• Title/Summary/Keyword: Gas pores

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The Formation of Nitrogen Gas Pore During Solidification of 16Cr-3Ni Stainless Steels

  • Seong, Ho-Yang;Kim, Do-Hyung;Park, Young-Hwan;Lee, Zin-Hyoung
    • Journal of Korea Foundry Society
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    • v.23 no.3
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    • pp.147-152
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    • 2003
  • 질소 용해도가 낮은 ${\delta}$상으로 응고가 시작되는 16Cr-3Ni 계 스테인리스강의 응고시 질소기포 형성에 미치는 질소 함량과 냉각속도의 영향이 조사되었으며 이를 기반으로 질소 기포 결함이 발생하는 임계 질소 함량을 예측하는 방법을 제시하였다. 질소함량의 증가는 질소 기포 결함을 증가시켰으며, 냉각속도의 증가는 질소기포결함의 형성을 다소 억제 할 수 있는 것으로 조사되었다. 실험적으로 구한 Fe-16Cr-3Ni-9Mn 합금의 임계 질소 함량은 0.19wt%였으며, 임계 질소 압력은 평형응고로 가정한 경우 1.27atm, Scheil 응고로 가정한 경우에는 1.23atm으로 계산되었다. 질소 용해도를 증가시킬 수 있는 Mn 함량의 변화에 따른 임계 질소 함량의 변화를 예측하기 위하여 계산된 임계 질소 압력을 Fe-16Cr-3Ni-11Mn 합금에 적용하였으며 이를 통해 얻은 임계 질소 함량은 평형응고로 가정한 경우 0.25wt%, Scheil 응고로 가정한 경우에는 0.24wt% 로 예측되었다. 예측 결과의 타당성을 확인하기 위하여 Fe-16Cr-3Ni-11Mn 합금의 실험 결과와 비교하였으며, 일치하는 결과가 얻어졌다.

Effects of Different Shielding Gases in Laser Welding of Secondary Ni battery with Multi-thin Plates (이차전지용 니켈 다층 박판의 레이저 용접 보호가스의 영향)

  • You, Young-Tae;Lee, Ka-Ram;Kim, Jin-Woo
    • Journal of the Korean Society of Manufacturing Technology Engineers
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    • v.25 no.5
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    • pp.329-337
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    • 2016
  • The demand for the eco-friendly vehicles is skyrocketing because of the increasing $CO_2$ emissions and global warming. In the industrial field, the battery process, a core part of an eco-friendly vehicle, is drawing increased attention; its weight lightening as well as high energy density are becoming increasingly important. In this study, pure Ni plates that were used as the battery pole plate were welded using the laser. The lab joint welding was conducted on ten pure Ni plates at a laser power of 1900 W and a feed speed of 2.8-3.4 m/min. As observed in the experiment, a faster feed speed reduced the bead width, but the laser did not penetrate all ten specimen plates. In addition, pores were trapped when protective gas was used, but they were not trapped when the welding was conducted in atmospheric condition.

Modeling of Pore Coarsening in the Rim Region of High Burn-up UO2 Fuel

  • Xiao, Hongxing;Long, Chongsheng
    • Nuclear Engineering and Technology
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    • v.48 no.4
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    • pp.1002-1008
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    • 2016
  • An understanding of the coarsening process of the large fission gas pores in the high burn-up structure (HBS) of irradiated $UO_2$ fuel is very necessary for analyzing the safety and reliability of fuel rods in a reactor. A numerical model for the description of pore coarsening in the HBS based on the Ostwald ripening mechanism, which has successfully explained the coarsening process of precipitates in solids is developed. In this model, the fission gas atoms are treated as the special precipitates in the irradiated $UO_2$ fuel matrix. The calculated results indicate that the significant pore coarsening and mean pore density decrease in the HBS occur upon surpassing a local burn-up of 100 GWd/tM. The capability of this model is successfully validated against irradiation experiments of $UO_2$ fuel, in which the average pore radius, pore density, and porosity are directly measured as functions of local burn-up. Comparisons with experimental data show that, when the local burn-up exceeds 100 GWd/tM, the calculated results agree well with the measured data.

Pore Properties of Magnesium Oxide Matrix using Red Mud and Vermiculite (버미큘라이트 및 레드머드를 활용한 산화마그네슘 경화체의 공극 특성)

  • Lim, Hyun-Ung;Lee, Won-Gyu;Lee, Sang-Soo;Song, Ha-Young
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2018.11a
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    • pp.120-121
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    • 2018
  • Radon is one of the substances that pollute the indoor air and is classified as a first-level carcinogen by the International Agency for Research on Cancer(IARC) together with asbestos, and it is reported that it can cause lung cancer. The World Health Organization(WHO) reports that lung cancer is the second leading cause of lung cancer, and 6-15% of lung cancer patients report lung cancer caused by radon. Radon occurs in cracks in concrete and aged buildings, and is detected in soil, rocks, groundwater, and so on. It is a colorless, odorless and tasteless gas which is adsorbed to dust in the air and enters through human respiratory system. This study used vermiculite (expanded vermiculite), which has excellent ion exchange ability and a large number of pores, and industrial by - product red mud which has heavy metal adsorption ability, in order to adsorb radon. A matrix capable of adsorbing radon was prepared, and the characteristics of each material were compared and analyzed.

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Effect of Alumina Content on the Hot Corrosion of SiC by NaCl and Na2SO4 (NaCl과 Na$_2$SO$_4$에 의한 SiC 고온 부식에 미치는 Alumina 첨가량의 영향)

  • 이수영;고재웅;김해두
    • Journal of the Korean Ceramic Society
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    • v.28 no.8
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    • pp.626-634
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    • 1991
  • The specimens for the corrosion test were made by hot-pressing of SiC power with 2 wt% Nl2O3 and 10wt% Al2O3 additions at 200$0^{\circ}C$ and 205$0^{\circ}C$. The specimens were corroded in 37 mole% NaCl and 63 mole% Na2SO4 salt mixture at 100$0^{\circ}C$ up to 60 min. SiO2 layer was formed on SiC and then this oxide layer was dissolved by Na2O ion in the salt mixture. The rate of corrosion of the specimen containing 10 wt% Al2O3 was slower than that of the specimen containing 2 wt% Al2O3. This is due to the presence of continuous grain boundary phase in the specimen containing 10 wt% Al2O3. The oxidation of SiC produced gas bubbles at the SiC-SiO2 interface. The rate of corrosion follows a linear rate law up to 50 min. and then was accelerated. This acceleration is due to the disruption oxide layer by the gas evolution at SiC-SiO2 interface. Pitting corrosion has found at open pores and grain boundaries.

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Formation of YSZ Coatings Deposited by Suspension Vacuum Plasma Spraying (서스펜션 진공 플라즈마 용사법을 통한 YSZ 코팅의 형성)

  • Yoo, Yeon Woo;Byon, Eungsun
    • Journal of the Korean institute of surface engineering
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    • v.50 no.6
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    • pp.460-464
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    • 2017
  • As increasing thermal efficiency of the gas turbine, the performance improvement of thermal barrier coatings is also becoming important. Ytrria stabilized zirconia(YSZ) is the most popular materials for ceramic top coating because of its low thermal conductivity. In order to enhance the performance of thermal barrier coatings for hot sections in the gas turbine, suspension plasma spraying was developed in order to feed nano-sized powders. YSZ coatings formed by suspension plasma spraying showed better performance than YSZ coatings due to its exclusive microstructure. In this research, two YSZ coatings were deposited by suspension vacuum plasma spraying at 400 mbar and 250 mbar. Microstructures of YSZ coatings were analyzed by scanning electron image(SEM) on each spraying conditions, respectively. Crystalline structure transformation was not detected by X-ray diffraction. Thermal conductivity of suspension vacuum plasma sprayed YSZ coatings were measured by laser flash analysis. Thermal conductivity of suspension vacuum plasma sprayed YSZ coatings containing horizontally oriented nano-sized pores and vertical cracks showed $0.6-1.0W/m{\cdot}K$, similar to thermal conductivity of YSZ coatings formed by atmospheric plasma spraying.

Odor Removal by Using Compost and Granular Scrap Tires (퇴비 및 폐타이어 Granule을 이용한 악취 제거)

  • Chung, Yoon-Jin
    • Journal of Korean Society of Water and Wastewater
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    • v.13 no.1
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    • pp.43-50
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    • 1999
  • In spite of low energy requirement, and operation and construction cost, biofilters with soil beds have not been operated efficiently. Because of excess moisture in winter and rainy periods, saturated pores in the bed prevent passage and sorption of odorous compounds. Sometimes this results in septic conditions that release previously sorbed and oxidized sulfur. Therefore, an economical and effective alternative needs to be developed. The objectives of this study were to confirm applicability of the granular scrap tires with compost for treating odorous gas as well as to obtain optimum design parameters for proposed system. In lab-scaled test, multiple stage reactors had lower headloss than a single stage reactor and less headloss was occurred for the gas with higher moisture content. For practical purpose, pilot-scaled reactor was operated to remove odor from septic tank, manure and animal wastewater treatment plant and composting machine. According to the results of pilot scaled test, $H_2S$ can be always removed completely and ammonia/amine can be removed excellently when proper moisture content is provided. The results from lab and pilot test showed that granular scrap tire could be replaced with soil as supporting material for biofilter showed excellent drainage because of its ability to reject moisture.

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Development and Evaluation of the Characteristics of Porous Materials for a Mold (금형 소재용 다공질 재료의 개발과 특성 평가)

  • 박선준;정성일;임용관;정해도;이석우;최헌종
    • Journal of the Korean Society for Precision Engineering
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    • v.21 no.6
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    • pp.35-42
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    • 2004
  • At the large-sized mold fer injection molding, the remaining gas in the mold causes some problems with final products. In order to solve these problems, air-bent was drilled on the surface of mold. However, this method leaves the scar on the surface of a product. Therefore, porous material was developed to the removal of remaining gas in this study. Porcerax II, which is a commercialized porous material, were developed in USA. It requires the electric discharge machining(EDM) process to make pores on the surface of the materials. The electric discharge machining (EDM) process, however, cause the increase of the time and cost for the fabrication of the mold. In this study, high speed machining(HSM) process was applied to the fabrication of porous mold without electric discharge machining(EDM) process. Some characteristics of the developed materials machined by high speed machining(HSM) and electric discharge machining(EDM) including air-permeability and porosity were compared with those of Porcerax II. Besides, in order to be applied to the molding process, hardness and tensile & yield strength were compared between Porcerax II and developed materials.

Selective Laser Sintering of Co-Cr Alloy Powders and Sintered Products Properties

  • Dong-Wan Lee;Minh-Thuyet Nguyen;Jin-Chun Kim
    • Journal of Powder Materials
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    • v.30 no.1
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    • pp.7-12
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    • 2023
  • Metal-additive manufacturing techniques, such as selective laser sintering (SLS), are increasingly utilized for new biomaterials, such as cobalt-chrome (Co-Cr). In this study, Co-Cr gas-atomized powders are used as charge materials for the SLS process. The aim is to understand the consolidation of Co-Cr alloy powder and characterization of samples sintered using SLS under various conditions. The results clearly suggest that besides the matrix phase, the second phase, which is attributed to pores and oxidation particles, is observed in the sintered specimens. The as-built samples exhibit completely different microstructural features compared with the casting or wrought products reported in the literature. The microstructure reveals melt pools, which represent the characteristics of the scanning direction, in particular, or of the SLS conditions, in general. It also exposes extremely fine grain sizes inside the melt pools, resulting in an enhancement in the hardness of the as-built products. Thus, the hardness values of the samples prepared by SLS under all parameter conditions used in this study are evidently higher than those of the casting products.

Gas Permeation of SiC Membrane Coated on Multilayer γ-Al2O3 with a Graded Structure for H2 Separation

  • Yoon, Mi-Young;Kim, Eun-Yi;Kim, Young-Hee;Whang, Chin-Myung
    • Korean Journal of Materials Research
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    • v.20 no.9
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    • pp.451-456
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    • 2010
  • A promising candidate material for a $H_2$ permeable membrane is SiC due to its many unique properties. A hydrogen-selective SiC membrane was successfully fabricated on the outer surface of an intermediate multilayer $\gamma-Al_2O_3$ with a graded structure. The $\gamma-Al_2O_3$ multilayer was formed on top of a macroporous $\alpha-Al_2O_3$ support by consecutively dipping into a set of successive solutions containing boehmite sols of different particle sizes and then calcining. The boehmite sols were prepared from an aluminum isopropoxide precursor and heated to $80^{\circ}C$ with high speed stirring for 24 hrs to hydrolyze the precursor. Then the solutions were refluxed at $92^{\circ}C$ for 20 hrs to form a boehmite precipitate. The particle size of the boehmite sols was controlled according to various experimental parameters, such as acid types and acid concentrations. The topmost SiC layer was formed on top of the intermediate $\gamma-Al_2O_3$ by pyrolysis of a SiC precursor, polycarbosilane, in an Ar atmosphere. The resulting amorphous SiC-on-$Al_2O_3$ composite membrane pyrolyzed at $900^{\circ}C$ possessed a high $H_2$ permeability of $3.61\times10^{-7}$ $mol{\cdot}m^{-2}{\cdot}s^{-1}{\cdot}Pa^{-1}$ and the $H_2/CO_2$ selectivity was much higher than the theoretical value of 4.69 in all permeation temperature ranges. Gas permeabilities through a SiC membrane are affected by Knudsen diffusion and a surface diffusion mechanism, which are based on the molecular weight of gas species and movement of adsorbed gas molecules on the surface of the pores.