• Proceedings of the KSR Conference
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• 2007.11a
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• pp.1314-1317
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• 2007

This study is on the fire resistance evaluation method, expecially on the toxicity of smoke gases generated from the fire, of materials for railway car and structures. Until now, Although international standard related to the quantifying evaluation method of smoke gas is provided but the specific procedure is not contained. On this reason, Test results of toxicity show deviation with the different technique being applied. For now, In advanced railway country, various instrument, like ion chromatography and etc., is used but FT-IR is recommended due to its lots of advantages. while FT-IR has a lot of strong points but still has some problems like water vapor interferences. In this paper, To improve credibility and repeatability of FT-IR it contains some technical solutions in quantifying the 8 toxic components.

• Proceedings of the Korea Institute of Fire Science and Engineering Conference
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• 1997.11a
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• pp.66-76
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• 1997

In order to investigate the generation of carbon monoxide and heat loss of incomplete combustion in compartment fires, an experiment was conducted in a small scale compartment by using methanol as a fuel. The concentration of carbon monoxide and the toxicity parameter showed high values when the mass air - to - fuel stoichiometric ratio is under 1.0. The constitution of the combustion gas was showed to estimate it from the . The heat loss due to incompleteness of combustion is about one third of heat of combustion in case of under 1.0.

• Proceedings of the Korea Air Pollution Research Association Conference
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• 1999.04a
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• pp.176-177
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• 1999

• Journal of Environmental Health Sciences
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• v.47 no.4
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• pp.366-377
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• 2021

Background: Polycyclic aromatic hydrocarbons (PAHs) are generated in petrochemical complexes, can spread to residential areas and affect the health of residents. Although harmful PAHs are mainly present in particle phase, gas phase PAHs can generate stronger toxic substances through photochemical reaction. Therefore, the risk assessment for PAHs around the petrochemical complex should consider both particle and gas phase concentrations. Objectives: This study aimed to investigate the concentration characteristics of particle and gas phase PAHs by season in residential areas around petrochemical complexes, and to assess the risk of PAHs. Methods: Samples were collected for 7 days by seasons in 2014~2015 using a high volume air sampler. Particle and gas phase PAHs were sampled using quartz filter and polyurethane foam, respectively, analyzed by GC-MS. Chronic toxicity and probabilistic risk assessment were performed on 14 PAHs. For chronic toxicity risk assessment, inhalation unit risk was used. Monte-Carlo simulation was performed for probabilistic risk assessment using the mean and standard deviation of measured PAHs. Results: The concentration of particle total PAHs was highest in autumn. The gas phase concentration was highest in autumn. The average gas phase distribution ratio of low molecular weight PAHs composed of 2~3 benzene rings was 85%. The average of the medium molecular weight composed of 4 benzene rings was 53%, and the average of the high molecular weight composed of 5 or more benzene rings was 9%. In the chronic toxicity risk assessment, 7 of the 14 PAHs exceeded the excess carcinogenic risk of 1.00×10^-6. In the Monte-Carlo simulation, Benzo[a]pyrene had the highest probability of exceeding 1.00×10^-6, which was 100%. Conclusions: The concentration of PAHs in the residential area around the petrochemical complex exceeded the standard, and the excess carcinogenic risk was evaluated to be high. Therefore, it is necessary to manage the air environment around the petrochemical complex.

• Proceedings of the Korea Institute of Fire Science and Engineering Conference
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• 2002.05a
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• pp.21-29
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• 2002

With regard to the personnel safety and other safety when the gas suppressants are discharged into the area where occupants exist, the short term and long term effects to the health of people are discussed mainly with the Carbon dioxide agent and Halon Replacement agents system. To gain the benefits of CO2 extinguishing systems while minimizing risk to people serious attention must be given to personnel safety in the design, installation, and maintenance of CO2 systems. Training of personnel is essential. A major factor in the use of a clean agent fire suppressant in a normally occupied area is toxicity. While all halocarbon agents are tested for long-term health hazards, the primary endpoint is acute or short-term exposure, The primary acute toxicity effects of the halocarbon agents described here are anesthesia and cardiac sensitization. For inert gases, the primary physiological concern is reduced oxygen concentration.

• Fire Science and Engineering
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• v.21 no.1 s.65
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• pp.90-97
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• 2007

Combustion characteristics and toxicity of combustion gas of wallpaper samples were analyzed to evaluate the fire risk of wallpaper furnished in living space. In this study ash residue ratio was measured with high temperature electric furnace, and thermal analysis was carried out with TGA. Combustion time and smoke concentration were measured with cone heater and combustion gas analyzer. Smoke density of samples was measured using smoke chamber of ASTM E 662. The experimental results were showed as followings. Pyrolysis of silk wallpaper started at lower temperature compared to the other samples. It means that the silk wallpaper can be ignited at low heat flux and will have more fire risk than the others. Ignition time by radiation heat flux of silk wallpaper is shorter compared to the other samples, so evacuation time must be reduced. In the case of vinyl coated silk wall paper, carbon mono oxide concentration is the highest and the toxicity and damage effect to consciousness was stronger compared to the other samples. Smoke density of silk wall paper and fire retardant mixed coated silk wall paper were very high due to vinyl coating.

• Journal of the Korean Institute of Gas
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• v.18 no.2
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• pp.55-61
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• 2014

In this study, we evaluated the measurement of working environment, the amount of exposure, the hazards and risks of biphenyl, that was registered as 2A in IARC. Based on the exposure scenario, it was calculated that the exposure amounts are $1.0{\times}10^{-2}$, $4.2{\times}10^{-4}$, $7.0{\times}10^{-6}mg/m^3$, respectively, and the $RfC_{work}$ is 0.21, 2.13, 0.53 $0.31mg/m^3$ as carcinogenicity, target toxicity (oral), target toxicity (inhalation), developmental toxicity, respectively. According to these hazards evaluation and risk assessments, it was estimated that 0.57, 0.39 as carcinogenicity and non-carcinogenicity (developmental toxicity), respectively. It was also estimated relatively lower risks below 1. But since biphenyl is hazardous used much amounts, and could be exposed to workers directly, it was determined to require exposure monitoring to protect workers' health.

• Korean journal of applied entomology
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• v.43 no.4 s.137
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• pp.323-328
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• 2004

These studies were carried out to investigate the fumigation and contact toxicities of spearmint oil (Mentha spicata) against adults of greenhouse whitefly, Trialeurodes vaporariorum and sweet-potato whitefly, Bemisia tabaci. And we carried out the constituent analysis of spearmint oil using gas chromatograph (GC) and gas chromatograph mass spectrometry (GC/MS). Spearmint oil showed $99.1\%,\;91.7\%,\;41.1\%$ fumigation toxicity against T. vaporariorum adults at $10{\mu}L/954mL,\;5{\mu}L/954mL,\;1{\mu}L/954mL$ air concentration, respectively. In case of B. tabaci adults, spearmint oil showed $100\%,\;100\%,\;61.3\%$ fumigation toxicity, respectively. However, spearmint oil showed < $30\%$ contact toxicity against adults of T. vaporariorum and B. tabaci. Through the constituent analysis using GC and GC/MS, we confirmed main constituents of spearmint oil were limonene ($16.1\%$), ${\gamma}$-terpinene($13.8\%$), ${\rho}$-cymene($5.8\%$), 3-octanol($6.9\%$), carvone($40.9\%$). Carvone, major constituent of spearmint oil, also showed $100\%$ fumigation toxicity at $10{\mu}L/954mL$ air concentration.

• Fire Science and Engineering
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• v.23 no.6
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• pp.1-9
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• 2009

In this study, the burning behaviours of five different kinds of carpet samples covered with nylon, PP (polypropylene), PTT (poly(trimethylene terephthalate)), wool fabric and NW (nylon and wool) were evaluated by using the cone calorimeter having a radiant flux of 50kW/$m^2$. And the combustion gas toxicity was evaluated according to KS F 2271 test method. As a result of the cone calorimeter test (KS F ISO 5660-1), nylon carpet samples were ignited most easily. In ignition ability or initial flammability, NW carpet samples showed the highest value. In heat release rate (HRR), fire intensity, PP carpet samples were larger than any other samples. Nylon carpet samples were the highest smoke production rate, while N/W carpet samples the lowest. The following were in mass loss rates: NW > wool > nylon > PP > PTT. CO (carbon monoxide) was one of the most toxic gases released from the combustion. PTT carpet samples gave rise to the highest CO concentration, while NW carpet samples the lowest. In addition, PP carpet samples caused the highest $CO_2$ (carbon dioxide) concentration, while NW carpet samples the lowest. Toxicity of the gas produced from carpet samples was determined by the mouse stop motion, and it resulted in the fact that the combustion gas of PTT carpet samples was more toxic than that of any other samples.

• Korean Chemical Engineering Research
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• v.60 no.4
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• pp.519-524
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• 2022

Domestic building finishing materials are being evaluated according to KS F 2271 standards according to the notification of the Ministry of Land, Infrastructure and Transport, and this test is evaluated using laboratory animals. In this study, experiments were conducted on highly combustible organic insulation materials such as EPS, urethane, and phenolic foam. The purpose of this study was to analyze the cause of the behavioral suspension of the experimental mice by measuring the average behavioral suspension time of the mice caused by the harmful gas generated when these three types of insulation materials were burned. FTIR analysis and smoke density experiment were performed as a cause analysis method for the behavioral suspension of mice, and the experimental results were analyzed by dividing the causes of behavioral suspension into suffocation by particulate matter and toxic inhalation by gaseous substances. As a result of the test, urethane was evaluated as the most harmful insulation material, and as a result of FTIR analysis and smoke density test as a cause analysis for the gas toxicity test results, it is judged that the behavioral stop of the rats by suffocation is higher than the effect of toxic inhalation. This study is a basic study on the cause analysis of harmful gases, and it will be necessary to prepare the toxicity basis and analyze various materials and gases.