• 제목/요약/키워드: Gas Mixtures

검색결과 600건 처리시간 0.03초

Effects of Tropical High Tannin Non Legume and Low Tannin Legume Browse Mixtures on Fermentation Parameters and Methanogenesis Using Gas Production Technique

  • Seresinhe, Thakshala;Madushika, S.A.C.;Seresinhe, Y.;La, P.K.;Orskov, E.R.
    • Asian-Australasian Journal of Animal Sciences
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    • 제25권10호
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    • pp.1404-1410
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    • 2012
  • In vitro experiments were conducted to evaluate the suitability of several mixtures of high tanniniferous non legumes with low tanniniferous legumes on in vitro gas production (IVGP), dry matter degradation, Ammonia-N, methane production and microbial population. Eight treatments were examined in a randomized complete block design using four non-legumes and two legumes (Carallia integerrima${\times}$Leucaena leucocephala (LL) (Trt 1), C. integerrima${\times}$Gliricidia sepium (GS) (Trt 2), Aporosa lindeliyana${\times}$LL (Trt 3), A. lindeliyana${\times}$GS (Trt 4), Ceiba perntandra${\times}$LL (Trt 5), C. perntandra${\times}$GS (Trt 6), Artocarpus heterophyllus${\times}$LL (Trt 7), A. heterophyllus${\times}$GS (Trt 8). The condensed tannin (CT) content of non legumes ranged from 6.2% (Carallia integerrima) to 4.9% (Ceiba perntandra) while the CT of legumes were 1.58% (Leucaena leucocephala) and 0.78% (Gliricidia sepium). Forage mixtures contained more than 14% of crude protein (CP) while the CT content ranged from 2.8% to 4.0% respectively. Differences (p<0.05) were observed in in vitro gas production (IGVP) within treatments over a 48 h period dominated by C. perntandra${\times}$G. sepium (Trt 6). The net gas production (p<0.05) was also high with Trt6 followed by A. heterophyllus${\times}$L. leucocephala (Trt 7) and A. heterophyllus${\times}$G. sepium (Trt 8). Highest (p>0.05) NH3-N (ml/200 mg DM) production was observed with the A. heterophyllus${\times}$G. sepium (Trt 8) mixture which may be attributed with it's highest CP content. The correlation between IVGP and CT was 0.675 while IVGP and CP was 0.610. In vitro dry matter degradation (IVDMD) was highest in Trt 8 as well. Methane production ranged from 2.57 to 4.79 (ml/200 mg DM) to be synonimous with IVGP. A higher bacteria population (p<0.05) was found in C. perntandra${\times}$G. sepium (Trt 6) followed by Artocarpus heterophyllus+G. sepium (Trt 8) and the same trend was observed with the protozoa population as well. The results show that supplementing high tannin non leguminous forages by incremental substitution of legume forage increased gas production parameters, NH3-N, IVDMD and microbial population in the fermentation liquid. Methane production was not significantly affected by the presence of CT or different levels of CP in forage mixtures. Among non legumes, Ceiba perntandra and Artocarpus heterophyllus performed better in mixture with L. leucocephala and G. sepium.

an effective approach to electron-atom/molecule collision study

  • Nakamura, Y.
    • E2M - 전기 전자와 첨단 소재
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    • 제8권6호
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    • pp.806-810
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    • 1995
  • Electron swarm studies to derive electron collision cross sections of atoms and molecules from measurements of electron swarm data are reviewed. Stress is placed on those using molecular gas-rare gas mixtures.

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Optimum Condition for Xe Gas Excitation in Plasma Display Panels through Ternary Gas of He, Ne, Xe

  • Khorami, Alireza;Ghanbari, Shirin
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2009년도 9th International Meeting on Information Display
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    • pp.744-747
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    • 2009
  • Plasma Display Panels (PDPs) have illustrated impressive results in terms of light emission efficiency of the Ne-Xe mixture compared with the He-Xe mixture. However, He-Xe has shown to achieve superior color purity. This paper presents the optimization of excitation efficiency and color purity for He-Ne-Xe ternary gas mixtures. Furthermore, we investigate the effect that a protective dielectric layer has on UV photon efficiency in a matrix known as electrode type PDP.

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Multidimensional Gas Chromatography-A Powerful Tool for the Analysis of Multicomponent Mixtures

  • Kim, Kyoung-Su
    • Preventive Nutrition and Food Science
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    • 제1권1호
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    • pp.127-133
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    • 1996
  • The development of high resolution capillary columns and a large variety of different detectors led to a strong position of gas chromatography in instrumental analysis. Every effort has been made to solve sophisticated separation problems by column switching. Nowadays, several systems are commercially available for this purpose. The principle and the capabilities of multidimensional gas chromatography(MDGC) are illustrated by different applications in the field of modern flavor and essential oil research.

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불평등전계 중에서 $SF_{6}-N_{2}$ 혼합기체의 절연파괴 특성 (Breakdown Characteristics of $SF_{6}-N_{2}$ Mixtures in Nonuniform electric Field)

  • 이복희;이경옥
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2000년도 하계학술대회 논문집 C
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    • pp.1999-2001
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    • 2000
  • Impulse breakdown voltage characteristics of sulphur-hexafluoride/nitrogen ($SF_{6}-N_{2}$) mixtures were presented. The applied voltages were the positive and negative lightning impulse (1.2/44${\mu}s$) and oscillating impulse ($0.4{\mu}s$/2.08MHz) voltages. The predischarge current was observed to clarify the breakdown mechanism. The electrode system was consisted of plane to plane configuration with a needle-shaped protrusion whose length and diameter are 10mm and 1mm. The measurements were carried out at the gas pressure of mixtures up to 0.5MPa with nitrogen concentrations varying from 5 to 20%. The electrical breakdown in $SF_{6}-N_{2}$ mixtures develops with steplike pulses in leader mechanism. The minimum breakdown voltages for the negative lightning and oscillating impulse voltages were higher than those for the positive.

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Estimation of Mass Discrimination Factor for a Wide Range of m/z by Argon Artificial Isotope Mixtures and NF3 Gas

  • Min, Deullae;Lee, Jin Bok;Lee, Christopher;Lee, Dong Soo;Kim, Jin Seog
    • Bulletin of the Korean Chemical Society
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    • 제35권8호
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    • pp.2403-2409
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    • 2014
  • Absolute isotope ratio is a critical constituent in determination of atomic weight. To measure the absolute isotope ratio using a mass spectrometer, mass discrimination factor, $f_{MD}$, is needed to convert measured isotope ratio to real isotope ratio of gas molecules. If the $f_{MD}$ could be predicted, absolute isotope ratio of a chemical species would be measureable in absence of its enriched isotope pure materials or isotope references. This work employed gravimetrically prepared isotope mixtures of argon (Ar) to obtain $f_{MD}$ at m/z of 40 in the magnetic sector type gas mass spectrometer (gas/MS). Besides, we compare the nitrogen isotope ratio of nitrogen trifluoride ($NF_3$) with that of nitrogen molecule ($N_2$) decomposed from the same $NF_3$ thermally in order to identify the difference of $f_{MD}$ values in extensive m/z region from 28 to 71. Our result shows that $f_{MD}$ at m/z 40 was $-0.044%{\pm}0.017%$ (k = 1) from measurement of Ar artificial isotope mixtures. The $f_{MD}$ difference in the range of m/z from 28 to 71 is observed $-0.12%{\pm}0.14%$ from $NF_3$ and $N_2$. From combination of this work and reported $f_{MD}$ values by another team, IRMM, if $f_{MD}$ of $-0.16%{\pm}0.14%$ is applied to isotope ratio measurement from $N_2$ to $SF_6$, we can determine absolute isotope ratio within relative uncertainty of 0.2 %.

Detection for Non-Milk Fat in Dairy Product by Gas Chromatography

  • Kim, Ha-Jung;Park, Jung-Min;Lee, Jung-Hoon;Kim, Jin-Man
    • 한국축산식품학회지
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    • 제36권2호
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    • pp.206-214
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    • 2016
  • The aim of this study was to evaluate the potential use of fatty acids, triacylglycerols, and cholesterol in the detection of adulterated milk fat. The fatty acid, triacylglycerol, and cholesterol profiles of the mixtures of milk and non-milk fat (adulteration ratios of 10%, 30%, 50%, 70%, and 90%) were analyzed by gas chromatography. The results showed that concentrations of the fatty acids with oleic acid (C18:1n9c) and linoleic acid (C18:2n6c), triglycerides with C52 and C54, and cholesterol detected are proportional to the adulteration ratios remarkably. Oleic acid (C18:1n9c), linoleic acid (C18:2n6c), C52, and C54 were lower in pure milk fat than in adulterated mixtures. In contrast, pure milk has a higher cholesterol concentration than all adulterated mixtures (adulteration concentration in the range 10-90%). Thus, we suggest that oleic acid (C18:1n9c), linoleic acid (C18:2n6c), C52, C54, and cholesterol are suitable indicators and can be used as biomarkers to rapidly detect adulterated milk fat by gas chromatography. This study is expected to provide basic data for adulteration and material usage. Moreover, this new approach can detect the presence of foreign oils and fats in the milk fat of cheese and can find application in related studies.

반복 인장-압축하중을 받는 이온질화처리한 SM 45C의 피로파괴거동에 관한 연구 (A Study on the Fatigue Failure Behavior SM45C on Ion-Nitrided under Alternating Tension-Compression Axial Loading)

  • 만창기;김희송
    • 한국정밀공학회지
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    • 제5권3호
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    • pp.71-80
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    • 1988
  • This paper dealt with experimentally the effect of $N_2$ and $H_2$ gas mixtures ratio in the fatigue characteristics of SM45C on Ion-nitrided. The specimen were treated water cooling after Ion-nitriding at $500^{\circ}C$ and 5 torr. in 80% $N_2$and 50% $N_2$gas mixtures ratio in the atmosphere for 3 hrs. The hardness distribution and the depth of nitriding layer shows more increase in 80% $N_2$gas mixture ratio than 50% $N_2$. Ion-nitrided specim- en for 80% $N_2$gas mixture ratio show more increase infatigue strenght in the $>1.5{\times}10^5$ cycles region than 50% $N_2$. In the $<1.5{\times}10^5$cycles region, fatigue failure is due to cracking of the brittle nitrided case, and the propergation of the surface cracks into the core. But in the $>1.5{\times}10^5$cycles region, it is found that cracks propagate from the non-metallic inclusions in the subsurface.

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HBr/Ar/CHF3 혼합가스를 이용한 ZnO 박막의 유도결합 플라즈마 식각 (Etching Characteristics of ZnO Thin Films Using Inductively Coupled Plasma of HBr/Ar/CHF3 Gas Mixtures)

  • 김문근;함용현;권광호;이현우
    • 한국전기전자재료학회논문지
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    • 제23권12호
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    • pp.915-918
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    • 2010
  • In this work, the etching characteristics of ZnO thin films were investigated using an inductively coupled plasma(ICP) of HBr/Ar/$CHF_3$ gas mixtures. The plasma characteristics were analyzed by a quadrupole mass spectrometer (QMS) and double langmuir probe (DLP). The surface reaction of the ZnO thin films was investigated using X-ray photoelectron spectroscopy (XPS). The etch rate of ZnO was measured as a function of the $CHF_3$ mixing ratio in the range of 0-15% in an HBr:Ar=5:2 plasma at a fixed gas pressure (6mTorr), input power (700 W), bias power (200 W) and total gas flow rate(50sccm). The etch rate of the ZnO films decreased with increasing $CHF_3$ fraction due to the etch-blocking polymer layer formation.

초임계조건에서 $CO_2$-PEC9 혼합물의 물성예측을 통한 냉각 열전달특성 연구 (Gas cooling heat transfer coefficient for $CO_2$-PEC9 mixture under supercritical condition)

  • 윤린
    • 대한설비공학회:학술대회논문집
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    • 대한설비공학회 2009년도 하계학술발표대회 논문집
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    • pp.821-826
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    • 2009
  • Due to environmental concerns $CO_2$ has been reintroduced as a potential candidate to replace HFCs in refrigeration systems. Oils are always required in a vapor-compression cycle, and thus actual working fluid in the system is $CO_2$-oil mixtures even though the oil concentrations are low at the heat exchangers and the expansion device. The cooling heat transfer coefficients for $CO_2$-oil mixtures under supercritical condition are required to designing of the gas cooler in the $CO_2$ refrigeration system properly. In the present study, the gas cooling heat transfer coefficients for $CO_2$-PEC9 was estimated by using the Gnileinski correlation, and the Kim and Ghajar model through the previous prediction models for the thermo-physical properties of $CO_2$-oil mixture. The Gnileinski correlation was used when the oil wt.% in the mixture is less than 1.0, and for the higher oil concentration the Kim and Ghajar model was applied. The estimated results agree with the experimental results conducted by the Dang et al.

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