• Title/Summary/Keyword: Gas pores

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The Study on the Formation Mechanism of Gas Pore During Lost Foam Casting of Al alloys (알루미늄 합금의 소실모형주조 중 기포 형성 기구에 관한 연구)

  • Shin, Seung-Ryoul;Han, Sang-Won;Lee, Kyong-Whoan;Lee, Zin-Hyoung
    • Journal of Korea Foundry Society
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    • v.23 no.5
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    • pp.268-275
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    • 2003
  • The mechanism of the hydrogen gas pore formation was investigated in Lost Foam Casting of Al-alloy by reduced pressure test and real casting. The hydrogen gas pick-up was affected by the formed gas during the decomposition of polystyrene in addition to the liquid product. It depended on pouring temperature and a proper temperature of metal front gave the minimum hydrogen pick-up. At a low pouring temperature, the hydrogen went into the melt mainly from entrapped liquid product of polystyrene but pores were formed from the gas as well as the liquid product at a high pouring temperature. The mold flask evacuation down to 710torr decreased the gas porosity down by around 0.4% vol%. The entrapped decomposition product of polystyrene in the melt was observed through the visualization of filling behavior of Al alloy-melt with the high speed camera.

Gas Sensing Characteristics of SnO2 Coated with Catalyst for Hydrocarbon Gas (촉매가 첨가된 SnO2 가스센서의 탄화수소 가스에 대한 감응 특성)

  • Lee, Ji-Young;Yu, Il
    • Korean Journal of Materials Research
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    • v.22 no.7
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    • pp.358-361
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    • 2012
  • Co and Ni as catalysts in $SnO_2$ sensors to improve the sensitivity for $CH_4$ gas and $CH_3CH_2CH_3$ gas were coated by a solution reduction method. $SnO_2$ thick films were prepared by a screen-printing method onto $Al_2O_3$ substrates with an electrode. The sensing characteristics were investigated by measuring the electrical resistance of each sensor in a chamber. The structural properties of $SnO_2$ with a rutile structure investigated by XRD showed a (110) dominant $SnO_2$ peak. The particle size of the $SnO_2$:Ni powders with Ni at 6 wt% was about 0.1 ${\mu}m$. The $SnO_2$ particles were found to contain many pores according to a SEM analysis. The sensitivity of $SnO_2$-based sensors was measured for 5 ppm of $CH_4$ gas and $CH_3CH_2CH_3$ gas at room temperature by comparing the resistance in air to that in the target gases. The results showed that the best sensitivity of $SnO_2$:Ni and $SnO_2$:Co sensors for $CH_4$ gas and $CH_3CH_2CH_3$ gas at room temperature was observed in $SnO_2$:Ni sensors coated with 6 wt% Ni. The $SnO_2$:Ni gas sensors showed good selectivity to $CH_4$ gas. The response time and recovery time of the $SnO_2$:Ni gas sensors for the $CH_4$ and $CH_3CH_2CH_3$ gases were 20 seconds and 9 seconds, respectively.

Characteristics of Indium Doped SnO2 Thick Film for Gas Sensors (Indium 첨가된 SnO2 후막형 가스센서의 특성)

  • Yu, Il;Lee, Ji-Young
    • Korean Journal of Materials Research
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    • v.20 no.8
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    • pp.408-411
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    • 2010
  • Indium doped $SnO_2$ thick films for gas sensors were fabricated by a screen printing method on alumina substrates. The effects of indium concentration on the structural and morphological properties of the $SnO_2$ were investigated by X-ray diffraction and Scanning Electron Microscope. The structural properties of the $SnO_2$:In by X-ray diffraction showed a (110) dominant $SnO_2$ peak. The size of $SnO_2$ particles ranged from 0.05 to $0.1\;{\mu}m$, and $SnO_2$ particles were found to contain many pores, according to the SEM analysis. The thickness of the indium-doped $SnO_2$ thick films for gas sensors was about $20\;{\mu}m$, as confirmed by cross sectional SEM image. Sensitivity of the $SnO_2$:In gas sensor to 2000 ppm of $CO_2$ gas and 50 ppm of H2S gas was investigated for various indium concentrations. The highest sensitivity to $CO_2$ gas and H2S gas of the indium-doped $SnO_2$ thick films was observed at the 8 wt% and 4 wt% indium concentration, respectively. The good sensing performances of indium-doped $SnO_2$ gas sensors to $CO_2$ gas were attributed to the increase of oxygen vacancies and surface area in the $SnO_2$:In. The $SnO_2$:In gas sensors showed good selectivity to $CO_2$ gas.

Study on the Manufacture of Ethylene Gas Absorbing Corrugated Board (에틸렌 가스 흡착 기능성 골판지 제조를 위한 기초연구)

  • Lee, Ji Young;Kim, Chul Hwan;Kim, Eun Hea;Park, Tae Ung;Choi, Jae Sung
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.48 no.2
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    • pp.20-27
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    • 2016
  • Ethylene gas is a natural hormone that directly affects the freshness of agricultural products, so it is very important for the maintenance of freshness to remove ethylene gas from corrugated board boxes. Many methods for the removal of this and other gases have been reported. In this study, the utilization of an absorbent using activated carbon was adopted for the removal of ethylene gas from a corrugated board box. Activated carbon powders were prepared by grinding in a laboratory and were used to treat the surface and to laminate paperboards with a starch solution. The ethylene gas absorption was evaluated by using a gas chromatography to measure the residual ethylene gas concentration. About 60% of the ethylene gas was absorbed by the activated carbon itself. However, the paperboards that were surface-treated and laminated with starch and activated carbon showed lower than 20% ethylene gas absorption. This was because the starch and smaller particles of activated carbon blocked the surface pores of activated carbon particles. Therefore, either the use of the binders must be minimized for the surface treatment of paperboards, or activated carbon packs can be used as absorbents in corrugated boxes.

Clinical Application of OXYREX Hollow Fiber Membrane Oxygenator (국산 막형 산화기 (OXYREX)의 체외순환 임상 성적 - 개심수술 40례 적용 -)

  • 김형묵
    • Journal of Chest Surgery
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    • v.23 no.6
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    • pp.1049-1056
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    • 1990
  • The OXYREX hollow fiber membrane oxygenator developed by joint work of KIST and Green Cross Medical company has been evaluated by experimental investigation and clinical application, In this oxygenator gas exchanges occur through small pores of 0.1pm size which are distributed on 70% of surface of polypropylene hollow fiber. The Oxyrex membrane oxygenator consists of 36 thousand hollow fibers and it has 3.3m2 of gas exchange surface. The Oxyrex membrane oxygenator has unique blood flow path: blood enters the oxygenator passes between the hollow fibers and exits through outlet ports, that provides low transmembrane pressure drop. In the animal experiment and in vitro investigations of Oxyrex oxygenator, it showed low transmembrane pressure difference, effective heat exchanger performance, stable gas transfer function and less blood trauma. The Oxyrex oxygenator been used from March, 1990, to October, 1990, in 40 patients undergoing open heart operations. In the clinical applications of Oxyrex, adequate oxygenation[PaO2, 283$\pm$70mmHg] and carbon dioxide removal[PaCO2, 27\ulcorner6mmHg]were maintained under the condition of FiO2: below 0.6, Hct; 25%, perfusion flow; 2.4 L/min, gas flow: 2.1 L/min. During maximum 365 minutes of cardiopulmonary bypass[CPB] time period, the Oxyrex oxygenator maintained stable condition of PaO2, PaCO2 respectively and it also kept low plasma hemoglobin level. The complement proteins C3 and CH50 were not significantly changed pre to post CPB. There were no complications related to the oxygenator during and after the CPB.

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Fabrication of Gas Diffusion Layer for Fuel Cells Using Heat treatment Slurry Coating Method (열처리 슬러리코팅법을 이용한 연료전지 가스확산층의 제조)

  • Kim, Sungjin;Park, Sung Bum;Park, Yong-Il
    • Journal of the Korean Society for Heat Treatment
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    • v.25 no.2
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    • pp.65-73
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    • 2012
  • The Gas Diffusion Layer (GDL) of fuel cell, are required to provide both delivery of reactant gases to the catalyst layer and removal of water in either vapor or liquid form in typical PEMFCs. In this study, the fabrication of GDL containing Micro Porous Layer (MPL) made of the slurry of PVDF mixed with carbon black is investigated in detail. Physical properties of GDL containing MPL, such as electrical resistance, gas permeability and microstructure were examined, and the performance of the cell using developed GDL with MPL was evaluated. The results show that MPL with PVDF binder demonstrated uniformly distributed microstructure without large cracks and pores, which resulted in better electrical conductivity. The fuel cell performance test demonstrates that the developed GDL with MPL has a great potential due to enhanced mass transport property due to its porous structure and small pore size.

Effect of Coal Tar Pitch Viscosity on Impregnation for Manufacture of Carbon Blocks with High Density (고밀도화 탄소 블록 제조 시 콜타르계 피치의 점도가 함침에 미치는 영향)

  • Cho, Jong Hoon;Hwang, Hye In;Kim, Ji Hong;Lee, Young-Seak;Im, Ji Sun;Kang, Seok Chang
    • Applied Chemistry for Engineering
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    • v.32 no.5
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    • pp.569-573
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    • 2021
  • In this study, high-density carbon blocks were manufactured using coke, binder pitch, and impregnated pitch, then the effect of pitch fluidity on the densification of carbon blocks during the impregnation process was investigated. A green block was manufactured through high-pressure figuration of coke and binder pitch, and a carbon block was obtained through a heat treatment process. An impregnation process was performed to remove pores generated by volatilization of the binder pitch during the heat treatment process. The impregnation process was carried out the high-pressure reaction step of impregnating the pitch into the carbon block followed by the pretreatment step of melting the impregnation pitch. Melting of the impregnation pitch was carried out at 140~200 ℃, and the viscosity of the impregnation pitch decreased as the heat treatment temperature increased. The decrease in the viscosity of the impregnation pitch improved the fluidity and effectively impregnated the pores inside the carbon block, reducing the porosity of the carbon block by 83% and increasing the apparent density by 5%.

Gas Sensing Characteristics of Nano Sized SnO2 Sensors for Various Co and Ni Concentration (Co, Ni 농도 변화에 따른 나노 SnO2 센서의 감응 특성)

  • Lee, Ji-Young;Yu, Yoon-Sic;Yu, Il
    • Korean Journal of Materials Research
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    • v.21 no.10
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    • pp.546-549
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    • 2011
  • Nano-sized $SnO_2$ thick films were prepared by a screen-printing method onto $Al_2O_3$ substrates. The sensing characteristics were investigated by measuring the electrical resistance of each sensor in a test box as a function of the detection gas. The nano-sized $SnO_2$ thick film sensors were treated in a $N_2$ atmosphere. The structural properties of the nano $SnO_2$with a rutile structure according to XRD showed a (110) dominant $SnO_2$ peak. The particle size of $SnO_2$:Ni nano powders at Ni 8 wt% was about 45 nm, and the $SnO_2$ particles were found to contain many pores according to the SEM analysis. The sensitivity of the nano $SnO_2$-based sensors was measured for 5 ppm $CH_4$ gas and $CH_3CH_2CH_3$ gas at room temperature by comparing the resistance in air with that in the target gases. The results showed that the best sensitivity of $SnO_2$:Ni and $SnO_2$:Co sensors for $CH_4$ gas and $CH_3CH_2CH_3$ gas at room temperature was observed in $SnO_2$:Ni sensors doped with 8 wt% Ni. The response time of the $SnO_2$:Ni gas sensors was 10 seconds and recovery time was 15 seconds for the $CH_4$ and $CH_3CH_2CH_3$ gases.

Fabrication of Porous Mullite Ceramics and Its Properties (다공성 Mullite 세라믹스 제조 및 그 특성)

  • 김병훈;나용한
    • Journal of the Korean Ceramic Society
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    • v.31 no.3
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    • pp.275-281
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    • 1994
  • Mullite ceramics have recently been utilized as ceramic gas filters for high-temperature treatment of solid wastes due to their low thermal expansion coefficient and high refractoriness under load. In this experiment, mechanical, thermal and microstructural properties of porous mullite ceramics, which were used as carriers and high-temperature gas filters in food industry, were investigated as a function of starting raw materials. Porous mullite ceramics showed different microstructures depending on their starting materials. The specimen M2 had excellent resistance to thermal spalling and high mechanical strength. The average pore size varied from 0.3 ${\mu}{\textrm}{m}$ to 16.6 ${\mu}{\textrm}{m}$, and porous mullite ceramics fabricated by thermal decomposition of Al(OH)3 had very large pores and broad distribution of pore size.

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A study on porous metal mold using organic binder (유기바인더를 이용한 통기성 금형제작에 관한 연구)

  • 김경래;정성일;임용관;정해도;이석우;최헌종
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2002.05a
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    • pp.1026-1029
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    • 2002
  • Outlet of gas has been a big problem in deforming rubber or plastic in pressing mold. Air vent has been used to solve the problem, but it has weak points such as the increased cost, the increased number of process, and vent marks on the surface of a produce. In this study, the sintering method is used for making porous metal mold. Porous metal mold has many open pores, which are very small. When Porous metal mold is used for pressing mold, all process would be made short, produce cost would be down, and it would not leave vent marks on the surface of a produce. Porosity varies from sintering and pressing conditions, which are the pressure of compacting powder, the length of sintering time, sintering temperature and sintering atmosphere etc. This study will find optimized sintering temperature condition for the Porous metal mold.

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