• Title/Summary/Keyword: Gas condensation

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Performance Evaluation to Develop an Engineering Scale Cathode Processor by Multiphase Numerical Analysis (다상유동 전산모사를 통한 공학 규모의 cathode processor의 성능평가)

  • Yoo, Bung Uk;Park, Sung Bin;Kwon, Sang Woon;Kim, Jeong Guck;Lee, Han Soo;Kim, In Tae;Lee, Jong Hyeon
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.12 no.1
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    • pp.7-17
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    • 2014
  • Molten salt electrorefining process achieves uranium deposits at cathode using an electrochemical processing of spent nuclear fuel. In order to recover pure uranium from cathode deposit containing about 30wt% salt, the adhered salt should be removed by cathode process (CP). The CP has been regarded as one of the bottle-neck of the pyroprocess as the large amount of uranium is treated in this step and the operation parameters are crucial to determine the final purity of the product. Currently, related research activities are mainly based on experiments consequently it is hard to observe processing variables such as temperature, pressure and salt gas behavior during the operation of the cathode process. Hence, in this study operation procedure of cathode process is numerically described by using appropriate mathematical model. The key parameters of this research are the amount of evaporation at the distillation part, diffusion coefficient of gas phase salt in cathode processor and phase change rate at condensation part. Each of these conditions were composed by Hertz-Langmuir equation, Chapman-Enskog theory, and interphase mass flow application in ANSYS-CFX. And physical properties of salt were taken from the data base in HSC Chemistry. In this study, calculation results on the salt gas behavior and optimal operating condition are discussed. The numerical analysis results could be used to closely understand the physical phenomenon during CP and for further scale up to commercial level.

Recent Progress in Air Conditioning and Refrigeration Research -A Review of Papers Published in the Korean Journal of Air-Conditioning and Refrigeration Engineering in 2000 and 2001- (공기조화, 냉동 분야의 최근 연구 동향 -2000년 및 2001년 학회지 논문에 대한 종합적 고찰 -)

  • 강신형;한화택;조금남;이승복;조형희;김민수
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.14 no.12
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    • pp.1102-1139
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    • 2002
  • A review on the papers published in the Korean Journal of Air-Conditioning and Refrigerating Engineering in 2000 and 2001 has been done. Focus has been put on current status of research in the aspect of heating, cooling, ventilation, sanitation and building environment. The conclusions are as follows. (1) Most of fundamental studies on fluid flow were related with heat transportation of facilities. Drop formation and rivulet flow on solid surfaces were interesting topics related with condensation augmentation. Research on micro environment considering flow, heat, humidity was also interesting for comfortable living environment. It can be extended considering biological aspects. Development of fans and blowers of high performance and low noise were continuing topics. Well developed CFD technologies were widely applied for developing facilities and their systems. (2) Most of papers related with heat transfer analysis and heat exchanger shows dealt with convection, evaporation, and channel flow for the design application of heat exchanger. The numerical heat transfer simulation studies have been peformed and reported to show heat transfer characteristics. Experimental as well as numerical studies on heat exchanger were reported, while not many papers are available for the system analysis including heat exchanger. (3) A review of the recent studies on heat pump system shows that performance analysis and control of heat pump have been peformed by various simulations and experiments. The research papers on multi-type heat pump system increased significantly. The studies on heat pipe have been examined experimently for change of working characteristics and strut lure. Research on the phase change has been carried out steadily and operation strategies of encapsulated ice storage tank are reported experimentally in several papers. (4) A review of recent studies on refrigeration/air conditioning system have focused on the system performance and efficiency for new alternative refrigerants. Evaporation and condensation heat transfer characteristics are investigated for tube shapes and new alternative refrigerants. Studies on components of refrigeration/air conditioning system are carried to examine efficiency for various compressors and performance of new expansion devices. In addition to thermophysical properties of refrigerant mixtures, studies on new refrigerants are also carried out, however research works on two-phase flow seemed to be insufficient. (5) A review of the recent studies on absorption cooling system indicates that heat and mass transfer phenomena have been investigated to improve absorber performance. Various experimental data have been presented and several simulation models have been proposed. A review of the recent studies on duct and ventilation shows that ventilation indices have been proposed to quantify the ventilation performance in buildings and tunnels. Main efforts have been focused on the applications of ventilation effectiveness in practice, either numerically using computational fluid dynamics or experimentally using tracer gas techniques. (6) Based on a review of recent studies on indoor thermal environment and building service systems, research issues have mainly focused on many innovative ideas such as underfloor air-conditioning system, personal environmental modules, radiant floor cooling and etc. Also, the new approaches for minimizing energy consumption as well as improving indoor environmental conditions through predictive control of HVAC systems, various activities of building energy management and cost-benefit analysis for economic evaluation were highlighted.

Annealing effects of organic inorganic hybrid silica material with C-H hydrogen bonds (C-H 수소결합을 갖는 유무기 하이브리드 물질에서의 열처리 효과)

  • Oh, Teresa
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.44 no.11
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    • pp.20-25
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    • 2007
  • In this paper, It was reported the dielectric constant in organic inorganic hybrid silica material such as SiOC film modeling of bond structure by annealing in organic properties. The organic inorganic hybrid silica material were deposited using bis-trimethylsilymethane (BTMSM, [(CH3)3Si]2CH2) and oxygen gas precursor by a plasma chemical vapor deposition (CVD). The organic inorganic hybrid silica material have three types according to the deposition condition. The dielectric constant of the films were performed MIS(Al/Si-O-C film/p-Si) structure. The C 1s spectra in organin inorganic silica materials with the flow rate ratio of O2/BTMSM=1.5 was organometallic carbon with the peak 282.9 eV by XPS. It means that organometallic carbon component is the cross-link bonding structure with good stability. The dielectric constant was the lowest at annealed films with cross-link bonding structure.

Experimental Study on the Characteristics of Heat and Mass Transfer on the Teflon Coated Tubes (테프론 코팅 전열관 표면으로의 열 및 물질 전달 특성에 관한 실험적 연구)

  • Lee, Jang-Ho;Kim, Hyeong-Dae;Kim, Jung-Bae;Kim, Moo-Hwan
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.27 no.8
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    • pp.1051-1060
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    • 2003
  • The heat and mass transfer on two kinds of tube surfaces (bare stainless steel tube and Teflon coated tube) in steam-air mixture flow are experimentally studied to obtain design data for the heat exchanger of the latent heat recovery from flue gas. In the test section, 3-tubes are horizontally installed, and steam-air mixture is vertically flowed from the top to the bottom. The pitch between tubes is 67mm, the out-diameter of tube is 25.4mm, and the thickness is 1.2mm ; blockage factor (cross sectional tube area over the cross sectional area of the test section) is about 0.38. All of sensors and measurement systems (RTD, pressure sensor, flow-meter, relative humidity sensor, etc.) are calibrated with certificated standard sensors and the uncertainty for the heat transfer measurement is surveyed to have the uncertainty within 7%. As experimental results, overall heat transfer coefficient of the Teflon (FEP) coated tube is degraded about 20% compared to bare stainless tube. The degradation of overall heat transfer coefficient of Teflon coated tube comes from the additional heat transfer resistance due to Teflon coating. Its magnitude of heat transfer resistance is comparable to the in-tube heat transfer resistance. Nusselt and Sherwood numbers on Teflon (FEP) coated surface and bare stainless steel surface are discussed in detail with the contact angles of the condensate.

On-road Investigation of PM Emissions according to Vehicle Fuels (Diesel, DME, and Bio-diesel) (Diesel, DME, Bio-diesel 연료가 실제 도로 주행 조건에서 입자상물질 배출에 미치는 영향 파악)

  • Lee, Seok-Hwan;Kim, Hong-Seok;Park, Jun-Hyuk;Cho, Gyu-Baek
    • Transactions of the Korean Society of Automotive Engineers
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    • v.20 no.3
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    • pp.88-97
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    • 2012
  • To measure the traffic pollutants with high temporal and spatial resolution under real conditions, a mobile emission laboratory (MEL) was designed. The equipment of the mini-van provides gas phase measurements of CO, NOx, CO2 and THC (Total hydrocarbon), and number density & size distribution measurements of fine and ultra-fine particles by a fast mobility particle sizer (FMPS) and a condensation particle counter (CPC). The inlet sampling port above the bumper enables the chasing of different type of vehicles. This paper introduces the technical details of the MEL and presents data from the experiment in which a MEL chases a city bus fuelled by diesel, DME and Bio-diesel. The dilution ratio was calculated by the ratio of ambient NOx and tail-pipe NOx. Most particles from the bus fuelled by diesel were counted under 300 nm and the peak concentration of the particles was located between 30 and 60 nm. However, most particles in the exhaust of the bus fuelled by DME were nano-particles (diameter: less than 50 nm). The bus fuelled by Bio-diesel shows less particle emissions compare to diesel bus due to the presence of the oxygen in the fuel.

Changes of Microstructure and Properties of Manufactured Modified Pitches via Pressure Changes during Heat Treatments in Coal Tar Pitch (석탄계 타르의 열처리 중 압력변화에 따른 변성 콜타르 핏치의 미세구조 및 물성 변화)

  • Ko, Hyo Joon;Chung, Sung Mo;Han, Ji Hoon;Park, Chang Uk;Kim, Myung-Soo;Lim, Yun-Soo
    • Korean Journal of Materials Research
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    • v.24 no.6
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    • pp.293-300
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    • 2014
  • Coal-tar pitch, a feedstock which can be heat-treated to create graphite, is composed of very complex molecules. Coal-tar pitch is a precursor of many useful carbon materials (e.g., graphite, carbon fibers, electrodes and matrices of carbon/carbon composites). Modified coal-tar pitch (MCTP) was prepared using two different heat-treatment methods and their properties were characterized and compared. One was prepared using heat treatment in nitrogen gas; the other was prepared under a pressure of 350 mmHg in air. The MCTPs were investigated to determine several properties, including softening point, C/H ratio, coke yield, formation of anisotropic mesophase and viscosity. The MCTPs were subject to considerable changes in chemical composition due to condensation and polymerization in the used-as-received coal-tar pitch after heat-treatment under different conditions. The MCTPs showed considerable increases in softening point, C/H ratio, and coke yield, compared to those of as-received coal-tar pitch. The MCTP formed by heat-treatment in nitrogen showed isotropic phases below $350^{\circ}C$ for 1 h of soaking time. However, MCTP heat-treated under high pressure (350 mmHg) showed isotropic phases below $300^{\circ}C$, and showed anisotropic phases above $350^{\circ}C$, for 1 h of soaking time. The viscosity of the MCTPs increased with increase in their softening points.

On-road Investigation of PM Emissions of Diesel Aftertreatment Technologies (DPF, Urea-SCR) (차량 추적 실험을 통하여 디젤 후처리 장치가 입자상 물질 배출에 미치는 영향 파악)

  • Lee, Seok-Hwan;Kim, Hong-Seok;Park, Jun-Hyuk;Cho, Gyu-Baek
    • Transactions of the Korean Society of Automotive Engineers
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    • v.19 no.5
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    • pp.92-99
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    • 2011
  • To measure the traffic pollutants with high temporal and spatial resolution under real conditions, a mobile emission laboratory (MEL) was designed. The equipment of the mini-van provides gas phase measurements of CO, NOx, $CO_2$, THC (Total hydrocarbon) and number density & size distribution measurements of fine and ultra-fine particles by a fast mobility particle sizer (FMPS) and a condensation particle counter (CPC). The inlet sampling port above the bumper enables the chasing of different type of vehicles. This paper introduces the technical details of the MEL and presents data from the car chasing experiment of diesel bus equipped with aftertreatment system. The dilution ratio was calculated by the ratio of ambient NOx and tail-pipe NOx. Most particles from the diesel bus were counted under 300 nm and the peak concentration of the particles was located between 30 and 60 nm. The total PM number emission from diesel bus equipped with DPF was 10 orders of magnitude lower compared to those emitted from base diesel bus. And the total PM number emission from diesel bus equipped with SCR was comparable to the particle emission from base diesel bus.

The $SO_2$ effect on NOx removal by Corona Shower System (코로나 샤워 시스템을 이용한 NOx제거에서 $SO_2$의 영향)

  • Park, Jae-Yoon;Kim, Ick-Kewn;Lee, Jae-Dong;Kim, Jong-Dal;Lee, Duck-Chool;Chang, J.S.
    • Proceedings of the KIEE Conference
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    • 1998.07e
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    • pp.1794-1796
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    • 1998
  • In this study, the $SO_2$ addition effect on NOx removal has been conducted from a combustion flue gases by the do corona discharge-activated radical shower systems. The simulated flue gases were consisted of NO-O_2-$N_2$, NO-$CO_2-N_2-O_2$ and $NO-SO_2-CO_2-Na-O_2$([NO]o:200ppm and $[SO_2]o$:800ppm). The injection gases used as radical source gases were $NH_3$-Ar-air. $SO_2$ and NOx removal efficiency and the other by-products were measured by Fourier Transform Infrared(FTIR) as well as $SO_2$. NOx and $NO_2$ gas detectors. By-product aerosol particles were also observed by Condensation Nucleation Particle Counter(CNPC) and SEM images after sampling. The results showed that asignificant aerosol Particle formation was observed during a removal operation in corona radical shower systems. The NOx removal efficiency significantly increased with increasing applied voltage and $NH_3$ molecule ratio. The $SO_2$ removal efficiency was not significantly effected by applied voltage and slightly increased with increasing $NH_3$ molecule ratio. The NOx removal efficiency for NO-$SO_2-CO_2-N_2-O_2$ was better than that for NO-$CO_2-N_2-O_2$.

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Effects of Film Thickness and Moisture Absorbing material on Ginger Quality during MA Storage (필름두께 및 흡습제 처리에 따른 생강의 MA 저장효과)

  • 정문철;남궁배;김동만
    • Food Science and Preservation
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    • v.6 no.3
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    • pp.264-269
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    • 1999
  • The effects of film thickness and moisture absorbing materials(MAM) on the ginger qualities were investigated during MA storage for 150 days. LDPE films of 0.04, 0.06 and 0.08mm thicknesses were applied to select the adequate film in gas permiability. MAMs of sheet and sachet type were applied to 0.06mm-LDPE film bag to prevent moisture condensation during storage. Thickness of film used affected neither weight loss nor firmness of gingers during U storage. But the thinner in thickness showed the less changes in sprouting, spoilage and reducing sugar. Moreover, compared with MAP alone, MAPs with MAM of both sachet and sheet styles led to the weight loss of gingers increasing by more than 3-4 times, but sprouting rate, spoilage rate and reducing sugar decreasing by 3.3, 1.4 and 2.3 times, respectively. These results showed that MAP with UM was significantly effective to prolong the freshness of ginger by longer than 2 times, compared with MAP alone.

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Two-Phase Flow Analysis of The Hydrogen Recirculation System for Automotive Pem Fuel Cell (자동차용 고분자 연료전지 수소 재순환 시스템의 이상 유동해석)

  • Kwag, Hyun-Ju;Chung, Jin-Taek;Kim, Jae-Choon;Kim, Yong-Chan;Oh, Hyung-Seuk
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.32 no.6
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    • pp.446-454
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    • 2008
  • The purpose of this paper is to analyze two-phase flows of the hydrogen recirculation system. Two-phase flow modeling is one of the great challenges in the classical sciences. As with most problems in engineering, the interest in two-phase flow is due to its extreme importance in various industrial applications. In hydrogen recirculation systems of fuel cell, the changes in pressure and temperature affect the phase change of mixture. Therefore, two-phase flow analysis of the hydrogen recirculation system is very important. Two-phase computation fluid dynamics (CFD) calculations, using a commercial CFD package FLUENT 6.2, were employed to calculate the gas-liquid flow. A two-phase flow calculation was conducted to solve continuity, momentum, energy equation for each phase. Then, the mass transfer between water vapor and liquid water was calculated. Through an experiment to measure production of liquid water with change of pressure, the analysis model was verified. The predictions of rate of condensed liquid water with change of pressure were within an average error of about 5%. A comparison of experimental and computed data was found to be in good agreement. The variations of performance, properties, mass fraction and two-phase flow characteristic of mixture with resepct to the fuel cell power were investigated.