• 제목/요약/키워드: Gas generation

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연소 불안정 예측을 위한 열음향 해석 모델 - Part 2 : 비선형 안정성 해석 (Thermoacoustic Analysis Model for Combustion Instability Prediction - Part 2 : Nonlinear Instability Analysis)

  • 김대식;김규태
    • 한국추진공학회지
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    • 제16권6호
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    • pp.41-47
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    • 2012
  • 연소 불안정 현상을 완전하게 이해하기 위해서는 천이 과정과 한계 진폭과 같은 비선형 거동에 대한 예측이 매우 중요하다. 가스터빈 희박 예혼합 연소기에서 이러한 비선형 거동은 화염의 비선형 동특성에 크게 의존하게 된다. 본 연구에서는 기존에 선형 해석으로부터 비선형 열음향 해석으로 확장하기 위해서 화염 묘사 함수를 통한 시스템 안정성 해석 기법이 소개되었다. 이를 위하여, 주파수 뿐만 아니라 속도 진폭에 따른 열발생율의 변동 특성이 실험 결과로부터 모델링되었다. 현재 해석 조건에서 비선형 모델링 결과, 주어진 연소기 길이에서 속도 진폭이 불안정 주파수에 미치는 영향은 미비하였으나, 성장률에는 크게 영향을 미치는 것으로 나타났다. 향후 다양한 조건에서 비선형 모델의 검증과 한계 진폭의 예측 결과에 대한 실험 결과와의 비교가 요구된다.

유기 태양전지의 개발 현황과 기술 과제 (Technical Tasks and Development Current Status of Organic Solar Cells)

  • 장지근;박병민;임성규;장호정
    • 한국재료학회지
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    • 제24권8호
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    • pp.434-442
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    • 2014
  • Serious environmental problems have been caused by the greenhouse effect due to carbon dioxide($CO_2$) or nitrogen oxides($NO_x$) generated by the use of fossil fuels, including oil and liquefied natural gas. Many countries, including our own, the United States, those of the European Union and other developed countries around the world; have shown growing interest in clean energy, and have been concentrating on the development of new energy-saving materials and devices. Typical non-fossil-fuel sources include solar cells, wind power, tidal power, nuclear power, and fuel cells. In particular, organic solar cells(OSCs) have relatively low power-conversion efficiency(PCE) in comparison with inorganic(silicon) based solar cells, compound semiconductor solar cells and the CIGS [$Cu(In_{1-x}Ga_x)Se_2$] thin film solar cells. Recently, organic cell efficiencies greater than 10 % have been obtained by means of the development of new organic semiconducting materials, which feature improvements in crystalline properties, as well as in the quantum-dot nano-structure of the active layers. In this paper, a brief overview of solar cells in general is presented. In particular, the current development status of the next-generation OSCs including their operation principle, device-manufacturing processes, and improvements in the PCE are described.

XRD와 XPS를 사용한 산화아연 박막의 결함형성과 산소연관 결합사이의 상관성 (Correlation between Oxygen Related Bonds and Defects Formation in ZnO Thin Films by Using X-ray Diffraction and X-ray Photoelectron Spectroscopy)

  • 오데레사
    • 한국재료학회지
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    • 제23권10호
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    • pp.580-585
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    • 2013
  • To observe the formation of defects at the interface between an oxide semiconductor and $SiO_2$, ZnO was prepared on $SiO_2$ with various oxygen gas flow rates by RF magnetron sputtering deposition. The crystallinity of ZnO depends on the characteristic of the surface of the substrate. The crystallinity of ZnO on a Si wafer increased due to the activation of ionic interactions after an annealing process, whereas that of ZnO on $SiO_2$ changed due to the various types of defects which had formed as a result of the deposition conditions and the annealing process. To observe the chemical shift to understand of defect deformations at the interface between the ZnO and $SiO_2$, the O 1s electron spectra were convoluted into three sub-peaks by a Gaussian fitting. The O 1s electron spectra consisted of three peaks as metal oxygen (at 530.5 eV), $O^{2-}$ ions in an oxygen-deficient region (at 531.66 eV) and OH bonding (at 532.5 eV). In view of the crystallinity from the peak (103) in the XRD pattern, the metal oxygen increased with a decrease in the crystallinity. However, the low FWHM (full width at half maximum) at the (103) plane caused by the high crystallinity depended on the increment of the oxygen vacancies at 531.66 eV due to the generation of $O^{2-}$ ions in the oxygen-deficient region formed by thermal activation energy.

서스펜션 플라즈마 용사법으로 제조한 La2Zr2O7, (La0.5Gd0.5)2Zr2O7, Gd2Zr2O7 열차폐코팅의 상형성과 열전도 특성 (Phase Formation and Thermal Diffusivity of Thermal Barrier Coatings of La2Zr2O7, (La0.5Gd0.5)2Zr2O7, Gd2Zr2O7 Fabricated by Suspension Plasma Spray)

  • 김선주;이성민;오윤석;김형태;장병국;김성원
    • 한국표면공학회지
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    • 제49권6호
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    • pp.604-611
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    • 2016
  • In order to comply with demand for high efficient gas turbines operating at higher temperatures, considerable amounts of research efforts have been performed with searching for the next-generation thermal barrier coatings (TBCs) with respect to coating materials as well as processing methods. In this study, thermal barrier coatings in the $(La_{1-x}Gd_x)_2Zr_2O_7$ system, which is one of the most versatile materials replacing yttria-stabilized zirconia (YSZ), are fabricated by suspension plasma spray with suspension made of synthesized powders via solidstate reaction. Dense, $100{\sim}400{\mu}m$ thick coatings of fluorite-phase zirconate with moderate amount of segmented microstructures are obtained by using suspension plasma spray. Phase formation and thermal diffusivity are characterized with coating compositions. The feasibility of $(La_{1-x}Gd_x)_2Zr_2O_7$ coatings for TBC applications is also discussed.

Investigating the Relationship of Sustainability Factors with Project Management Success

  • Khalilzadeh, Mohammad;Akbari, Hassan;Foroughi, Amin
    • Industrial Engineering and Management Systems
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    • 제15권4호
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    • pp.345-353
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    • 2016
  • One of the main concerns of the present age, is attending to the issue of sustainability that in recent decades, the concept of it has grown in terms of recognition and importance. Sustainability have defined further the development of the welfare and living standards of the present generation, without the lives of future generations is at stake. One of these tasks of the business is project management and today, "green or sustainable project management" as one of the most important global trends of project management have been identified. The issue of present study was to investigate the relationship of sustainability factors with success of a project. The population of the research consists of directors of oil and gas in the South Pars region including 150 people that according to Cochran formula, the number of samples were obtained 108 people. In this study, data collection was conducted based on a structured questionnaire that from a sample set of questions was used for sustainability impact on 6 scale of project management success. For this purpose, the whole five-item Likert has been used. Also for statistical analysis, PLS software was used. The results of path analysis at confidence level of 95%, showed a significant relationship exists between "sustainability factor" and "project success criteria." Since the correlation coefficient is positive, so this type of relationship is positive. Thus all the hypotheses at confidence level of 95 percent was confirmed and it became clear that there is a significant positive relationship between "sustainability factors" and "project success criteria."

해양환경하에서의 알루미늄 합금 선박용 재료의 기계적 특성과 전기화학적 특성 평가

  • 김성종;고재용;정석기;김정일
    • 해양환경안전학회:학술대회논문집
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    • 해양환경안전학회 2005년도 춘계학술발표회
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    • pp.161-165
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    • 2005
  • Recently, it is on the increase interest for Al alloy with new material for ship application to substitute for FRP ship. The reason is thatAl alloy ship has beneficial characteristics such as high sea speed, increase of loadage and easy to recycle compared with FRP ship. In this paper, mechanical and electrochemical properties are investigated by slow strain rate test experiment in various applied potential condition. These results will provide as reference data to design ship by deciding optimum protection potential regard to hydrogen embrittlement and stress corrosion cracking. In general, Al and Al alloys are not corroded with forming film which has the corrosion resistance property in neutral solution. However, it was observed that formation and destruction of passive film by $Cl^-$ ion in sea water environment. At comparison of current density after 1200 sec in potentiostatic experiment, the current density in the potential range of -0.68 $\~$-1.5 V is shown low value. The low current density means protection potential range. Elongation in applied potential of 0 V was high. However, the corrosion protection application in this condition is impossible potential because the toughness is low value by decreasing strength by active dissolution reaction at parallel part of specimen. The film composed with $CaCO_3$ and $Mg(OH)_2$ has a corrosion resistance property. However, the uniform electrodeposition coating at below -1.6 V potential is not formed since the time to form the uniform electrodeposition coating is short. Therefore, it is concluded that mechanical property is poor because effect by hydrogen gas generation is larger than that of electrodeposition coating. It is concluded that the optimum protection potential range from comparison of_maxim urn tensile strength, elongation and time to fracture is -1.3$\~$0.7 V (SSCE).

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5kW 급 MCFC 발전시스템 촉매연소기의 유동 및 연소 특성에 대한 수치적 연구 (A Numerical Study on the Internal Flow and Combustion Characteristics of the Catalytic Combustor for the 5kW MCFC Power system)

  • 김종민;이연화;김만영;김형곤;홍동진;조주형;김한석;안국영
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2008년도 추계학술대회B
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    • pp.3049-3052
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    • 2008
  • MCFC(molten carbonate fuel cell) power generation system is prime candidate for the utilization of fossil based fuels to generate ultra clean power with a high efficiency. In the MCFC power plant system, a combustor performs a role to supply high temperature mixture gases for cathode and heat for reformer by using the stack off-gas of the anode which includes a high concentration of $H_2O$ and $CO_2$. Since a combustor needs to be operated in a very lean condition and to avoid excessive local heating, catalytic combustor is usually used. The catalytic combustion is accomplished by the catalytic chemical reaction between fuel and oxidizer at catalyst surface, different from conventional combustion. In this study, a mathematical model for the prediction of internal flow and catalytic combustion characteristics in the catalytic combustor adopted in the MCFC power plant system is suggested by using the numerical methods. The numerical simulation models are then implemented into the commercial CFD code. After verifying result by comparing with the experimental data and calibrated kinetic parameters of catalytic combustion reaction, a numerical simulation is performed to investigate the variation of flow and combustion characteristics by changing such various parameters as inlet configuration and inlet temperature. The result show that the catalytic combustion can be effectively improved for most of the case by using the perforated plate and subsequent stable catalytic combustion is expected.

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A Study on CNN based Production Yield Prediction Algorithm for Increasing Process Efficiency of Biogas Plant

  • Shin, Jaekwon;Kim, Jintae;Lee, Beomhee;Lee, Junghoon;Lee, Jisung;Jeong, Seongyeob;Chang, Soonwoong
    • International journal of advanced smart convergence
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    • 제7권1호
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    • pp.42-47
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    • 2018
  • Recently, as the demand for limited resources continues to rise and problems of resource depletion rise worldwide, the importance of renewable energy is gradually increasing. In order to solve these problems, various methods such as energy conservation and alternative energy development have been suggested, and biogas, which can utilize the gas produced from biomass as fuel, is also receiving attention as the next generation of innovative renewable energy. New and renewable energy using biogas is an energy production method that is expected to be possible in large scale because it can supply energy with high efficiency in compliance with energy supply method of recycling conventional resources. In order to more efficiently produce and manage these biogas, a biogas plant has emerged. In recent years, a large number of biogas plants have been installed and operated in various locations. Organic wastes corresponding to biogas production resources in a biogas plant exist in a wide variety of types, and each of the incoming raw materials is processed in different processes. Because such a process is required, the case where the biogas plant process is inefficiently operated is continuously occurring, and the economic cost consumed for the operation of the biogas production relative to the generated biogas production is further increased. In order to solve such problems, various attempts such as process analysis and feedback based on the feedstock have been continued but it is a passive method and very limited to operate a medium/large scale biogas plant. In this paper, we propose "CNN-based production yield prediction algorithm for increasing process efficiency of biogas plant" for efficient operation of biogas plant process. Based on CNN-based production yield forecasting, which is one of the deep-leaning technologies, it enables mechanical analysis of the process operation process and provides a solution for optimal process operation due to process-related accumulated data analyzed by the automated process.

The interaction between helium flow within supersonic boundary layer and oblique shock waves

  • Kwak, Sang-Hyun;Iwahori, Yoshiki;Igarashi, Sakie;Obata, Sigeo
    • 한국추진공학회:학술대회논문집
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    • 한국추진공학회 2004년도 제22회 춘계학술대회논문집
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    • pp.75-78
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    • 2004
  • Various jet engines (Turbine engine family and RAM Jet engine) have been developed for high speed aircrafts. but their application to hypersonic flight is restricted by principle problems such as increase of total pressure loss and thermal stress. Therefore, the development of next generation propulsion system for hypersonic aircraft is a very important subject in the aerospace engineering field, SCRAM Jet engine based on a key technology, Supersonic Combustion. is supposed as the best choice for the hypersonic flight. Since Supersonic Combustion requires both rapid ignition and stable flame holding within supersonic air stream, much attention have to be given on the mixing state between air stream and fuel flow. However. the wider diffusion of fuel is expected with less total pressure loss in the supersonic air stream. So. in this study the direction of fuel injection is inclined 30 degree to downstream and the total pressure of jet is controlled for lower penetration height than thickness of boundary layer. Under these flow configuration both streams, fuel and supersonic air stream, would not mix enough. To spread fuel wider into supersonic air an aerodynamic force, baroclinic torque, is adopted. Baroclinic torque is generated by a spatial misalignment between pressure gradient (shock wave plane) and density gradient (mixing layer). A wedge is installed in downstream of injector orifice to induce an oblique shock. The schlieren optical visualization from side transparent wall and the total pressure measurement at exit cross section of combustor estimate how mixing is enhanced by the incidence of shock wave into supersonic boundary layer composed by fuel and air. In this study non-combustionable helium gas is injected with total pressure 0.66㎫ instead of flammable fuel to clarify mixing process. Mach number 1.8. total pressure O.5㎫, total temperature 288K are set up for supersonic air stream.

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환경개선을 위한 형광방전등형 오존발생기의 특성 (Characteristics of Fluorescent Discharge Lamp Type Ozonizer for Environment Improvement)

  • 박용권;이상근;전병준;송현직;이광식;하장호
    • 대한전기학회논문지:전기물성ㆍ응용부문C
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    • 제51권10호
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    • pp.500-505
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    • 2002
  • In this paper, fluorescent discharge type ozonizer has been designed and manufactured. Ozone discharge and generation characteristics have been investigated in accordance with a sort of internal electrodes, output voltage of power supply, air flow rate and discharge power. Air has been used as the supplied gas of the ozonizer In this paper, when disuse fluorescent lamp was used as an internal electrode. Air flow rate was varied from 2[1/min] to 10[1/min]. The maximum ozone concentration and yield were 3495[ppm] and 23.4[g/kWh] respectively at 2[1/min] air flow rate and 35.2[W] input power. Illumination was appeared as 5[lx] within 15[cm] from external electrode. Whorl fluorescent discharge type ozonizer was used, air flow rate was also varied from 2[1/min] to 10[1/min]. At this moment, the maximum ozone concentration and yield were 2824[ppm] and 21.7[g/kWh] respectively at 2[1/min] air flow rate and 30.5[W] input power. Illumination was also appeared as 5[lx] within 15[cm] from external electrode like used fluorescent lamp.