effects on the active galactic nucleus(AGN) activity has been studied by many authors, but there is still controversy. We performed statistical analysis for nearby(0.01 < z < 0.05) volume limited(Mr < -19) sample via visual inspection based on Sloan Digital Sky Survey Data Release7. We visually inspect around 50,000 galaxy images to find peculiar objects which show not only ongoing merging features and tidal features, but also post merging features like shell or ring structures. We found that the frequency of AGN host galaxies is at least 2 times higher among peculiar galaxies than non-peculiar galaxies, and this trend is still visible when galaxy properties such as color or stellar mass are fixed. Furthermore, L[OIII] of peculiar galaxies is found to be more increased than those of normal galaxies. The majority of the most luminous AGN hosts show peculiar feature, which indicates that the luminous AGN galaxies may be the result of the local environmental effects. In addition, the enhancement of L[OIII] in peculiar galaxies is more significant for bluer galaxies, which implies that AGN activity is enhanced effectively when gas is available. In order to ensure our results, we also checked it for a smaller subsample with 2 magnitude deeper monochromatic images provided by SDSS Stripe82 database, and found consistent results. Overall, the results of this study tell us that the local environment of galaxies affects the frequency as well as the strength of AGN activity.

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연료전지차량용 고압수소저장시스템의 화재 안전성 평가 (Fire Safety evaluation of High Pressure Hydrogen System for FCEV)

  • 최영민;장규진;김상현;황기호;황인철;안병기;임태원
    • 한국수소및신에너지학회논문집
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    • 제20권3호
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    • pp.188-193
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    • 2009
  • Fuel cell vehicles are equipped with Pressure Relief Devices(PRDs) installed in pressure tank cylinder to prevent the explosion of the tank during a fire. PRDs are safety devices that perceive a fire and release gas in the pressure tank cylinder before it is exploded. But if the PRD does not actuate, because either the PRD fails or can't be surrounded by the flame of a fire, the tank will rupture and produce a blast wave and hydrogen fire ball. In this paper, we observed the fire behavior of actual fuel cell vehicle, comparing with that of gasoline vehicle.

화염 가수분해 증착공정에서 온도 및 OH 분포측정 (Measurements of Temperature and OH Radical Distributions in Flame Hydrolysis Deposition Process)

  • 황준영;길용석;김정익;최만수;정석호
    • 대한기계학회논문집B
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    • 제24권11호
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    • pp.1464-1469
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    • 2000
  • The effects of SiCl$_4$addition on flame structures have been studied in flame hydrolysis deposition (FHD) processes using Coherent anti-Stokes Raman spectroscopy (CARS) and planar laser induced fluorescence (PLIF) to measure temperatures and OH concentrations, respectively. The results demonstrate that even a small amount of SiCl$_4$ addition can change thermal and chemical structures of H$_2$/O$_2$ diffusion flames. When SiCl$_4$ is added to a flame temperature decreases in non-reacting zone due to the increases in both specific heat and density of the gas mixture, while flame temperature increase in particle formation zone due to the heat release through hydrolysis and oxidation reactions of SiCl$_4$. It is also found that OH concentration decreases dramatically in particle formation zone where temperatures increase. This can be attributed to consumption of oxidative species and generation of HCl during silica formation.

열 구동 엑츄에이터와 SU-8을 이용한 마이크로 그리퍼 설계 및 제조 (Design and fabrication of microgripper using thermal actuator and SU-8)

  • 정승호;박준식;이민호;박상일;이인규
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2007년도 춘계학술대회A
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    • pp.1613-1616
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    • 2007
  • A microgripper using thermal actuator and SU-8 polymer was designed and fabricated to manipulate cells and microparts. A chip size of a microgripper was 3 mm ${\times}$ 5 mm. The thermally actuated microgripper consisted of two couples of hot and cold arm actuators. The high thermal expansion coefficient, 52 $ppm/^{\circ}C$, of SU-8 compared to silicon and metals, allows the actuation of the microgripper. Thickness and width of SU-8 as an end-effector were 26 ${\mu}m$ and 80 ${\mu}m$, respectively. Initial gap between left jaw and right jaw was 120 ${\mu}m$. The ANSYS program as FEM tool was introduced to analyze the thermal distribution and displacement induced by thermal actuators. $XeF_2$ gas was used for isotropic silicon dry etching process to release SU-8 end-effector. Mechanical displacements of the fabricated microgripper were measured by optical microscopy in the range of input voltage from 0 V to 2.5 V. The maximum displacement between two jaws of a microgripper Type OG 1_1 was 22.4 ${\mu}m$ at 2.5 V.

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