• 열처리공학회지
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• 제26권3호
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• pp.105-112
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• 2013

The microstructural changes of Fe-20Mn-12Cr-1Cu alloy have been studied during high temperature gas nitriding (HTGN) at the range of $1000^{\circ}C{\sim}1150^{\circ}C$ in an atmosphere of nitrogen gas. The mixed microstructure of austenite and ${\varepsilon}$-martensite of as-received alloy was changed to austenite single phase after HTGN treatment at the nitrogen-permeated surface layer, however the interior region that was not affected nitrogen permeation remained the structure of austenite and ${\varepsilon}$-martensite. With raising the HTGN treatment temperature, the concentration and permeation depth of nitrogen, which is known as the austenite stabilizing element, were increased. Accordingly, the depth of austenite single phase region was increased. The outmost surface of HTGN treated alloy at $1000^{\circ}C$ appeared Cr nitride. And this was in good agreement with the thermodynamically calculated phase diagram. The grain growth was delayed after HTGN treatment temperature ranges of $1000^{\circ}C{\sim}1100^{\circ}C$ due to the grain boundary precipitates. For the HTGN treatment temperature of $1150^{\circ}C$, the fine grain region was shown at the near surface due to the grain boundary precipitates, however, owing to the depletion of grain boundary precipitates, coarse grain was appeared at the depth far from the surface. This depletion may come from the strong affinity between nitrogen and substitutional element of Al and Ti leading the diffusion of these elements from interior to surface. Because of the nitrogen dissolution at the nitrogen-permeated surface layer by HTGN treatment, the surface hardness was increased above 150 Hv compared to the interior region that was consisted with the mixed microstructure of austenite and ${\varepsilon}$-martensite.

• 한국수자원학회:학술대회논문집
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• 한국수자원학회 2007년도 학술발표회 논문집
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• pp.46-52
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• 2007

As flue gas desulfurization (FGD) wastewater contains high concentrations of nitrate and is very low in organic carbon, the feasibility of nitrate removal by autotrophic denitrification using Thiobacillus denitrificans was studied. This autotrophic bacteria oxidizes elemental sulfur to sulfate while reducing nitrate to elemental nitrogen gas, thereby eliminating the need for addition of organic compounds such as methanol. Owing to the unusually high concentrations of dissolved salts $(Ca^{2+},\;Mg^{2+},\;Na^+,\;K^+,\;B^+,\;SO_4^{2-},\;Cl^-,\;F^-,)$ in the FGD wastewater, extensive laboratory-scale and pilot-scale tests were carried out in sulfur-limestone reactors (1) to determine the effect of salinity on autotrophic denitrification, (2) to evaluate the use of limestone for pH control and as source of inorganic carbon for microbial growth, and, (3) to find the optimum environmental and operational conditions for autotrophic denitrification of FGD wastewater. The experimental results demonstrated that (1) autotrophic denitrification is not inhibited up to 1.8 mol total dissolved salt content; (2) inorganic carbon and inorganic phosphorus must be present in sufficiently high concentrations; (3) limestone can supply effective buffering capacity and inorganic carbon; (4) the high calcium concentration may interfere with pH control, phosphorus solubility and limestone dissolution, hence requiring pretreatment of the FGD wastewater; and, 5) under optimum conditions, complete autotrophic denitrification of FGD wastewater was obtained in a sulfur-limestone packed bed reactor with a sulfur:limestone volume ratio of 2:1 for volumetric loading rates up to 400g $NO_{3^-}N/m^3.d$. The interesting interactions between autotrophic denitrification, pH, alkalinity, and the unusually high calcium and boron content of the FGD wastewater are highlighted. The engineering significance of the results is discussed.

• 한국세라믹학회지
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• 제28권8호
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• pp.625-625
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• 1991

2wt% Al2O3와 10wt% Al2O3를 첨가하여 2000℃와 2050℃에서 가압소결된 SiC를 37 mol% NaCl과 63 mol% Na2SO4 Salt에 의해 60분까지 hot corrosion을 시켰다. 부식은 SiC표면에 형성된 SiO2층이 Na2O 이온에 의한 basic dissolution에 이해 일어남이 관찰되었고 10wt%의 Al2O3가 함유된 시편은 입계에 Al2O3를 함유한 입계상의 존재로 2wt% Al2O3가 함유된 시편보다 낮은 corrosion rate를 나타냈다. SiC와 산화물층 사이에서 gas bubble의 형성이 관찰되었고 이 gas bubble이 산화물층을 심하게 파괴하기 전까지 corrosion rate은 linear하게 변했다. 부식 양상은 개기공과 입계에서 pitting corrosion에 의해 시작되었다.

• Bulletin of the Korean Chemical Society
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• 제34권6호
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• pp.1625-1631
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• 2013

We report a facile synthetic approach of high-quality chromium(III) terephthalate [MIL-101(Cr)] by acetate-assisted method in the absence of toxic HF. Results indicate that the morphology and surface area of the MIL-101(Cr) can be tuned by modifying the molar ratio of acetate/$Cr(NO_3)_3$. The Brunauer-Emmett-Teller (BET) surface area of MIL-101(Cr) synthesized at the optimized condition can exceed 3300 $m^2/g$. It is confirmed that acetate could promote the dissolution of di-carboxylic linker and accelerate the nucleation ratio. So the pure and small size of MIL-101(Cr) with clean pores can be obtained. $CO_2$, $CH_4$ and $N_2$ adsorption isotherms of the samples are studied at 298 K and 313 K. Compared with the traditional method, MIL-101(Cr) synthesized by acetate-assisted method possess enhanced $CO_2$ selective adsorption capacity. At 1.0 bar 298 K, it exhibits 47% enhanced $CO_2$ adsorption capacity. This may be attributed to the high surface area together with clean pores of MIL-101(Cr).

• 한국포장학회지
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• 제22권3호
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• pp.79-84
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• 2016

A kimchi container actively controlling $CO_2$ concentration by timely flushing of $CO_2$ gas was structured and tested in its capability and effectiveness because high $CO_2$ concentration enhances the sensory flavor of the product. The inlet and outlet valves of $CO_2$ gas were programmed to open and close allowing synchronous vent/$CO_2$ flush according to the requirements of its dissolution in the contained kimchi. During the chilled storage, the headspace of container could be maintained at desired high $CO_2$ concentration providing the preferred kimchi in sensory quality compared to control of the conventional container. However, there was no significant difference between the high $CO_2$ container and control (container simply closed with air) in kimchi quality attributes of pH, titratable acidity, total viable bacterial count, Lactobacillus sp. count and Leuconostoc sp. count. The flow rate and time interval of $CO_2$ flushing need to be adjusted considering the kimchi amount, headspace volume and ripening time. The designed system has potential to be applied in refrigerator appliances in homes and food service industry.

• Journal of Welding and Joining
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• 제16권6호
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• pp.59-68
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• 1998

In this study, effects of solidification modes (primary $\delta$-ferrite, primary ${\gamma}$-austenite) on the pit initiation and propagation in the 304L and 316L austenitic stainless steel weld metals were investigated. The solidification mode of weld metal was controlled by the addition of nitrogen to Ar shielding gas. Through the electrochemical experiments (potentiodynamic anodic polarization and potentiostatic time-current transient test) and metallographic examination (microstructure and elemental distribution), the following results were obtained. The more the volume content of nitrogen in the shielding gas were, the lower critical current density for passivity was observed. In comparison with weldments solidified through the primary $\delta$-ferrite solidification mode and the primary ${\gamma}$-solidification mode, the former showed higher critical pitting potential and a longer incubation time for stable pit initiation than the latter. However, in the pit propagation stage the former exhibited a faster dissolution rate than the latter. These results were believed to ee related to the distribution of alloying elements such as Cr, Mo, Ni and S.

• Macromolecular Research
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• 제15권4호
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• pp.343-347
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• 2007

Novel composite membranes, which delivered high separation performance for propylene/propane mixtures, were developed by coating inert poly(ethylene-co-propylene) rubber (EPR) onto a porous polyester substrate, followed by the physical distribution of $AgBF_4$. Scanning electron microscopy-wavelength dispersive spectrometer (SEM-WDS) revealed that silver salts were uniformly distributed in the EPR layer. The physical dispersion of the silver salts in the inert polymer matrix, without specific interaction, was characterized by FT-IR and FT-Raman spectroscopy. The high separation performance was presumed to stem from the in-situ dissolution of crystalline silver ionic aggregates into free silver ions, which acted as an active propylene carrier within a propylene environment, leading to facilitated propylene transport through the membranes. The membranes were functional at all silver loading levels, exhibiting an unusually low threshold carrier concentration (less than 0.06 of silver weight fraction). The separation properties of these membranes, i.e. the mixed gas selectivity of propylene/propane ${\sim}55$ and mixed gas permeance ${\sim}7$ GPU, were stable for several days.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2009년도 추계학술대회 논문집
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• pp.132-132
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• 2009

To achieve the commercialization of PEM fuel cell, the durability problem must be solved. Recently, many researchers have focused on this durability problem and degradation studies about membrane and electrode have been reported. But durability characteristics of gas diffusion layer is not much reported yet. Durability of GDL is very important to maintain the performance of PEM fuel cell because the main function of GDL is a path of fuel and water and the GDL degradation causes the loss of the GDL function. In this study, the degradation of GDL, especially, the mechanical degradation process was investigated with the leaching test. The effect of water dissolution was observed through the test and the amount of GDL degradation was measured with various measurement methods such as weight measurement, static contact angle measurement, scanning electron microscope. After 2,000 hours test, the GDL showed structural damage and loss of hydrophobicity.

• 한국재료학회지
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• 제18권8호
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• pp.438-443
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• 2008

SnO nanosheets were prepared at room temperature through a reaction between an aqueous solution of $SnCl_2$, $N_2F_4$, and NaOH and were converted into $SnO_2$ nanosheets without a morphological change. The SnO nanosheets were formed through a dissolution-recrystallization mechanism. Uniform and well-dispersed SnO nanosheets with the round-shape morphology were attained when the solution was treated by ultrasonic sound immediately after the addition of NaOH. The $SnO_2$ nanosheets prepared by means of solution reduction under the ultrasonic treatment, and subsequent oxidation at $600^{\circ}C$ showed a high level of gas sensitivity to $C_2H_5OH$ and $CH_3COCH_3$.

• 해양환경안전학회지
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• 제27권7호
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• pp.1116-1123
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• 2021

해수에 유출된 유류는 대기와 해수와의 접촉을 통해 다양한 풍화 과정(증발, 확산, 분산, 유화, 용해, 산화, 침전 및 생물분해 등)을 통해 물리·화학적 변화와 함께 생물학적 분해과정을 겪는다. 본 연구에서는 여러 가지 풍화작용 중 가장 즉각적이고 빠르며 오염물질의 질량에 가장 큰 영향을 미치는 인자라고 알려진 증발(evaporation)에 대한 영향을 확인해보고자 하였다. 휘발유, 등유, 경유를 대상으로 25 ℃(해수 연평균 온도)와 35℃(적도 부근 온도) 조건에서 유류의 휘발특성을 비교하였다. 이를 위해, 일정 기간마다 채취한 유류를 전처리하여 GC/MS 분석을 수행하고, 탄화수소의 변화량을 계산하여 비교하였다.