• 한국신재생에너지학회:학술대회논문집
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• 2008.10a
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• pp.192-195
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• 2008

Conventional gas deposits consist of pressurized gas held in porous and permeable reservoir rocks and its recovery takes place where the natural pressure of the gas reservoir forces gas to the surface. But gas hydrate is a crystalline solid, its prospects require reservoir rock properties approprate porosity, permeability with mapping of temperature and pressure conditions to define the hydrate stability zone. In this study, we have carried out to investigate the dissociation characteristics of methane hydrates and the productivities of dissociated gas and water with depressurization scheme. Also, it has been conducted the flowing behavior of the dissociated gas and water in porous rock and the efficiency of the production.

• 한국신재생에너지학회:학술대회논문집
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• 2007.06a
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• pp.515-518
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• 2007

Gas hydrates are ice-like crystalline compounds that form under low temperature and elevated pressure conditions. Recently, gas hydrates present a novel means for natural gas storage and transportation with potential applications in a wide variety of areas. An important property of hydrates that makes them attractive for use in gas storage and transportation is their very high gas-to-sol id ratio. In addition to the high gas content, gas hydrates are remarkably stable. The main barrier to development of gas hydrate technology is the lack of an effective mass production method of gas hydrate in solid form. In this study, some performance comparison among several cases classified by different volume sizes of solution were carried to identify the characteristics due to the volume increment. And it is found that one of the main reasons disturbing hydrate formation is related to the lack of cooling heat transfer due to the volume increase of the solution. So, three kinds of heat transfer plates which have different shapes and cross sectional areas were made and tested for the performance comparison following to the shape and area of each plate. Finally it is clarified that the heat transfer is one of the major factors effecting hydrate formation performance and the installation of heat transfer plate can enhance the formation performance especially not in terms of the quantity but the speed.

• 한국신재생에너지학회:학술대회논문집
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• 2006.06a
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• pp.386-386
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• 2006

• Journal of the Korean Solar Energy Society
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• v.29 no.4
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• pp.34-40
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• 2009

$1m^3$ hydrate of pure methane can be decomposed to the maximum of $216m^3$ methane at standard condition. If these characteristics of hydrate are reversely utilized, natural gas is fixed into water in the form of hydrate solid. Therefore, the hydrate is considered to be a great way to transport and store natural gas in large quantity. Especially the transportation cost is known to be 18-24% less than the liquefied transportation. In the present investigation, experiments and theoretical calculation carried out for the formation of methane hydrate in NaCl 3.5wt% solution. The results show that the equilibrium pressure in seawater is more higher than that in pure water, and methane hydrate could be formed rapidly during pressurization if the subcooling is maintained at 9K or above in seawater and 8K or above in pure water, respectively. Also, amount of consumed gas volume in pure water is more higher that in seawater at the same experimental conditions. Therefore, it is found that NaCl acts as a inhibitor.

• The Journal of the Acoustical Society of Korea
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• v.28 no.5
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• pp.424-431
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• 2009

This study investigates the difference of sound velocity (compressional wave velocity) between gas hydrate-bearing sediments and nongas hydrate-bearing sediments in the Ulleung Basin, East Sea. We use a dataset measured from one site in the central part of the Ulleung Basin. Sound velocity for gas hydrate-bearing sediment shows the range from 1600 m/s to 2200 m/s. However, the value for nongas hydrate-bearing sediment is mostly around 1500 m/s, being less than 1400 m/s below 140 m subbottom depth. This trend is probably due to the presence of free gas below BSR (Bottom Simulating Reflector). Gas hydrate-bearing sediments show high value (maximum 150 Ohm-m) of resistivity. The physical properties between gas hydrate-bearing sediment and nongas hydrate-bearing sediment are characterized by the different patterns due to the presence of gas hydrate in comparison with those of marine unconsolidated sediments. Therefore, in order to investigate acoustic and physical properties for gas hydrate-bearing sediments, the study for the occurrence type and the amount of gas hydrates should be conducted simultaneously.

• Journal of the Korean Solar Energy Society
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• v.26 no.2
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• pp.19-25
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• 2006

Methane hydrate, non-polluting new energy resource, satisfies requirement and considered as a precious resource that can prevent the global warming. Fortunately, there are abundant resources of methane hydrate distribute in the earth widely. Therefore, developing the techniques that can utilize these gases effectively is highly desired. The work in this paper here is to develop a skill which can transport and store methane hydrate. As a first step, the equilibrium experiment was carried out by increasing temperatures in the cell at fixed pressures. The influence of gas consumption rates under variable degree of subcooling, stirring and water injection has been investigated formation to clarify kinetic characteristics of the hydrate. The results of present investigation showed that the enhancements of the hydrate formation in terms of the gas/water ratio are closely related to operational pressure, temperature, degrees of subcooling, and water injection.

• Economic and Environmental Geology
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• v.38 no.2 s.171
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• pp.165-176
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• 2005

Natural gas in deep sediment may occur in three phases based on the physical and chemical conditions. If the concentration of gas in pore water is less than the solubility, gas is dissolved. If the concentration of gas is greater than its solubility (water is saturated or supersaturated with gas), gas occurs as a fee gas below the gas hydrate stability Lone (GHSZ) and is present as solid hydrate within the GHSZ. The knowledge of gas concentration in deep sediment appears critical to determine the phase of natural gases and to understand the formation and distribution of gas hydrate. However, reliable data on gas concentration are usually available only from the upper section of marine sediment by the headspace gas technique, which is widely used for sampling of gases from the sediments. The headspace gas technique represents only a fraction of gases present in situ because sediments release most of the gases during recovery and sampling. The PCS (Pressure Core Sampler) is a downhole tool developed to recover a nominal $1{\cal}m$ long, $4.32{\cal}cm$ diameter core containing $1,465cm^3$ of sediment, pore water and gas at in situ pressure up to 68.9 MPa. During Leg 204, the PCS was deployed at 6 Sites. In situ methane gas concentration and distribution of gas hydrate was measured by using PCS tool. Characteristics of methane concentration and distribution is different from site to site. Distribution of gas hydrate in the study area is closely related to characteristics of in situ gas concentration measured by PCS.

• 한국신재생에너지학회:학술대회논문집
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• 2008.10a
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• pp.196-199
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• 2008

In this study, gas hydrate production has been followed using swapping method to investigate the effect of injection rate of flue gas and soaking period in unconsolidated artificial sand sample. The results shows that recovery factor of methane gas decreases with increasing the injection rate of flue gas. This indicates that the velocity of flue gas in porous media may act as kinds of inhibitor for production of hydrate. Also recovery factor increases with increasing the soaking time.

• Proceedings of the Korean Society of Marine Engineers Conference
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• 2005.11a
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• pp.156-157
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• 2005

Gas hydrate is ice-like crystalline lattice, formed at appropriate temperature and pressure, in which gas molecules are trapped. It is worldwide popular interesting subject as a potential energy. In korea, a seismic survey for gas hydrate have performed over the East sea by the KIGAM since 1997. In this paper, we had conducted numerical and physical modeling experiments for seismic properties on gas hydrate with field data which had been acquired over the East sea in 1998. We used a finite difference seismic method with staggered grid for 2-D elastic wave equation to generate synthetic seismograms from multi-channel surface seismic survey, OBC(Ocean Bottom Cable) and VSP(Vertical Seismic Profiling). We developed the seismic physical modeling system which is simulated in the deep sea conditions and acquired the physical model data to the various source-receiver geometry. We carried out seismic complex analysis with the obtained data. In numerical and physical modeling data, we observed the phase reversal phenomenon of reflection wave at interface between the gas hydrate and free gas. In seismic physical modeling, seismic properties of the modeling material agree with the seismic velocity estimated from the travel time of reflection events. We could easily find out AVO(Amplitude Versus Offset) in the reflection strength profile through seismic complex analysis.

• Journal of the Korean Institute of Gas
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• v.19 no.3
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• pp.54-59
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• 2015

The gas hydrate of 10 trillion tons are buried under continental slope in the world(permafrost : 2%, marine continental slope: 98%), but technology for the the commercial gas recovery has not developed yet. There are normally four representative recovery methods: depressurization method, thermal stimulation method, inhibition injection method, and displacement method. This study focuses on change of dissociation time and gas production according to gas hydrate saturation rate and depressurization rate. It was found that the correlation between depressrization rate and dissociation time was like as $Y=0.0004X^2-0.499X+176.86$. It was also found that the bigger depressurization rate is, the better production is(methane gas is produced over 46.2% at depressurization rate 50% compared with 40%). However, on the contrary to this, it is presumed that gas production is decreased at 60% due to gas hydrate reformation.