• Journal of the Korea Concrete Institute
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• v.21 no.4
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• pp.409-417
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• 2009

In this study, autogenous crack healing and artificial crack healing using electrochemical electro deposition method were conducted to compare in the aspects of corrosion monitoring. Furthermore, the analysis of impressed voltage characteristics, galvanic current and linear polarization resistance comparison, and photo image processing technique were performed for quantitative comparisons of healing ratio. As a result, it was found that, in view of impressed voltage of artificial crack healing, the measured voltage was increased as time goes by. From the galvanic test results of artificial crack healing, the current vs. potential distribution value were formed widely in comparison with autogenous crack healing. In this point, it was shown that artificial crack healing has more eleatic resistance capacity than autogenous crack healing technique. Finally, it was found that artificial crack healing was 1.63 times higher than autogenous healing in view of crack healing ratio.

• Proceedings of the Materials Research Society of Korea Conference
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• 2012.05a
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• pp.55.2-55.2
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• 2012

Intensive theoretical and experimental studies have been carried out at Korean Institute of Science and Technology (KIST) on controlling the bio absorbing rate of the Mg alloys with high mechanical strength through tailoring of electrochemical potential. Key technology for retarding the corrosion of the Mg alloys is to equalize the corrosion potentials of the constituent phases in the alloys, which prevented the formation of Galvanic circuit between the constituent phases resulting in remarkable reduction of corrosion rate. By thermodynamic consideration, the possible phases of a given alloy system were identified and their work functions, which are related to their corrosion potentials, were calculated by the first principle calculation. The designed alloys, of which the constituent phases have similar work function, were fabricated by clean melting and extrusion system. The newly developed Mg alloys named as KISTUI-MG showed much lower corrosion rate as well as higher strength than previously developed Mg alloys. Biocompatibility and feasibility of the Mg alloys as orthopedic implant materials were evaluated by in vitro cell viability test, in vitro degradation test of mechanical strength during bio-corrosion, in vivo implantation and continuous observation of the implant during in vivo absorbing procedures. Moreover, the cells attached on the Mg alloys was observed using cryo-FIB (focused ion beam) system without the distortion of cell morphology and its organ through the removal of drying steps essential for the preparation of normal SEM/TEM samples. Our Mg alloys showed excellent biocompatibility satisfying the regulations required for biomedical application without evident hydrogen evolution when it implanted into the muscle, inter spine disk, as well as condyle bone of rat and well contact interface with bone tissue when it was implanted into rat condyle.

• Journal of the Korean Institute of Gas
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• v.5 no.3 s.15
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• pp.45-50
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• 2001

Open rack vaporizer (ORV) has been used in liquefied natural gas (LNG) receiving terminal in order to vaporize LNG into natural gas (NG) by heat exchange with seawater The U-type ORV which had been operated with seawater for 14 years is one of the important utilities of the gas production and the weld part of tube connected with header_ pipe had experienced many corrosion problems. To elucidate the cause of corrosion at weld part of vaporizer tube, corrosion potentials were compared by parts. This study concerns on the measurement of corrosion pit depth using non-destructive method and the evaluation of stress distribution in an aspect of safety with finite element analysis. In order to confirm the reliability of galvanic corrosion between weld parts and base metal, the measurement of corrosion potential by parts was conducted for 20 minutes in 3.5$\%$(wt.) NaCl solution. Many non-destructive methods were tried to measure the remaining thickness of vaporizer tube at fields. For general corrosion, tangential radiography test was confirmed as an effective method. In case of a fine corrosion pit, the shape of corrosion pit was reproduced using surface replication method. From collected data, stress distributions were quantitatively evaluated with 2-dimensional finite element method and the diagnostic evaluation on internal pressure of the U-type vaporizer could be made.

• Journal of Ocean Engineering and Technology
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• v.27 no.3
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• pp.79-84
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• 2013

The seawater pipes in the engine rooms of ships are surrounded by severely corrosive environments caused by fast flowing seawater containing chloride ions, high conductivity, etc. Therefore, it has been reported that seawater leakage often occurs at a seawater pipe because of local corrosion. In addition, the leakage area is usually welded using shielded metal arc welding with various electrodes. In this study, when seawater pipes were welded with four types of electrodes(E4311, E4301, E4313, and E4316), the difference between the corrosion resistance values in their welding zones was investigated using an electrochemical method. Although the corrosion potential of a weld metal zone welded with the E4316 electrode showed the lowest value compared to the other electrodes, its corrosion resistance exhibited the best value compared to the other electrodes. In addition, a heat affected zone welded with the E4316 electrode also appeared to have the best corrosion resistance among the electrodes. Furthermore, the corrosion resistance of the weld metal zone and heat affected zone exhibited relatively better properties than that of the base metal zone in all of the cases welded with the four types of electrodes. Furthermore, the hardness values of all the weld metal zones were higher than the base metal zone.

• Journal of Ocean Engineering and Technology
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• v.28 no.4
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• pp.356-362
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• 2014

Wear and corrosion of the engine parts surrounded with combustion chamber is more serious compared to the other parts of the engine because temperature of the exhaust gas in a combustion chamber is getting higher and higher with increasing of using the heavy oil of low quality. Therefore, an optimum repair weldment as well as an available choice of the base metal for these parts are very important to prolong their lifetime in a economical point of view. It reported that there was an experimental result for repair weldment on the forged steel which would be generally used with piston crown material, however, it is considered that there is no study for the repair weldment on the cast steel of piston crown material. In this study, four types of electrodes such as 1.25Cr-0.5Mo, 0.5Mo Inconel 625 and 718 were welded with SMAW and GTAW methods on the cast steel which would be generally used with piston crown material. And the corrosion properties of weld metal, heat affected zone and base metal were investigated using electrochemical methods such as measurement of corrosion potential, anodic polarization curves, cyclic voltammogram and impedance etc. in 35% $H_2SO_4$ solution. In the cases of Inconel 625, 718, the weld metals and base metals exhibited the best and worst corrosion resistance respectively, however, 1.25Cr-0.5Mo and 0.5Mo indicated that corrosion resistance of the base metal was better than the weld metal. And the weld metal welded with electrodes of Inconel 625 revealed the best corrosion resistance among the electrodes, and Inconel 718 followed the Inconel 625. Hardness relatively also indicated higher value in the weld metal compared to heat affected zone and base metal. In particular, Inconel 718 indicated the highest value of hardness compared to other electrodes in the heat affected zone.

• Journal of Advanced Marine Engineering and Technology
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• v.38 no.4
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• pp.409-417
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• 2014

Since the oil price has been significantly jumped for recent some years, the diesel engine of the merchant ship has been mainly used the heavy oil of low quality. Thus, it has been often exposed to severely corrosive environment more and more because temperature of the exhaust gas in a combustion chamber is getting higher and higher with increasing of using the heavy oil of low quality. As a result, wear and corrosion of most parts surrounded with combustion chamber is more serious compared to the other parts of the engine. Therefore, an optimum weldment for these parts is very important to prolong their lifetime in a economical point of view. In this study, four types of filler metals such as Inconel 625, 718, 1.25Cr-0.5Mo and 0.5Mo were welded with SMAW and GTAW methods in the forged steel which would be generally used with piston crown material. And the corrosion properties of weld metal, heat affected zone and base metal were investigated using electrochemical methods such as measurement of corrosion potential, anodic polarization curves, cyclic voltammogram and impedance etc. in 35% H2SO4 solution. The weld metal and base metal exhibited the best and worst corrosion resistance in all cases of filler metals. In particular, the weld metal welded with filler metals of Inconel 718 revealed the best corrosion resistance among the filler metals, and Inconel 625 followed the Inconel 718. Hardness relatively indicated higher value in the weld metal compared to the base metal. Furthermore, Inconel 625 and 718 indicated higher values of hardness compared to 1.25cr-0.5Mo and 0,5Mo filler metals in the weld metal.

• Environmental Engineering Research
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• v.19 no.4
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• pp.363-367
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• 2014

One chambered sediment microbial fuel cell (SMFC) was equipped with Fe, brass (Cu/Zn), Fe/Zn, Cu, Cu/carbon cloth and graphite felt anode. Graphite felt was used as common cathode. The SMFC was membrane-less and mediator-less as well. Order of anodic performance on the basis of power density was Fe/Zn ($6.90Wm^{-2}$) > Fe ($6.03Wm^{-2}$) > Cu/carbon cloth ($2.13Wm^{-2}$) > Cu ($1.13Wm^{-2}$) > brass ($Cu/Zn=0.24Wm^{-2}$) > graphite felt ($0.10Wm^{-2}$). Fe/Zn composite anode have twisted 6.73% more power than Fe alone, Cu/carbon cloth boosted power production by 65%, and brass (Cu/Zn) produced 65% less power than Cu alone. Graphite felt have shown the lowest electricity generation because of its poor galvanic potential. The estuarine sediment served as supplier of oxidants or electron producing microbial flora, which evoked electrons via a complicated direct microbial electron transfer mechanism or making biofilm, respectively. Oxidation reduction was kept to be stationary over time except at the very initial period (mostly for sediment positioning) at anodes. Based on these findings, cost effective and efficient anodic material can be suggested for better SMFC configurations and stimulate towards practical value and application.

• Journal of Advanced Marine Engineering and Technology
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• v.37 no.8
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• pp.877-885
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• 2013

A seawater pipe of the engine room in the ships is being surrounded with severely corrosive environments caused by fast flowing of the seawater, containing aggressive chloride ion and high conductivity etc.. Therefore, the leakage of the seawater from its pipe have been often occurred due to its local corrosion by aggressive chloride ions. Subsequently, its leakage area is usually welded by AC shielded metal arc welding with various electrodes. In this study, when the sea water pipe is welded with several types of electrodes such as E4301, E4311, E4313 and E4316, a difference of the corrosion resistance on the welding metal zones was investigated using an electrochemical method, observing microstructure, measuring polarization behaviors and hardness. The weld metal zone welded with E4313 electrode exhibited the lowest value of hardness compared to other weld metal zones. In addition, its zone indicated also the best corrosion resistance than those of other weld metal zones. Furthermore, all of the weld metal zones revealed a relatively better corrosion resistance than those of the base metal zones. and also showed higher hardness than the base metal zones.

• Journal of the Korea Concrete Institute
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• v.21 no.5
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• pp.565-572
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• 2009

In this study, corrosion resistance of palm oil fuel ash (POFA) concrete as a blended concrete is evaluated by using electrochemical technique. The POFA is an industrial byproduct obtained from fuel ash after extracting palm oil from palm-tree. In order to obtain basic material characteristics of the POFA concrete, tests on compressive strength, slump, weight loss, bleeding and expansion ratio were carried out the early-aged POFA concrete. On the other hand, durability characteristics, both chloride penetration and carbonation depth test, were also conducted. Finally, corrosion resistance were evaluated by applying electro-chemical artificial crack healing technique, and the tests on the impressed voltage characteristic, galvanic current and linear polarization resistance. From the experimental results, it was found that long-term strength, bleeding, lower slump ratio, expansion ratio, chloride penetration, carbonation and corrosion resistance were improved by using the POFA due to activated pozzolanic reaction. It can be also mentioned that POFA concrete has a potential to be used as a cementitious binder for green-recycling resources.