• 제목/요약/키워드: Gas Mixtures

검색결과 601건 처리시간 0.025초

시뮬레이션을 이용한 $SF_6$-Ar혼합기체의 전자 이동속도 (Drift Velocities for Electrons in $SF_6$-Ar Mixtures Gas by Simulation)

  • 황청호;김상남
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2007년도 하계학술대회 논문집 Vol.8
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    • pp.451-452
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    • 2007
  • Drift velocities for electrons in $SF_6$-Ar mixtures gas by simulation has been analysed over the EIN range 30~300[Td] by a two term Boltzmann equation and by a Monte Carlo Simulation using a set of electron cross sections determined by other authors, experimentally the electron swarm parameters for 0.2[%] and 0.5[%] $SF_6$-Ar mixtures were measured by time-of-flight (TOF) method. The results show that the deduced electron drift velocities, the electron ionization or attachment coefficients. longitudinal and transverse diffusion coefficients and mean energy agree reasonably well with theoretical for a rang of E/N values.

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Trichlorosliane 및 Dichlorosilane-Trichlorosliane 혼합물의 자연발화 특성 (Characteristics of Auto-ignition for Trichlorosliane and Dichlorosilane-Trichlorosliane Mixtures)

  • 하동명
    • 한국가스학회지
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    • 제14권4호
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    • pp.24-30
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    • 2010
  • 최소자연발화온도(AIT, autoignition temperature)의 정확한 정보는 산업화재를 예방하고 제어하는데 중요하다. 본 연구에서는 ASTM E659-78 장치를 이용하여 트리클로로실란 순수물질 그리고 디클로로실란(DCS)과 트리클로로실란(TCS) 혼합물의 AIT를 측정하였다. 트리클로로실란의 AIT는 $225^{\circ}C$로 측정되었으며, TCS(90wt%)-DCS(10wt%) 혼합물은 $250^{\circ}C$, TCS(70wt%)-DCS(30wt%) 혼합물은 각각 $236^{\circ}C$에서 발화가 발생하였다.

시뮬레이션을 이용한 $SF_6$-Ar혼합기체의 전자 평균에너지 (A Simulation of the Mean energy of electrons in $SF_6$-Ar Mixtures Gas)

  • 김상남
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2005년도 하계학술대회 논문집 Vol.6
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    • pp.578-580
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    • 2005
  • Energy distribution function for electrons in SF6-Ar mixtures gas used by MCS-BEq algorithm has been analysed over the E/N range 30~300[Td] by a two term Boltzmann equation and by a Monte Carlo Simulation using a set of electron cross sections determined by other authors, experimentally the electron swarm parameters for 0.2[%] and 0.5[%] $SF_6$-Ar mixtures were measured by TOF method, The results show that the deduced electron drift velocities, the electron ionization or attachment coefficients, longitudinal and transverse diffusion coefficients and mean energy agree reasonably well with theoretical for a rang of E/N values. The results obtained from Boltzmann equation method and Monte Carlo simulation have been compared with present and previously obtained data and respective set of electron collision cross sections of the molecules.

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SF6+Ar혼합기체의 MCS-BEq에 의한 전자분포함수 (Energy Distribution Function for Electrons in SF6+Ar Mixtures Gas used by MCS-BEQ Algorithm)

  • 김상남
    • 전기학회논문지P
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    • 제51권1호
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    • pp.28-32
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    • 2002
  • Energy distribution function for electrons in $SF_6+Ar$ mixtures gas used by MCS-BEq algorithm bas been analysed over the E/N range 30-300[Td] by a two term Boltzmann equation and by a Monte Carlo Simulation using a set of electron cross sections determined by other authors, experimentally the electron swarm parameters for 0.2[%] and 0.5[%] $SF_6+Ar$ mixtures were measured by time-of-flight(TOF) method. The results show that the deduced electron drift velocities, the electron ionization or attachment coefficients, longitudinal and transverse diffusion coefficients and mean energy agree reasonably well with theoretical for a rang of E/N values.

내연기관엔진의 가스혼소발전 경제성 예측모델 개발 (Development of Economic Prediction Model for Internal Combustion Engine by Dual Fuel Generation)

  • 허광범;장혁준;이형원
    • 한국수소및신에너지학회논문집
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    • 제31권4호
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    • pp.380-386
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    • 2020
  • This paper represents an analysis of the economic impact of firing natural gas/diesel and natural gas/by-product oil mixtures in diesel engine power plants. The objects of analysis is a power plant with electricity generation capacity (300 kW). Using performance data of original diesel engines, the fuel consumption characteristics of the duel fuel engines were simulated. Then, economic assessment was carried out using the performance data and the net present value method. A special focus was given to the evaluation of fuel cost saving when firing natural gas/diesel and natural gas/by-product oil mixtures instead of the pure diesel firing case. Analyses were performed by assuming fuel price changes in the market as well as by using current prices. The analysis results showed that co-firing of natural gas/diesel and natural gas/by-product oil would provide considerable fuel cost saving, leading to meaningful economic benefits.

내압방폭을 위한 Safe Gap의 측정에 관한 연구 (A Study on the Safe Gap for Explosion-proof)

  • 오규형
    • 한국가스학회지
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    • 제1권1호
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    • pp.1-6
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    • 1997
  • 가연성 가스가 존재하는 위험 분위기에서 전기기기를 사용할 경우 전기 스파크에 의한 폭발위험성이 존재하기 때문에 점화원을 격리시키거나 고립시키는 것이 필요하지만 현실적으로 점화원의 고립이 불가능하므로 폭발을 방지하기 위한 일반적인 방법으로 내압 방폭형전기기기를 사용하고 있다. 따라서 내압방폭기기의 내부에 침투한 가연성 가스가 폭발하여도 화염이나 열이 틈새를 통과하여 외부의 가연성 분위기를 점화시킬 수 없는 최대 틈새크기를 찾아야 할 필요가 있다. 본 논문에서는 수소-공기 혼합기와 메탄-공기 혼합기에 대하여 실험적 최대틈새크기(MESG)를 찾아내어 기존의 결과와 비교하고, MESG에 영향을 미치는 요인들을 찾아내고자 하였다. 실험장치는 내용적 8${\iota}$의 구형용기를 사용하였으며 실험 변수들로는 전화위치, 혼합기의 농도, 초기압력 등이었다. 실험결과 각각의 변수들에 의해 영향을 받으며 특히 농도와 초기압력에 크게 영향을 받는 것을 알 수 있었으며, 당량 농도 가까이에서 최소값을 나타내었으며 초기압력의 상승과 함께 MESG는 감소하였다.

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수송조건 내 포집 이산화탄소의 전달물성 예측. 2. 열전도계수 (Prediction of Transport Properties for Transporting Captured CO2. 2. Thermal Conductivity)

  • 이원준;윤린
    • 설비공학논문집
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    • 제29권5호
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    • pp.213-219
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    • 2017
  • This study investigated the thermal conductivity of $CO_2$ gas mixtures in order to ascertain the effects of particular impurities in $CO_2$ in pipeline transportation. We predicted the thermal conductivity of three $CO_2$ gas mixtures ($CO_2+N_2$, $CO_2+H_2S$, and $CO_2+CH_4$) by utilizing three different methods : Chung et al., TRAPP, and the REFPROP model. We validated predictions by comparing the estimated results with 216 experimental data for $CO_2+CH_4$, $CO_2+N_2$, and $CO_2+C_2H_6$. Following $CO_2$ transportation conditions, we observed that the model developed by Chung et al. showed the lowest mean deviation of 3.07%. Further investigations were carried out on the thermal conductivity of $CO_2$ gas mixtures based on the Chung et al. model including the effects of the operation parameters of pressure, temperature, and mole fraction of impurities.

Fabrication of triazine-based Porous Aromatic Framework (PAF) membrane with structural flexibility for gas mixtures separation

  • Wang, Lei;Jia, Jiangtao;Faheem, Muhammad;Tian, Yuyang;Zhu, Guangshan
    • Journal of Industrial and Engineering Chemistry
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    • 제67권
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    • pp.373-379
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    • 2018
  • A transparent, freestanding Porous Aromatic Framework-97 (PAF-97) membrane was successfully synthesized via a one-step acid-catalyzed reaction. Due to the introduction of ether groups, the obtained PAF-97 membrane possesses enhanced structural flexibility, thus increasing the flexibility of the resulting membrane. This is proofed by the fact that the feeding pressure of the membrane reaches as high as 5.5 bar during the separation of gas mixtures. The Young's moduli of the membrane were 6.615 GPa and 11.11 GPa, either in a dry or hydrated state respectively. To be highlighted, under a feeding pressure of 3.6 bar, the PAF-97 membrane rendered the permeance values of $2.90{\times}10^{-7}$, $1.29{\times}10^{-8}mol\;m^{-2}s^{-1}Pa^{-1}$ for $CO_2$ and $CH_4$, respectively, with a $CO_2/CH_4$ permselectivity of 22.48.

$SF_6$-Ar 혼합기체(混合氣體)의 전자(電子) 평균(平均)에너지 (Mean energy of electrons in $SF_6$-Ar Mixtures Gas)

  • 김상남;성낙진
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2003년도 학술대회 논문집 전문대학교육위원
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    • pp.75-78
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    • 2003
  • Energy distribution function for electrons in $SF_6$-Ar mixtures gas used by MCS-BEq algorithm has been analysed over the E/N range $30\sim300$[Td] by a two term Boltzmann equation and by a Monte Carlo Simulation using a set of electron cross sections determined by other authors, experimentally the electron swarm parameters for 0.2[%] and 0.5[%] $SF_6$-Ar mixtures were measured by time-of-flight(TOF) method. The results show that the deduced electron drift velocities, the electron ionization or attachment coefficients, longitudinal and transverse diffusion coefficients and mean energy agree reasonably well with theoretical for a rang of E/N values. The transport coefficients for electrons in (0.2[%])$SF_6$-Ar and (0.5[%]$SF_6$ - Ar mixtures were measured by time-of-flight method, and the electron energy distribution function and the parameters of the velocity and the diffusion were determined by the variation of the collision cross-sections with energy. The results obtained from Boltzmann equation method and Monte Carlo simulation have been compared with present and previously obtained data and respective set of electron collision cross sections of the molecules.

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CF4, CH4, Ar 혼합기체의 전리와 부착계수 (Ionization and Attachment Coefficients in CF4, CH4, Ar Mixtures Gas)

  • 김상남
    • 전기학회논문지P
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    • 제61권1호
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    • pp.13-17
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    • 2012
  • Ionization and Attachment Coefficients in pure $CH_4$, $CF_4$ and mixtures of $CF_4$ and Ar, have been analyzed over a range of the reduced electric field strength between 0.1 and 350[Td] by the two-term approximation of the Boltzmann equation (BEq.) method and the Monte Carlo simulation (MCS). The calculations of electron swarm parameters require the knowledge of several collision cross-sections of electron beam. Thus, published momentum transfer, ionization, vibration, attachment, electronic excitation, and dissociation cross-sections of electrons for $CH_4$, $CF_4$ and Ar, were used. The results of the Boltzmann equation and the Monte Carlo simulation have been compared with the data presented by several workers. The deduced transport coefficients for electrons agree reasonably well with the experimental and simulation data obtained by Nakamura and Hayashi. The energy distribution function of electrons in $CF_4$-Ar mixtures shows the Maxwellian distribution for energy. That is, f(${\varepsilon}$) has the symmetrical shape whose axis of symmetry is a most probably energy. The proposed theoretical simulation techniques in this work will be useful to predict the fundamental process of charged particles and the breakdown properties of gas mixtures.