• Title/Summary/Keyword: Gas generation

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Case Study on Optimization of Send-out Operation in Liquefied Natural Gas Receiving Terminal (LNG 터미널 송출 운전 최적화 사례 연구)

  • Park, Chansaem;Han, Chonghun
    • Korean Chemical Engineering Research
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    • v.53 no.2
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    • pp.150-155
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    • 2015
  • Recently, LNG receiving terminals have been widely constructed and expanded for an increase in LNG demand. Selection of the storage tank for send-out and estimation of send-out flow rate have significant influence to process operation and economics. In this study, a send-out flow rate of each storage tank is optimized in order to minimize the total BOG generation rate. Considering a size and characteristic of each storage tanks, BOG flow rates are estimated using a dynamic simulation with varying liquid levels in the tanks. The regression model is developed fitting BOG flow rates and tank liquid levels, which are boil off rate model to predict BOG flow rates with particular level data. The objective function and constraints including required total send-out flow rate and level limit in the tanks are formulated to optimize a send-out flow rate of each tank. This method for optimization of send-out operation is applied to the Incheon LNG receiving terminal considering two scenarios for various liquid levels and maximum and minimum required send-out flow rates. For maximum required send-out flow rate, this method achieves BOG reduction of 9% comparing with assumed conventional operation.

Effects of dietary forage-to-concentrate ratio on nutrient digestibility and enteric methane production in growing goats (Capra hircus hircus) and Sika deer (Cervus nippon hortulorum)

  • Na, Youngjun;Li, Dong Hua;Lee, Sang Rak
    • Asian-Australasian Journal of Animal Sciences
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    • v.30 no.7
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    • pp.967-972
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    • 2017
  • Objective: Two experiments were conducted to determine the effects of forage-to-concentrate (F:C) ratio on the nutrient digestibility and enteric methane ($CH_4$) emission in growing goats and Sika deer. Methods: Three male growing goats (body weight $[BW]=19.0{\pm}0.7kg$) and three male growing deer ($BW=19.3{\pm}1.2kg$) were respectively allotted to a $3{\times}3$ Latin square design with an adaptation period of 7 d and a data collection period of 3 d. Respiration-metabolism chambers were used for measuring the enteric $CH_4$ emission. Treatments of low (25:75), moderate (50:50), and high (73:27) F:C ratios were given to both goats and Sika deer. Results: Dry matter (DM) and organic matter (OM) digestibility decreased linearly with increasing F:C ratio in both goats and Sika deer. In both goats and Sika deer, the $CH_4$ emissions expressed as g/d, g/kg $BW^{0.75}$, % of gross energy intake, g/kg DM intake (DMI), and g/kg OM intake (OMI) decreased linearly as the F:C ratio increased, however, the $CH_4$ emissions expressed as g/kg digested DMI and OMI were not affected by the F:C ratio. Eight equations were derived for predicting the enteric $CH_4$ emission from goats and Sika deer. For goat, equation 1 was found to be of the highest accuracy: $CH_4(g/d)=3.36+4.71{\times}DMI(kg/d)-0.0036{\times}neutral$ detergent fiber concentrate (NDFC,g/kg)+$0.01563{\times}dry$ matter digestibility (DMD,g/kg)-$0.0108{\times}neutral$ detergent fiber digestibility (NDFD, g/kg). For Sika deer, equation 5 was found to be of the highest accuracy: $CH_4(g/d)=66.3+27.7{\times}DMI(kg/d)-5.91{\times}NDFC(g/kg)-7.11{\times}DMD(g/kg)+0.0809{\times}NDFD(g/kg)$. Conclusion: Digested nutrient intake could be considered when determining the $CH_4$ generation factor in goats and Sika deer. Finally, the enteric $CH_4$ prediction model for goats and Sika deer were estimated.

Stimulated Raman scattering at 1.54${\mu}m$ and Brillouin scattering at 1.06${\mu}m$ in $CH_4$ under 5 Hz repetition rate (반복률과 라만매질 압력에 따른 1.54 ${\mu}m$ 전방, 후방 유도라만 및 1.06${\mu}m$ Brillouin 산란광의 출력특성)

  • 최영수;전용근;김재기
    • Korean Journal of Optics and Photonics
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    • v.10 no.2
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    • pp.95-101
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    • 1999
  • We have studied the 1.54$\mu\textrm{m}$ forward and backward stimulated Raman scattering (SRS) and stimulated Brillouin scattering (SRS) for various $CH_4$pressures by 1.06$\mu\textrm{m}$ Q-switched Nd:YAG laser pumping under a repetition rate of Hz in single pass. We obtained that the output of backward SRS was more efficient than that of the forward SRS. The output energy and conversion efficiency of forward and backward SRS were higher than those of SBS since SRS is a steady state, but SBS is a transient state. In a $CH_4$gas uncirculating system, the output energy of the backward SRS and SBS were reduced the about 47% due to a thermal heating of $CH_4$medium in a focusing region for a repetition rate of 5 Hz. But, the output energy of forward SRS was slightly enhanced by about 8.5% due to the increase of the undepleted pump beam in the backward SRS generation. Inthe Raman half resonator using a dichromatic focusing lens, the conversion efficiency of SRS was more than 37% for a input pump laser energy of 40 mJ.

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Quality Characteristics of Muffins using Ethanol Fermentation By-product of Triticale (라이밀의 에탄올 생산 후 발효 부산물을 이용한 머핀의 품질 특성)

  • Seo, Eun-Ok;Ko, Seong-Hye;Lee, Nae-Taek;Kim, Kwang-Oh;Choi, Gi-Wook;Oh, Kyung-Chul
    • Journal of the East Asian Society of Dietary Life
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    • v.20 no.3
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    • pp.382-388
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    • 2010
  • This study was aimed to examine the quality characteristics of the bread with the muffin added with the by-product of fermented ethanol from wheat rye that has high $\beta$-glucan contents. In the muffin added with TEFB (Triticale Ethanol Fermentation By-product), the height of the muffin decreased as the additive contents increased. There was no significant difference among the volumes of the muffins added with TEFB 0%, 5%, 10% and 15%. In the muffin added with TEFB, the height of the muffin decreased as the additive contents increased. In the moisture measurement of TEFB muffin, the moisture contents increased as the TEFB additive contents increased. Using SEM, showed that as TEFB additive contents increased, gluten contents was relatively lowered, which led to the reduced gas retention power and generation of rough tissues. In chromaticity, as the TEFB additive contents increased, the brightness decreased and the redness and yellowness decreased as well. The result of texture measurement showed that as the TEFB additive contents increased, hardness increased. springiness decreased gradually as the TEFB additive contents increased. There was no significant difference in cohesiveness (p<0.005). Although there as signigicant difference between the control group and the additive group in gumminess (p<0.005), there was no significant difference for a certain amount of additive contents (p<0.05). While there was significant difference in chewiness between the control group and the additive group (p<0.05). there was no significant difference for a certain amount of additive contents (p<0.05). The result of taste test of TEFB added muffin showed that the preference for the muffins added with 5% or more TEFB decreased. This study found that more than 5% of TEFB additives to muffin decreases the preference level.

Generation of Femtosecond Pulses in a Passively Mode-Locked 100 MHz Cr4+:YAG Laser (수동 모드 잠금된 100 MHz Cr4+:YAG 레이저에서의 펨토초 펄스 발생)

  • Cho, Won-Bae;Rotermund Fabian;Kim, Jong-Doo;Jeon, Min-Yong;Suh, Ho-Suhng
    • Korean Journal of Optics and Photonics
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    • v.16 no.6
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    • pp.535-541
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    • 2005
  • We report on the development of a passively mode-locked near-infrared femtosecond laser with Cr:YAG crystal that operates near room temperature. The laser wavelength could easily be tuned by using only the internal prism pair over 110 nm from 1400 nm to 1510 nm in cw and over about 30 nm in mode-locked operation, respectively Maximum cw output powers of 810 mW were obtained with $1.5 \%$ output coupler for absorbed pump powers of 7.6 W. For compensation of the internal group velocity dispersion, an IR graded prism pair was used. The Cr:YAG laser delivered nearly Fourier-transform limited pulses with a pulse duration as short as 64 fs at 100 MHz repetition rate. In the mode-locked regime, the laser was operating at 1510 nm with a spectral bandwidth of 44 nm. In order to avoid unstable mode-locking and power instabilities, self-built tubes were inserted into the beam path in the resonator and purged with N2 gas. Finally, output powers of the Cr:YAG laser were optimized to 250 mW fer long time stable mode-locked operation.

New Smoke Risk Assessment on Wood Treated with Silicone Compound (실리콘 화합물로 처리된 목재의 새로운 연기위험성 평가)

  • Chung, Yeong-Jin;Jin, Eui
    • Fire Science and Engineering
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    • v.33 no.4
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    • pp.16-27
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    • 2019
  • A burning test was conducted on the smoke and combustion gases generated from cypress wood treated with sodium silicate, 3-aminopropyltrimethoxysilane sol, 3-(2-aminoethylamino)propylmethyldimethoxysilane sol, and 3-(2-aminoethylamino) propyltrimethoxysilane sol. The silicone compound sol was applied to each of the cypress wood specimens three times with a brush. The smoke and combustion generation gas were analyzed using a cone calorimeter (ISO 5660-1) and the smoke was also evaluated by applying new smoke risk assessment method. The smoke performance index (SPI) of the cypress treated with silicone compound increased 1.66 to 8.42 times and the smoke growth index (SGI) was 11.8 to 88.2%, respectively. The smoke intensity (SI) is expected to be 1.0~50.5% lower than that of the base specimens, resulting in lower smoke and fire hazards. The third maximum carbon monoxide (COpeak) concentration of the specimens treated with silicone compounds was 22.5~33.3% lower than that of the base specimens. On the other hand, it produced potentially fatal toxicity that was 1.48~1.72 times higher than the US Occupational Safety and Health Administration (OSHA) acceptance standard (PEL). Cypress wood itself produced a high carbon monoxide concentration, but the silicon compound played a role in reducing this level.

Life Cycle Assessment of Part Reuse/Recycling in the End-of-Life Stage of Personal Computers (부품 재사용 여부에 따른 폐컴퓨터에 대한 전과정평가(LCA))

  • Lim, Hyeong-Soon;Yang, Yun-Hee;Song, Jun-Il;Lee, Kun-Mo
    • Journal of Korean Society of Environmental Engineers
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    • v.28 no.5
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    • pp.494-500
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    • 2006
  • Life Cycle Assessment(LCA) is an environmental assessment tool for evaluating environmental burdens associated with products, processes and activities from the raw material acquisition stage to the end-of-life stage. End-of-life stage as well as other processes requires a reliant database in order to increase the confidence in the LCA results. In this study, the flow of Personal Computer(as PC) in the end-of-life stage was examined and the database of two scenarios has been established, i.e. one is part reuse and the other is no part reuse, in the end-of-life phase of PC. Also, key environmental issues were identified by carrying out LCA on a PC in the end-of-life phase for eight environmental impact categories. The 'ozone layer depletion' contributes the highest environmental impact due to generation of $Cl_2$ gas during the incineration of waste plastics. In addition, the scenario 1(part reuse) is more environmentally sound than the scenario 2(no part reuse) when comparing two scenarios.

The analysis of Change on Property and CO2 Emission Factor of Domestic Transportation Fuel from 2012 to 2015 (2012 ~ 2015년 국내 수송용 연료의 물성 및 CO2 배출계수의 변화추이 분석연구)

  • Kang, Hyungkyu;Doe, Jinwoo;Lim, Wanguy;Hwang, Inha;Ha, Jonghan;Na, Byungki
    • Journal of the Korean Applied Science and Technology
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    • v.33 no.4
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    • pp.855-863
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    • 2016
  • Most greenhouse gases were arisen from the generation and use of energy, more than about 95 % of greenhouse gas from the traffic section was resulted by the transportation fuels. Also, when using the $CO_2$ emission factor suggested at IPCC G/L, there was the weakness which did not reflect the own property of fuel by country. And most industrialized countries have applied with the $CO_2$ emission factor of Tier 2 or Tier 3 to make the national greenhouse report to submit to UN according to the Kyoto Protocol. In this study, the transportation fuels using in domestic like unleaded gasoline, diesel, etc were analysed to identify the physical/chemical properties and these data were used to calculate the $CO_2$ emission factor of each fuels. And the study analysed the time series analysis to compare the property of fuels according to the change of time.

Distribution of Abused Drugs in 275 Alcohol-positive Blood Samples of Korean Driver (음주운전자 275명 혈액 중 마약류 및 남용약물의 분석)

  • Choi, Hye-Young;Lee, Ju-Seon;Choi, Sang-Kil;Kim, Eun-Mi;Kim, Jae-Kyun;Kim, Young-Woon;Lim, Mi-Ae;Chung, Hee-Sun
    • YAKHAK HOEJI
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    • v.52 no.2
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    • pp.137-146
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    • 2008
  • Even though driving under the influence of drug (DUID) is a worldwide problem, we, Korea has no regulation system yet except for alcohol, and there are little cases reported related to DUID. In order to investigate the type of abused drugs for drivers in Korea, we tried to analyze controlled and non-controlled drugs in alcohol-positive blood samples. 275 whole bloods, which were positive for alcohol on the roadside test, were collected from the police for two months ($Nov.{\sim}Dec.$ 2006). The analytical strategy was constituted of three steps: First, alcohol in blood samples were confirmed and quantified by gas chromatography. Second, controlled drugs were screened by $Evidence_{investigator}\;^{TM}$ (Randox, U.K.) as preliminary test. It was based on immunoassay by biochip array analyzer. Nine groups of drug abuse were screened: amphetamines, methamphetamines, cannabis, cocaine, opiates, barbiturates, methadone, benzodiazepines I (oxazepam) & II (lorazepam). Finally, confirmation of these drugs was performed by GC-MS. Blood samples were extracted by solid-phase extraction by $RapidTrace^{TM}$ (Zymark, U.S.A.). After trimethylsilyl (TMS) derivatization, eluates were analyzed to GC-MS. Total 49 drugs were investigated in this study including controlled drugs, antidepressants, 1st generation antihistamines, dextromethorphan, nalbuphine, ketamine, etc. For rapid detection, we developed the automated identification system. It was made up a new software, "DrugMan", modified Chemstation data analysis menu and newly developed macro modules. A series of peak selection, identification and reporting of the results were performed automatically by this system. Concentrations of alcohol in 275 blood samples were ranged from 0.011 to 0.249% (average, 0.119%). Among 149 blood samples, just six samples (4.0%) were showed positive results to the immunoassay: one methamphetamine and five benzodiazepines group I. By GC-MS confirmation, only benzodiazepines were detected and methamphetamine was not detected from immunoassay positive blood sample. Besides these drugs, 5 chlorpheniramines, dextromethorphan, diazepam, doxylamine, ibuprofen, lidocaine and topiramate were also detected in whole bloods by GC-MS. Conclusively, the frequency of drug abuse for Korean drivers was relatively low. There was none case which illegal drug was detected. However these results were limited to alcohol positive blood samples, so it is necessary to analyze more samples including alcohol negative blood.

Laser Acceleration of Electron Beams to the GeV-class Energies in Gas Jets

  • Hafz, Nasr A.M.;Jeong, Tae-Moon;Lee, Seong-Ku;Choi, Il-Woo;Pae, Ki-Hong;Kulagin, Victor V.;Sung, Jae-Hee;Yu, Tae-Jun;Cary, John R.;Ko, Do-Kyeong;Lee, Jong-Min
    • Journal of the Optical Society of Korea
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    • v.13 no.1
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    • pp.8-14
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    • 2009
  • In a laser-plasma wakefield accelerator, the ponderomotive force of an ultrashort high intensity laser pulse excites a longitudinal wave or plasma bubble in a way similar to the excitation of a wake wave behind a boat as it propagates on the water surface. Electric fields inside the plasma bubble can be several orders of magnitude higher than those available in conventional RF-based particle accelerator facilities which are limited by material breakdown. Therefore, if an electron bunch is properly phase-locked with the bubble's acceleration field, it can gain relativistic energies within an extremely short distance. Here, in the bubble regime we show the generation of stable and reproducible sub GeV, and GeV-class electron beams. Supported by three-dimensional particle-in-cell simulations, our experimental results show the highest acceleration gradients produced so far. Simulations suggested that the plasma bubble elongation should be minimized in order to achieve higher electron beam energies.