• 한국가스학회지
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• 제19권4호
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• pp.29-34
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• 2015

화학물질을 다루는 실험실의 안전사고는 매년 끊이지 않고 있다. 특히 대학 내 실험실은 학생들이 주된 연구자로써 지식과 능력을 쌓아가고 경험을 축적하는 곳이기에 실험실의 안전은 더욱 중요하다. 학 내 실험실에서 주로 사용하는 5가지의 가스(CO, $NH_3$, $H_2$, $CH_4$, $N_2$)를 선정하여 이 가스들이 누출 될 경우의 시나리오들로부터 확산 과정을 PHAST v.6.7로 계산, 분석함으로써 피해 정도를 예측하였다. 실험실 내부 확산과정은 Computational Fluid Dynamics(CFD) 프로그램 FLUENT를 통하여 모델링하였다. 가스 누출 시 실험실 창을 통해 외부로 유출 될 경우 실내와 실외의 피해 영향에 대해서도 비교하였다. 각 가스들의 모델링 결과를 보면, 실험실 외부보다는 실험실 내부에서 그 피해 정도가 훨씬 큰 데, 학 내 실험실에서 일반적으로 사용하는 가스 용기, 즉 실린더의 용량은 47 L(혹은 그 이하)로 ton 단위로 사용하는 사업장에 비하면 그 양이 현저히 적기 때문에 실외의 영향이 플랜트와 비교해서 현저히 작다. 하지만 시뮬레이션 결과 작은 양으로도 실내에서는 큰 피해가 발생할 수 있음을 보여준다.

• Journal of Mechanical Science and Technology
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• 제16권8호
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• pp.1127-1134
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• 2002

The effects of pressure and temperature on the autoignition of propane and n-butane blends were investigated using a rapid compression machine (RCM) , which is widely used to examine the autoignition characteristics. The RCM was designed to be capable of varying the compression ratio between 5 and 20 and minimize the vortex formation on the cylinder wall using a wedge-shaped crevice. The initial temperature and pressure of the compressed gas were varied in range of 720∼900 K and 1.6∼ 1.8 MPa, respectively, by adjusting the ratio of the specific heat of the mixture by altering the ratio of the non-reactive components (N$_2$, Ar) under a constant effective equivalence ratio (ø$\_$f/= 1.0) The gas temperature after the compression stroke could be obtained from the measured time-pressure record. The results showed a two-stage ignition delay and a Negative Temperature Coefficient (NTC) behavior which were the unique characteristic of the alkane series fuels. As the propane concentration in the blend were increased from 20% and 40% propane, the autoignition delay time increased by approximately 41 % and 55% at 750 K. Numerical reduced kinetic modeling was performed using the Shell model, which introduced some important chemical ideas, represented by the generic species. Several rate coefficients were calibrated based on the experimental results to establish an autoignition model of the propane and n-butane blends. These coefficients can be used to predict the autoignition characteristics in LPG fueled Sl engines.

• 한국해양공학회지
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• 제30권2호
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• pp.91-99
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• 2016

The global demand for oil and natural gas has increased, and resource development is moving to the deep sea. Floating and flexible offshore structures such as semi-submersible, spar, and FPSO structures have been widely used. The major equipment of floating structures is always exposed to waves, currents, and other marine environmental factors, which cause structural damage. Moreover, flexible risers are susceptible to an exciting force due to the motion of the floating body. The inline and transverse responses from the three-dimensional behavior of a floating structure occur because of various forces. Typical risers are made of steel pipe and applied in the oil and gas development field, but flexible materials such as polyethylene are suitable for OTEC risers. Consequently, the optimal design of a flexible offshore plant requires a dynamic behavior analysis of slender bodies made of the different materials commonly used for offshore flexible risers. In this study, a three-dimensional motion measurement device was used to analyze the displacements of riser models induced by external force factors, and forced oscillation of a riser was linked to forced oscillation under a steady flow and regular wave condition.

• 한국환경과학회지
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• 제27권10호
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• pp.809-820
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• 2018

DeNOx experiments for the effects of hydrocarbon additives on diesel SNCR process were conducted under oxidizing diesel exhaust conditions. A diesel-fueled combustion system was set up to simulate the actual cylinder and head, exhaust pipe and combustion products, where the reducing agent $NH_3$ and $C_2H_6/diesel$ fuel additives were separately or simultaneously injected into the exhaust pipe, used as the SNCR flow reactor. A wide range of air/fuel ratios (A/F=20~40) were maintained, based on engine speeds where an initial NOx level was 530 ppm and the molar ratios (${\beta}=NH_3/NOx$) ranged between 1.0~2.0, together with adjusting the amounts of hydrocarbon additives. Temperature windows were normally formed in the range of 1200~1350K, which were shifted downwards by 50~100K with injecting $C_2H_6/diesel$ fuel additives. About 50~68% NOx reduction was possible with the above molar ratios (${\beta}$) at the optimum flow #1 ($T_{in}=1260K$). Injecting a small amount of $C_2H_6$ or diesel fuel (${\gamma}=hydrocarbon/NOx$) gave the promising results, particularly in the lower exhaust temperatures, by contributing to the sufficient production of active radicals ($OH/O/HO_2/H$) for NOx reduction. Unfortunately, the addition of hydrocarbons increased the concentrations of byproducts such as CO, UHC, $N_2O$ and $NO_2$, and their emission levels are discussed. Among them, Injecting diesel fuel together with the primary reductant seems to be more encouraging for practical reason and could be suggested as an alternative SNCR DeNOx strategy under diesel exhaust systems, following further optimization of chemicals used for lower emission levels of byproducts.

• 한국입자에어로졸학회지
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• 제13권3호
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• pp.119-125
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• 2017

A novel two stage cylindrical cyclone was developed for a 3 phase separator in shale oil production industry. The cyclone performance was compared with a cone type cyclone and multi cyclone at the same experimental condition using water and oil mists generated by a humidifier and atomizer at the flow rate 1 to $2m^3/min$. The removal efficiency of total suspended water droplets by the novel cyclone, calculated using inlet and outlet concentrations measured by an optical particle counter, was 99% which is higher than 90% of oil droplet removal efficiency at $2m^3/min$. It might be due to the evaporation of small water droplets during the tests. The water and oil droplet removal performance of the novel cyclone based on the quality factor which is a function of pressure drop and removal efficiency was the highest among three cyclones. The results indicate that the cyclone could be an economical device to remove water and oil mists from shale gas generation processes where a huge three phase separator is commonly used.

• Journal of Trauma and Injury
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• 제24권2호
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• pp.129-135
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• 2011

Purpose: During August 2010, a natural gas fuel cylinder on a bus exploded in downtown Seoul, injuring 20 citizens. This kind of blast injury has never been reported in Korea before. Thus, the goal of this study was to review the clinical features of these victims to help physicians manage similar cases and to understand the risk factors associated with blast injuries in everyday life. Methods: Twenty (20) victims who visited nearby emergency departments, and 3 peoples left hospital without care. Seventeen (17) victims were included in this study, and the following factors were investigated: age, sex, type of hospital, diagnosis of injury, injury mechanism, position of victim (in-bus/out of bus), classification of injury severity with START (simple triage and rapid treatment), and classification of injury according to the mechanism of the blast injury. Results: The victims included 8 males (47%), 9 females (53%). The mean age was $37.5{\pm}12$. Thirteen (13) victims were transferred to two tertiary hospitals, and 4 were transferred to two secondary hospitals. The types of injury were 3 fractures, 2 ligaments injuries, 6 contusions, 4 abrasions, and 3 open wounds (one of them was combined fracture). According to START classification, 17 victims were 1 immediate, 11 minor, 5 delayed, and no death. Classifications according to the mechanism of the blast injury were 1 primary injury, 6 secondary injuries (2 of them combined other mechanism), 3 tertiary injuries and 9 quaternary injuries. Conclusion: Trauma care physicians should be familiar with not only the specific types of injuries from blast accidents, but also the potential accidents that may occur in public facilities.

• 한국가스학회지
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• 제17권1호
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• pp.26-34
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• 2013

상 변화(phase change)를 수반한 다상 유동 연구(multiphase flow analysis)는 증발, 응축과 같은 많은 분야에 적용, 응용될 수 있고 현상의 복잡성 때문에 많은 연구의 관심을 받고 있는 분야이다. 본 연구에서는 극저온 유체인 액화질소가 다양한 밀도의 글라스 울 내부 다공성 매질속으로 스며들면서 나타나는 거동을 살펴보았다. 유동에 영향을 미치는 투과성 계수에 대해서, 외부 압력의 영향성에 대한 실험을 진행하였고 논의하였다. 극저온 유체인 액화질소를 실험유체로 사용하여 사각 기둥 실린더 내부의 유체의 유동에 대한 실험으로 유체의 유동을 살펴보았다. 그 결과 벌크 밀도가 커짐에 따라 투과성 계수가 작아지고, 거리에 따른 압력변화의 비선형성이 커짐을 보였다. 마지막으로 CFD 전산유동 프로그램으로 실험결과와 동일한 상황을 모사하였으며, 이를 실험결과와 비교 분석하였다. 이에 대한 검증결과, 시뮬레이션 결과가 실험결과와 유사한 경향과 결과를 보여주었다.

• Journal of Advanced Marine Engineering and Technology
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• 제37권7호
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• pp.701-710
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• 2013

The purpose of this study is to investigate experimentally the effect of low purity methanol (LPM) on performance and smoke emission characteristics by using a four-cycle, four-cylinder, water-cooled, direct injection diesel engine with EGR system. The experiments are performed by the change of engine load in the engine load ranges of 25 to 100% with an interval of 25% under the constant engine speed of 2000 rpm. The LPM in the fuel blends contained 24.88% water by volume. The blended fuel ratios of diesel oil to LPM are maintained at 100/0, 95/5, 90/10 and 85/15% on the volume basis. In this paper, EGR rates are varied in three conditions of 0, 12.8 and 16.5%. The result shows that the brake power of a blended fuel with 15% LPM is reduced more 11.1% than that of the neat diesel oil at the full load with the EGR rate of 16.5%. At this condition, also, the brake specific fuel consumption (BSFC) is increased by 3.2%, the exhaust gas temperature is decreased by 10.7%, the smoke opacity is decreased by 18.7% and the brake thermal efficiency is increased by 7.3%. The sharp reduction of smoke opacity for a blended fuel with the LPM content of 15% at the full load without EGR system is observed by 68.4% compared with that of the neat diesel oil due to the high oxygen content of LPM.

• 한국에너지공학회:학술대회논문집
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• 한국에너지공학회 2010년도 춘계학술 발표회
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• pp.43-43
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• 2010

국내에 천연가스버스가 보급된 이래 5차례의 용기파열 사고가 발생하였는데 그중 2005년 8월 전주 덕진충전소에서 발생한 용기파열사고는 CNG용기의 라이너를 감싸고 있는 복합재료가 손상되어 발생한 사고로 보고되었다. 복합재료용기의 외피손상이 원인이 되어 발생한 사고사례는 해외에서 약 13건이 보고되었다. CNG용기 외피손상은 용기룰 고정하는 스트랩과 밀접한 관련이 있다. 용기고정이 불완전하면 슬립이 발생하고 이는 복합재의 손상으로 이어진다. 본 연구에서는 ISO 19078, CGA C6.4 등 국제코드의 규정을 고려하여 국내에서 제조된 Type 2, 3, 4 용기와 외국에서 생산된 Type 3 용기를 대상으로 결함깊이, 길이, 넓이에 따른 복합재료 결함 내구성시험을 수행하여 CNG용기의 내구성능을 평가하였고, 시험과 동일한 조건으로 복합재료 손상결함 조건을 컴퓨터로 전산모사하여 시험결과의 타당성과 유효성을 비교 검증하였다. 실험결과, Type 2 용기의 경우, 11,250회의 최소반복가압 회수를 충족하였으나 외피손상부와 반복가압에 따른 실제누출부위가 일치하지 않아 실험조건을 달리한 추가실험이 요구되었다. Type 3 용기의 경우에는 복합재 결함부위와 누수부위가 일치된 시험용기의 수는 67%정도로, 복합재료 용기의 수명을 저하시키는 원인으로 라이너와 외피손상이 서로 밀접한 관련이 있음을 확인하였다. Type 4 용기는 국제기준에서 요구하는 반복횟수를 만족하였고, 손상깊이 0.75mm와 1.25mm에서 반복가압회수가 60,000회 이상이 되어도 누설이 발생되지 않았다. 이는 라이너의 재질이 폴리머로서 균일한데다 탄소섬유 복합재료층 위에 유리섬유 복합재료 층이 1.5mm 정도 추가로 적층되어 있어서 3등급의 손상결함(결함깊이 1.25mm)에서도 구조 층이 전혀 손상되지 않은 것으로 판단되며, 이는 Type 2 용기의 강재라이너나 Type 3의 알루미늄 라이너와 비교하여 Type 4 용기의 폴리에틸렌 라이너의 물성이 반복성능이 탁월함을 확인할 수 있었다.

• 한국가스학회지
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• 제18권6호
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• pp.1-6
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• 2014

이 연구는 가연성 액체물질인 methanol, tetrahydrofuran, xylene의 온도와 풍속에 따른 증발속도에 대하여 실험을 통해 조사하였다. 측정하고자하는 물질의 양은 약 24 g을 기준으로 하였고 혼합물질의 경우 24 g을 기준으로 하여 각각 같은 비율로 혼합하여 사용하였다. 또한 풍속에 대한 영향을 살펴보기 위하여 소형선풍기를 용기 입구 높이 약 10 cm, 측방향 30 cm의 위치에 설치하고 풍속계를 이용하여 풍속을 측정하였다. 대기속도에 대한 영향을 알아보기 위하여 풍속을 0 m/s, 1.63 m/s, 2.03 m/s로 변화시켜 실험하였고 온도의 미치는 영향은 $21^{\circ}C$, $32^{\circ}C$, $52^{\circ}C$로 변화시켜가며 항온조에서 조절하여 실험하였다. 그 결과 Xylene의 경우 1.4 mg/min, Tetrahydrofuran 19.8 mg/min, Methanol 10.2 mg/min의 속도로 차이 큰 것을 알 수 있었으며 또한 온도와 풍속에 대한 영향이 아주 민감한 것으로 나타났다. 또한 혼합물의 경우도 각 단일 물질의 평균 증발속도와의 차이가 큰 것을 알 수 있었다.