• 공업화학
• /
• 제27권1호
• /
• pp.62-67
• /
• 2016

본 연구에서는 정수슬러지를 원료로 사용하여 펠렛형 흡착제를 제조하고 질소흡착법, XRD, XRF 및 암모니아 승온탈착법 등을 사용하여 물리 화학적 특성을 분석하였다. 정수슬러지 유래 펠렛형 흡착제와 첨착활성탄의 암모니아 및 포름알데히드 기체의 흡착 성능을 비교하였다. 정수슬러지로부터 제조된 펠렛형 흡착제는 첨착활성탄보다 표면적과 기공부피는 훨씬 작지만 암모니아를 훨씬 더 많이 흡착할 수 있었다. 이는 정수슬러지로부터 제조된 펠렛형 흡착제 표면에 산점이 훨씬 더 많이 분포해 있어서 화학흡착에 의해 암모니아를 흡착하기 때문이다. 반면에, 산성가스인 포름알데히드 가스 흡착의 경우는 넓은 표면적과 발달된 기공으로 인하여 첨착활성탄의 흡착성능이 정수슬러지로부터 제조된 펠렛형 흡착제에 비해 훨씬 우수하였다.

• 한국전기전자재료학회:학술대회논문집
• /
• 한국전기전자재료학회 2002년도 춘계학술대회 논문집 유기절연재료 전자세라믹 방전플라즈마 일렉트렛트 및 응용기술
• /
• pp.117-121
• /
• 2002

In this paper, the proper manufacturing method to the use of Illite with many application was studied. We confirmed merit of manufacturing and forming according as respective temperature. The variety of crystallization and surface was confirmed by X-ray diffraction(XRD) analysis and SEM. Then, we performed the experiments such as a antibiosis, a heavy metal adsorption and a gas deodorizaton to confirm the function of Illite. As a result, the adsorption of gas decreased according as the heat treatment of Illite, but the ability of antibiosis wasn't changed.

• 한국분말재료학회지
• /
• 제14권6호
• /
• pp.391-398
• /
• 2007

The surface roughness of Al, Ag and Ni nano-powders which were prepared by pulsed wire evaporation method was quantified based upon the fractal theory. The surface fractal dimensions of metal nano-powders were determined from the linear relationship between In $V/V_{mono}$ and Inln ($P^o/P$) using multi-layer gas adsorption theory. Moreover, the fractal surface image was realized by computer simulation. The relationship between preparation condition and surface characteristics of metal nano-powders was discussed in detail.

• Advances in materials Research
• /
• 제13권3호
• /
• pp.203-210
• /
• 2024

Science mapping is a visual representation of the structure and dynamics of scholarly knowledge. Gas adsorption on catalyst supports is a crucial process in many catalytic reactions. The R package "Bibliometrix" and VosViewer software were employed for science mapping analysis. The results show that the upward trend but fluctuates from year to year for both annual scientific production and average article citations per year. Co-occurrence of the keywords were used to identify the primary fields of study and to map the existing state of research. Trending topics reveal some interesting features that support the growth of research in this field and are associated with emerging disciplines or areas of study that have not been extensively explored.

• 청정기술
• /
• 제17권4호
• /
• pp.389-394
• /
• 2011

바이오가스로부터 이산화탄소와 질소를 제거하기 위한 흡착공정은 많이 논의되고 있다. 특히 흡착공정 중에서 압력변동흡착(Pressure swing adsorption)공정은 에너지소모가 적고 가격이 경제적이기 때문에 기체의 분리와 정제를 위한 공정으로 적절하다. 물리적 흡착을 사용하는 PSA공정은 흡착과 탈착이 가능하다. 각 cycle단계의 구성은 가압, 주입 및 흡착, 압력 균등화, 감압 및 세정으로 이루어져있다. 본 실험에서 PSA공정은 이산화탄소와 질소를 제거하기 위한 흡착제로 zeolite 13X와 carbon molecular sieve (CMS)로 구성되어 있으며, 혼합 가스의 농도는 $CH_4/CO_2/N_2$ (75:21:4 vol%)의 비율을 갖고 있다. 각각 zeolite 13X와 CMS는 선택적으로 혼합가스로부터 질소와 이산화탄소를 흡착하여 분리하고 제거한다. 또한 CMS의 경우는 빠르게 분산되는 이산화탄소의 처리량이 높다. 상부탱크, 하부탱크, 주입탱크의 가스 조성은 TCD 검출기를 이용하는 gas chromatography (GC)에 의해서 측정되었다.

• 대한기계학회논문집B
• /
• 제31권5호
• /
• pp.425-434
• /
• 2007

An integrated adsorption/catalytic process has been considered to treat dioxin and $NO_x$ simultaneously. The process consists of a cyclone and a reactor with nine bag filters. In this study, numerical analysis has been performed to understand flow characteristics with inflow-duct types in the reactor. To consider flue gas and activated carbon particles simultaneously, Euler-Lagrangian model was employed. Fundamental flow patterns of flue gas and activated carbon particles, pressure distribution and distribution of activated carbon have been obtained from the numerical analysis. Also trace length and residence time of flue gas, residence time of activated carbon particles have been calculated directly. Flow patterns of flue gas and activated carbon particles in the reactor were very complicated and they moved along very various paths. Therefore, their residence time in the reactor was also various. The flow characteristics in the reactor were strongly influenced by inflow-duct types. The results obtained would be effectively used to estimate the removal efficiency in the reactor once the residence time is combined with the reaction equation.

• 한국대기환경학회지
• /
• 제9권1호
• /
• pp.101-106
• /
• 1993

In order to separate the Freon-12 and air mixture$(CF_2Cl_2/Air=0.1/99.9 vol.%)$ by pressure swing adsorption (PSA), the breakthrough curve was experimentally observed in a fixed bed adsorption column. A single adsorber was packed with various adsorbents such as, the activated carbon(S-AC, W-AC) and the molecular sieve(MS-5A, MS-13X). The order of appearance of breakthrough curve is MS-5A > MS-13X > W-AC > S-AC. The activated carbon was found to be more effective adsorbent for separating Freon-12 from the mixture than the molecular sieve was. From the experimental data obtained by the separation of Freon-12 gas out of the air stream in the steady-state PSA process cycle, whose size is the same one of column used for the breakthrough curve observation, it has been confirmed that Freon-rich gas could be obtained from the purge step of PSA and Freon-free air could be obtained from the adsorption step of PSA cycle.

• 한국환경과학회지
• /
• 제9권2호
• /
• pp.145-149
• /
• 2000

The purpose of this study was to determine whether Vermi Cast could be used effectively to remove $SO_2$ from flue gas, and then to investigate optimum adsorption conditions. The Vermi Cast used as adsorbent was mechanically screened with 8~20 mesh sieve. The adsorption data for $SO_2$ were regressed using the Freundlich isotherm. The fit was generally satisfactory ($R^2$=0.945~0.982). With the temperature changes from 2$0^{\circ}C$ to 4$0^{\circ}C$, the constant k in Freundlich isotherm qe= $kCe^{1/n}$, decreased from 1.409 at 2$0^{\circ}C$to 0.297 at 4$0^{\circ}C$, and the exponent 1/n were decreased from 0.343 to 0.134. With the bed depth changes from 10cm to 30cm, the adsorption capacity expressed as mmol of $SO_2$ adsorbed per g of Vermi Cast increased from 0.247 to 0.381. Moisture content is an important parameter in the $SO_2$ adsorbed were observed over 0.3mmol $SO_2$ /g Vermi Cast. The best adsorption capacity was 0.487mmol $SO_2$ /g Vermi Cast, and it was obtained with moisture content 37%, temperature 2$0^{\circ}C$. From the above results, ti might be concluded that Vermi Cast is effectively as a good adsorbent to remove $SO_2$ from flue gas.

• 한국자동차공학회논문집
• /
• 제17권4호
• /
• pp.133-138
• /
• 2009

The continued rise in the number of automobiles on the roads is prompting air pollution to emerge as a serious problem due to the harmful exhaust gas emissions throughout the world. Specifically, based on the exhaust gas regulation in North America represented by PZEV, the regulation on evaporative emission, which originates from the intake manifold system when the engine is stopped, is substantially being intensified. And the technology that can meet and satisfy these regulations has been needed. This study aimed to analyze and evaluate the butane working capacity (BWC) of HC adsorption filter according to the shape of it, which was developed to reduce evaporative emission, and the effect of HC adsorption filter on the engine performance. As a results, HC adsorption filter of the plate type, which was improved compared to that of the corrugated type and also became thinner, indicates higher absorption performance compared to the corrugated one. The absorption performance of the honeycomb type, derived from improving the shape of plate type, is 33.5% higher than that of the corrugated type. However, there was no significant difference in engine performance in all shapes.

• 펄프종이기술
• /
• 제34권3호
• /
• pp.9-16
• /
• 2002

The adsorption characteristics and surface energetics of hydrophobically modified MCC have been investigated by the inverse gas chromatography technique at infinite dilution. The thermodynamic parameters of adsorption, ΔG, ΔH and ΔS, for n-alkanes were determined at infinite dilution. Heats of adsoption of the n-alkanes increased as the level of hydrophobic modification increased. The hydrophobically modified MCC also showed greater entropy of adsorption indicating restricted mobility of the adsorbed n-alkanes. The acid/base characteristics of the MCC were evaluated using polar probes. As the hydrophobicity of MCC increased, the basisity of the MCC decreased.