• 제목/요약/키워드: Gas Mixtures

검색결과 600건 처리시간 0.028초

$SF_6$-Ar 혼합기체에서의 전리와부착계수 (Ionization and Attachment Coefficients in Mixtures of $SF_6$ and Ar)

  • 김상남;하성철
    • 한국전기전자재료학회논문지
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    • 제14권9호
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    • pp.773-778
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    • 2001
  • In this dissertation the results of the combined experimental and theoretical studies designed to understand and predict the spatial growth and transport coefficients for electrons in SF$_{6}$ and SF$_{6}$-Ar mixtures have described. The ionization and attachment coefficients in pure SF$_{6}$ and SF$_{6}$-Ar mixtures have been calculated over the range of 10$_{6}$ molecule and for Ar atom proposed by other authors. The transport coefficients for electrons in (0.2%)SF$_{6}$-Ar and (0.5%)SF$_{6}$-Ar mixtures were measured by time-of-flight method, and the electron energy distribution function and the parameters of the velocity and the diffusion were determined by the variation of the collision cross-sections with energy. The results obtained in this work will provide valuable information on the fundamental haviors of electrons in weakly ionized gases and the role of electron attachment in the choice of better gases and unitary gas dielectrics or electro negative components in dielectric gas mixtures. gas mixtures.

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$SF_6+Ar$ 혼합기체의 MCS-BE 알고리즘에 의한 전자에너지 분포함수 (A Study on the Electron Energy Distribution Function in $SF_6+Ar$ Mixtures Gas used by MCS-BE Algorithm)

  • 김상남;하성철
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2000년도 학술대회 논문집 전문대학교육위원
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    • pp.17-21
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    • 2000
  • A Study on the electron energy distribution function in $SF_6+Ar$ mixtures gas used by MCS-BE algorithm, the electron swam parameters in the 0.5% and 0.2% $SF_6+Ar$ mixtures are measured by time of flight method over the E/N(Td) range from 30 to 300(Td). A two-term approximation of the Boltzmann equation analysis and Monte Carlo simulation have been also used to study electron transport coefficients. The electron energy distribution function has been analysed in $SF_6$ gas and $SF_6+Ar$ mixtures at E/N : 200(Td) for a case of the equilibrium region in the mean electron energy. The measured results and the calculated results have been compared each other.

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TOF법에 의한 $CF_4+Ar$ 혼합기체의 전자수송특성 해석 (Analysis of electron transport properties of $CF_4+Ar$ mixtures gas by the TOF method)

  • 서상현;하성철;유회영
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1998년도 춘계학술대회 논문집
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    • pp.279-283
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    • 1998
  • The electron swarm parameters in the$CF_4$(O.l%, 5%)+Ar mixtures are measured by time of flight method over the E/N(Td) range from 10 to 300LTdl. A two-term approximation of the Boltzmann equation analysis and Monte Carlo simulation have been also used to study electron transport coefficients. We have calculated W, NDL, NDT, $\alpha$ and the limiting breakdown electric field to gas mixtures ratio in pure $CF_4$ gas and$CF_4+Ar$ mixtures. The measured results and the calculated results have been compared each other paper.

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평등 및 불평등 전계하에서 순수 Ar, $N_2$가스와 Ar/$N_2$혼합 가스의 교류절연파괴 특성 (AC Breakdown Characteristics of Pure Ar, $N_2$ Gas and Ar/$N_2$ Gas Mixutres under Uniform and Non-Uniform Fields)

  • 이상우;김인식;이동인;이광식;김이국
    • 조명전기설비학회논문지
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    • 제15권5호
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    • pp.20-27
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    • 2001
  • 본 연구에서는 평등 및 불평등 전계하에서 58.8~137.3[kPa]의 가스 압력변화에 따른 순수 Ar 및 $N_2$가스의 교류절연파괴 특성을 조사하였다. 그리고 가스 압력 변화에 따른 Ar/$N_2$ 혼합 가스의 교류절연파괴 특성과 비교하였다. 실험 결과를 요약하면, 평등 및 불평등 전계하에서 순수 $N_2$가스의 압력 변화에 따른 교류절연파괴 특성은 순수 Ar 가스에 비해 약 4.8배 1.1배 증가된 것으로 나타났으며, 압력이 증가됨에 따라 교류절연파괴전압은 증가되었다. Ar/$N_2$혼합 가스의 절연파괴전압은 순수 $N_2$가스의 혼합비가 적을수록 감소되었으며, 혼합 가스 압력이 101.3[kPa]일 때, 순수 Ar 가스에 비해 Ar 가스 혼합 비율이 각각 85[%] 및 70[%] 인 경우, 교류절연파괴전압은 평등 전계하에서는 약 1.5 및 2.1배 증가되었으며, 불평등 전계하에서는 약 1.1 및 1.3배 증가되었다. 또한 불평등 전계하에서 Ar(70%)$N_2$(30%) 혼합 가스의 코로나개시전압은 순수 Ar 가스에 비해 약 1.5배 증가되었다.

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Pridiction of Adsorption Equilibrium for Binary Gas Mixtures on Cation Exchanged Forms of ZSM-5

  • Going Yim;Chai Suck Yim
    • 공학논문집
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    • 제6권2호
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    • pp.85-98
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    • 2004
  • The adsorption equilibrium data for the binary gas mixture system from the pure gas adsorption data of carbon dioxide and ethylene on ZSM-5 prepared were predicted. The binary gas mixture adsorption data have been examined against predicted values by two models-the vacancy solution model(VSM) and the statistical thermodynamic model(STM), using parameters obtained from the single component isotherm. The binary gas mixture data for the carbon dioxide-ethylene system were obtained for cation exchanged forms of ZSM-5 for the gas phase carbon dioxide mole fraction of 0.752 at $37^{\circ}C$ and 1 atm. The experimental adsorption phase diagrams were obtained for carbon dioxide-ethylene on sodium form ZSM-5 synthesized. The single component adsorption isotherms for carbon dioxide and ethylene were also obtained for this zeolite. The single component data were used to obtain parameters derived in two models. These parameters were, in turn, used to predict the binary mixture isotherms for this zeolite. Both the vacancy solution and the statistical thermodynamic models give satisfactory predictions of adsorption phase diagrams for the binary gas mixtures of carbon dioxide and ethylene on sodium exchanged ZSM-5. Also the correlation between the experimental data and the predicted values is generally in good agreement. The system appears to show ideal behavior with a relatively constant separation factor. The slight increase in adsorption capacity with an increase in ionic radius is due, in part, to the higher polarizability associated with larger cations.

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나트륨 아지드와 금속산화물과의 혼합물에 대한 열분해 특성 (Thermal Decomposition Characteristics on Sodium Azide and Metallic Oxide Mixtures)

  • 이내우;최재욱;박광수;설수덕;왕석주
    • 한국안전학회지
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    • 제12권3호
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    • pp.106-113
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    • 1997
  • The thermal characteristics of two binary mixtures by sodium azide/manganese dioxide and ferric oxide, two ternary mixtures by sodium azide/silicon dioxide/manganese dioxide and ferric oxide were studied to obtain the basic data of gas-generating agents for air bags. The thermal reaction for all mixtures started at about $420^{\circ}C$, but the temperature at which the reaction rate reached a maximum was different with the states of samples. According to reaction results, nitrogen, nitrogen oxide and nitrogen dioxide were detected by GC-MS and so many kinds of new chemicals from sodium azide and metal oxide mixtures by XRD. NMS is considered as most stable and reasonable mixture for this types of gas-generating agents.

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회색가스재조합을 이용한 회색가스가중합법 개발 및 3차원 복사열전달에의 적용 (Development of the WSGGM with Gray Gas Regrouping and Application to the 3-Dimensional Radiative Transfer)

  • 김태국;박원희
    • 대한기계학회논문집B
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    • 제30권2호
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    • pp.101-109
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    • 2006
  • The narrow band-averaged transmissivity of $CO_2-H_2O$ mixtures is expressed by multiplying the transmissivities of $CO_2\;and\;H_2O$. Applying the multiplication property of narrow band transmissivities for gas mixtures of $CO_2-H_2O$ of the narrow band based WSGGM (weighted sum of gray gases model), the number of gray gases, required for accurate representation of the absorption characteristics by using the narrow band based WSGGM, is significantly increased. To reduce the computational loads by reducing the number of gray gases, we propose a gray gas regrouping process where the gray gases used for .the WSGGM are regrouped into a specified number of groups according to the magnitudes of absorption coefficients. To evaluate the proposed WSGGM for gas mixtures, the radiative transfer problems through 3-dimensional gas media are considered. The radiative source terms and the radiative heat fluxes obtained by using the proposed method are fairly well compared to previous results obtained by using the SNB model and other models. The regrouping technique results in an excellent computational efficiency with minor loss of accuracy.

회색가스 재조합에 의한 좁은밴드 회색가스가중합법을 이용한 3 차원 복사열전달 해석 연구 (3-Dimensional Radiative Transfer Analysis by Using the Narrow Band Based WSGGM with a Gray Gas Regrouping Technique)

  • 박원희;김태국;손봉세
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2003년도 추계학술대회
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    • pp.284-289
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    • 2003
  • The narrow band-averaged transmissivity of $CO_2-H_2O$ mixtures is expressed by multiplying the transmissivities of $CO_2$ and $H_2O$. Applying the multiplication property of narrow band transmissivities for gas mixtures of $CO_2-H_2O$, the number of gray gases, required for accurate representation of the absorption characteristics by using the narrow band based WSGGM, is significantly increased. To reduce the computational loads by reducing the number of gray gases, we propose a gray gas regrouping process where the gray gases used for the WSGGM are regrouped into a specified number of groups according to the magnitudes of absorption coefficients. To evaluate the proposed WSGGM for gas mixtures, the radiative transfer problems through three-dimensional gas media are considered. The radiative source terms and the radiative heat fluxes obtained by using the proposed method are fairly well compared to those obtained by using the SNB model. The regrouping technique results in an excellent computational efficiency with minor loss of accuracy.

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$SF_6-Ar$-혼합기체(混合氣體)의 전자(電子) 이동속도(移動速度) (Drift Velocities for Electrons in $SF_6$-Ar Mixtures Gas)

  • 김상남;하성철
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2003년도 하계학술대회 논문집 Vol.4 No.2
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    • pp.1102-1105
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    • 2003
  • Energy distribution function for electrons in $SF_6$-Ar mixtures gas used by MCS-BEq algorithm has been analysed over the E/N range $30{\sim}300[Td]$ by a two term Boltzmann equation and by a Monte Carlo Simulation using a set of electron cross sections determined by other authors, experimentally the electron swarm parameters for 0.2(%) and 0.5(%) $SF_6$-Ar mixtures were measured by time-of-flight(TOF) method, The results show that the deduced electron drift velocities, Electrons Drift Velocities for a rang of E/N values. As a consequence, it was known that the spatial growth rates and the dielectric behaviors in $SF_6$-Ar mixtures are strongly dependent on the addition rate of $SF_6$ gas but the transport coefficients of electrons are insensitive to the addition rate of $SF_6$ gas. The results obtained from Boltzmann equation method and Monte Carlo simulation have been compared with present and previously obtained data and respective set of electron collision cross sections of the molecules.

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혼합가스 식별을 위한 반도체식 가스센서의 온라인 드리프트 보상 (On-line drift compensation of a tin oxide gas sensor for identification of gas mixtures)

  • 신중엽;조정환;전기준
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2005년도 학술대회 논문집 정보 및 제어부문
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    • pp.130-132
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    • 2005
  • This paper presents two ART-based neural networks for the identification of gas mixtures subject to the drift. A fuzzy ARTMAP neural network is used for classifying $H_2S$, $NH_3$ and their mixture gases including a reference gas. The other fuzzy ART neural network is utilized to detect the drift of a tin oxide gas sensor by tracking a cluster center of the reference gas. After detecting the drift, the previous cluster center of each gas is updated as much as the drift of the reference gas. By the simulations, the proposed method is shown to compensate the drift on-line without making many categories of target gases compared with the previous studies.

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