• 제목/요약/키워드: Gas exchange

검색결과 648건 처리시간 0.027초

미세다공층의 침투깊이가 다른 기체확산층이 고분자전해질 연료전지의 성능과 내구성에 미치는 영향에 관한 연구 (Study on Performance and Durability of the Proton Exchange Membrane Fuel Cell with Different Micro Porous Layer Penetration Thickness)

  • 조준현;박재만;오환영;민경덕;정지영;이은숙
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2011년도 추계학술대회 초록집
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    • pp.81.2-81.2
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    • 2011
  • The gas diffusion layer (GDL) consists of two main parts, the GDL backing layer, called as a substrate and the micro porous layer (MPL) coated on the GDBL. In this process, carbon particles of MPL penetrates to the GDBL consequently forms MPL penetration part. In this study, the micro porous layer (MPL) penetration thickness is determined as a design parameter of the GDL which affect pore size distribution profile through the GDL inducing different mass transfer characteristics. The pore size distribution and water permeability characteristics of the GDL are investigated and the cell performance is evaluated under fully/low humidification conditions. Transient response and voltage instability are also studied. In addition, to determine the effects of MPL penetration on the degradation, the carbon corrosion stress test is conducted. The GDL that have deep MPL penetration thickness shows better performance in high current density region because of enhanced water management, however, loss of penetrated MPL parts is shown after aging and it induces worse water management characteristics.

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Catalytic Biofilms on Structured Packing for the Production of Glycolic Acid

  • Li, Xuan Zhong;Hauer, Bernhard;Rosche, Bettina
    • Journal of Microbiology and Biotechnology
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    • 제23권2호
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    • pp.195-204
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    • 2013
  • While structured packing modules are known to be efficient for surface wetting and gas-liquid exchange in abiotic surface catalysis, this model study explores structured packing as a growth surface for catalytic biofilms. Microbial biofilms have been proposed as selfimmobilized and self-regenerating catalysts for the production of chemicals. A concern is that the complex and dynamic nature of biofilms may cause fluctuations in their catalytic performance over time or may affect process reproducibility. An aerated continuous trickle-bed biofilm reactor system was designed with a 3 L structured packing, liquid recycling and pH control. Pseudomonas diminuta established a biofilm on the stainless steel structured packing with a specific surface area of 500 $m^2m^{-3}$ and catalyzed the oxidation of ethylene glycol to glycolic acid for over two months of continuous operation. A steady-state productivity of up to 1.6 $gl^{-1}h^{-1}$ was achieved at a dilution rate of 0.33 $h^{-1}$. Process reproducibility between three independent runs was excellent, despite process interruptions and activity variations in cultures grown from biofilm effluent cells. The results demonstrate the robustness of a catalytic biofilm on structured packing, despite its dynamic nature. Implementation is recommended for whole-cell processes that require efficient gas-liquid exchange, catalyst retention for continuous operation, or improved catalyst stability.

PFT법에 의한 수직적 3 ZONE 분할 조건에서의 환기량 측정 (Ventilation Measurement with PFT in Three-storied Detached House)

  • 김훈
    • 설비공학논문집
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    • 제25권9호
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    • pp.506-515
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    • 2013
  • The PFT (PerFluorocarbon Tracergas Technique) is of advantage to field surveys for evaluating the ventilation condition, due to its simplicity and convenience. On the other hand, it requires researchers to make some additional considerations that include uncertainties, such as the substance concentration distribution in indoor air, representativeness of a sampler, deviation of emission sources, and analysis error. In this study, the PFT and $CO_2$ tracer gas methods were applied simultaneously, to evaluate the accuracy of PFT on six ventilation conditions in the three-storied detached house. The air exchange and the outdoor air introduction a between and into zones were measured. As the results, deviations of PFT concentration distributions were observed at a sufficiently low level for an accurate determination for a house where the interior height was large, and there were relatively many partition walls. However, when a uniform airflow appeared in the indoor air, it was also validated that the indoor air would be exhausted without sufficient mixing, and consequently the measurement error of the PFT would be large.

Current Sensing Atomic Force Microscopy를 이용한 PEM의 수화 현상에 따른 모폴로지 변화 연구 (Current Sensing Atomic Force Microscopy Study of the Morphological Variation of Hydrated Pronton Exchange Membrane)

  • 권오성;이상철;손병락;이동하
    • 한국태양에너지학회 논문집
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    • 제34권4호
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    • pp.9-16
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    • 2014
  • A proton exchange membrane is a core component in the proton exchange membrane fuel cell because the role of proton exchange membrane(PEM)is supplying proton conductivity to fuel cell, a gas separator, and insulating between an anode and cathode. Among various role of PEM, supplying proton conductivity is the most important and the proton conductivity is strongly related the structural evolution of PEM by hydration. Thus a lot of studies have done by past few decade based on small angle X-ray scattering and wide angle X-ray scattering for understanding morphological structure of the PEM. Resulting from these studies, several morphological models of hydrated PEM are proposed. Current sensing atomic force microscopy (CSAFM) can map morphology and conductance on the membrane simultaneously. It can be the best tool for studying heterogenous structured materials such as PEM. In this study, the hydration of the membrane is examined by using CSAFM. Conductance and morphological images are simultaneously mapped under different relative humidity. The conductance images, which are mapped from different relative humidity, are analyzed by statistical methode for understanding ionic channel variation in PEM.

딤플형 EGR 냉각기의 설계 및 성능평가 (Design and Performance Evaluation of Dimpled EGR Cooler)

  • 서영호;이현민;허성찬;구태완;송우진;강범수;김정
    • 대한기계학회논문집A
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    • 제34권3호
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    • pp.291-298
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    • 2010
  • 본 논문은 자동차 디젤엔진의 EGR 시스템에 사용되는 EGR 냉각기의 열교환 효율에 관한 것으로 배기가스의 냉각수 사이의 열교환을 촉진시키기 위한 방법으로 딤플형 EGR 냉각기를 설계 및 그 성능을 평가하였다. 개발초기 단계에서 딤플형 EGR 냉각기의 성능을 평가하기 위하여 기존 스파이럴 타입의 EGR 냉각기와 딤플형 EGR 냉각기의 전열면적을 비교하였으며, 균질화 기법을 이용한 유한요소해석을 통하여 딤플형 EGR 냉각기의 구조 건전성을 평가하였다. 또한, 딤플형 열교환 튜브의 생산공정-딤플성형, edge bending, center v-notch bending, 압착, 플라즈마 용접-을 체계화하였다. 최종적으로 본 연구를 통하여 딤플형 EGR 냉각기를 개발하였으며, 그 성능을 검증하였다.

음이온 교환막 알칼리 수전해를 위한 운전 조건 및 구성요소의 최적화 (Optimization of Operating Parameters and Components for Water Electrolysis Using Anion Exchange Membrane)

  • 장명제;원미소;이규환;최승목
    • 한국표면공학회지
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    • 제49권2호
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    • pp.159-165
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    • 2016
  • The hydrogen has been recognized as a clean, nonpolluting and unlimited energy source that can solve fossil fuel depletion and environmental pollution problems at the same time. Water electrolysis has been the most attractive technology in a way to produce hydrogen because it does not emit any pollutants compared to other method such as natural gas steam reforming and coal gasification etc. In order to improve efficiency and durability of the water electrolysis, comprehensive studies for highly active and stable electrocatalysts have been performed. The platinum group metal (PGM; Pt, Ru, Pd, Rh, etc.) electrocatalysts indicated a higher activity and stability compared with other transition metals in harsh condition such as acid solution. It is necessary to develop inexpensive non-noble metal catalysts such as transition metal oxides because the PGM catalysts is expensive materials with insufficient it's reserves. The optimization of operating parameter and the components is also important factor to develop an efficient water electrolysis cell. In this study, we optimized the operating parameter and components such as the type of AEM and density of gas diffusion layer (GDL) and the temperature/concentration of the electrolyte solution for the anion exchange membrane water electrolysis cell (AEMWEC) with the transition metal oxide alloy anode and cathode electrocatalysts. The maximum current density was $345.8mA/cm^2$ with parameter and component optimization.

이산화탄소를 이용한 온수급탕용 초월임계사이클의 성능에 대한 실험적 연구 (Experimental Studies on the Performance of a Transcritical Cycle for Hot Water Heating Using Carbon Dioxide)

  • 김성구;김민수
    • 설비공학논문집
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    • 제15권6호
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    • pp.461-470
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    • 2003
  • The purpose of this study is to investigate the performance of a transcritical cycle for hot water heating using $CO_2$ as a working fluid. Some of the main parameters that affect the practical performance of the $CO_2$ system are discussed; the performance on the variation of refrigerant charge, changes in flow conditions of secondary fluids, and that with or without internal heat exchanger, The experimental results show that the optimum charge is approximately the same for various mass flow rates of the secondary fluid at gas cooler. The experimental results on the effect of secondary fluids are in general agreement with the experimental results of transcritical cycle in the open literature and show similar trend for conventional subcritical vapor compression cycles. The heat exchanger effectiveness increases with an increase of the heat exchange area of the internal heat exchanger regardless of the mass flow rate at the gas cooler.

G.C를 이용한 Ventilation 측정방법과 Ventilation에서의 블라우스형태변화의 영향 (Method of Ventilation by Gas Chromatography and the Effects of the Type of Blouse)

  • 박우미;최철호
    • 한국의류학회지
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    • 제16권1호
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    • pp.53-63
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    • 1992
  • The purpose of this study is to investigate the method of trace gas technique by G.C and the effects of the type of blouse on ventilation. The experimental system employed a trace gas technique in which ventilation was monitored to determine oxigen exchange rate. The experimental variables were tested with three types of blouse depending on the sizes of neckline, armhole and waist line. Exercise conditions include standing and walking position. The results and discussion forcused on the construct validity of the apparatus/testing protocol. the effect of experimental variables on ventilation was also discussed.

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불꽃점화 반켈 로터리 기관의 성능 시뮬레이션 (A Performance Simulation for Spark Ignition Wankel Rotary Engine)

  • 채재우;이상만;전영남;김규정;정영식
    • 한국자동차공학회논문집
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    • 제1권1호
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    • pp.80-89
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    • 1993
  • Performance simulation for a Spark Ignition Wankel rotary Engine is presented in this paper. The volume of chamber at each eccentric shaft angle is evaluated by using geometric models of housing and rotor. A thermodynamic model which includes the first law of thermodynamics, combustion and convective heat transfer from chamber contents to surroundings is imployed. A thermochemical equilibrium model which considers 10 species(CO, $CO_2$, $O_2$, $H_2$, $H_2O$, OH, O, NO, $N_2$) in the burned gas region, is also employed. Four processes of gas exchange, compression, combustion and expansion are considered and the pressure, temperature and composition of chamber gas at each eccentric shaft angle in each process are computed in this performance simulation. This performance simulation must be useful for optimal design of Spark Ignition Wankel Rotray Engine with parametric study for various design parameters and operating conditions.

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고체-고체-기체 화학 열펌프 시스템의 반응기 설계에 관한 연구 (A Study on the Reactor Design of Solid-Solid-Gas Chemical Heat Pump System)

  • 김성준;이태희;;최홍규;이종호
    • 설비공학논문집
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    • 제6권4호
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    • pp.406-416
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    • 1994
  • In this study the reactor design procedure and method of solid-solid-gas chemical heat pump system using STELF technology were investigated. For manufacturing IMPEX block which is the kernel of reactor, proper salt pair should be selected, and equilibrium temperature drop and COP should be examined for selected salt pair. Moreover, apparent density, residual porosity, and graphite ratio should be calculated to give minimum block volume and mass, and maximum energy density without causing heat and mass transfer problems. Since heat exchange area can be changed with operating condition, reactor diameter, length, and stainless steel thickness should be decided for desired specifications. These procedure and method were applied to the case study of 6kW cold production and 8 hours storage capacity reactor.

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