• Title/Summary/Keyword: GOES IR

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Objectification and validation of typhoon center intensity analysis based on MTSAT-1R satellite's infrared images (MTSAT-1R 위성 적외영상기반 태풍강도분석 객관화와 검증)

  • Park, Jeong-Hyun;Park, Jong-Seo;Kim, Baek-Min;Lee, Hee-Hoon
    • Proceedings of the KSRS Conference
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    • 2007.03a
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    • pp.219-223
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    • 2007
  • GMS(Geostational Meteorological Satellite), GOES(Geostationary Operational Environmental Satellite), MTSAT(Multi-Funcional Transport Satellite) 등의 정지기상위성은 거의 매시간 기상상황을 감시하고 태풍정보를 실시간 분석할 수 있어 드보락(Dvorak, 1975)등에 의해 이를 이용한 가시영상이나 적외영상기반의 태풍중심강도를 분석기법(드보락의 VIS/IR 분석법) 및 적외강조영상 분석기법(드보락의 EIR 분석법)이 개발되었다(Dvorak,1975, 1984). 그러나 주관적인 드보락의 VIS/IR 분석 법 및 EIR 분석법에 의한 결과는 분석자마다 다를 수 있고,절차 또한 복잡하여 시급성을 요하는 태풍 분석에서 취약점으로 지적되어 왔다. 이러한 주관적 방법의 한계를 극복하기 위하여 디지럴화된 영상과 자동 객관화된 알고리즘을 적용하는 객관 드보락 기법 (Advanced Objective Dvorak Technique, 이하 AODT)이 개발되었고(Velden et al, 1998), Zehr(1989)에 의해 비행기 관측자료등을 통해 보정되고 있다. 기상청에서는 2001 년부터 GMS 위성 관측영상을 이용하여 태풍의 중심위치를 분석하고,태풍강도를 정량화하기 위해 주관 드보락 기법 (Subjective Dvorak Technique 이하 SDT)을 이용하여 태풍중심위치와 강도정보를 실시간 예보관 및 일반인에게 제공하고 있다. 그러나 주관적인 드보락 기법이 분석자에 따라 다른 결과가 도출 될 수 있어, 이를 보완하기 위해 QuikSCAT 해상풍 관측자료, 정지 및 극 궤도위성자료를 활용한 해수면온도 둥 위성 분석자료와 기타 관측자료를 참조하고 있다. 정지기상위성자료를 이용한 드보락기법은 적외영상만으로 태풍중심 위치와 강도를 분석할 수 있는 장점 외에 앞에서 열거한 몇 가지 극복되지 못한 한계도 있으나,SSM/I 둥 기타 위성자료의 관측시간대와 분석정보 부족 등으로 정지기상위성자료를 이용한 드보락 기법을 대체할만한 현업용 분석기법이 개발되지 못했다. 기상청에서는 기존의 태풍분석업무를 개선하기 위해서 2005년부터 AODT를 도입하여 그 성능을 시험분석하고, 2006년 6월부터 AODT를 현업화하여 실시간 태풍강도분석 에 활용하였으며 2006년 제 3호 태풍 에위니아(EWINIAR)부터 두리안(DURlAN)까지 19개 태풍 434개 시간대자료를 분석한 결과 SDT 강도분석결과와 0.90의 상관도를 보였다. 또한 AODT 알고리즘이 기본적으로 대서양에서 발생하는 태풍에 초점을 두고 개발되어 북서태평양에서 발생하는 태풍에 직접 적용하기에는 어려움이 있는 것으로 알려져 있으므로(Velden et al. 1998), 이의 개선을 위하여 태풍강도지수인 SDT CI(Current Intensity) 수와 AODT CI 수간의 통계적 관계를 밝히고 신경망을 이용한 비선형 주성분 분석 (Hieh,2004)등을 통해 AODT CI 수 보정 시도를 하였다. 이와 더불어, 기상청은 근원적 객관 알고리즘 개선을 위해 AODT 자체 알고리즘 분석과 위성자료 DB 구축 동의 노력을 기울이고 있다.

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Characterization of Poly(methyl methacrylate)-tin (IV) Chloride Blend by TG-DTG-DTA, IR and Pyrolysis-GC-MS Techniques

  • Arshad, Muhammad;Masud, Khalid;Arif, Muhammad;Rehman, Saeed-Ur;Saeed, Aamer;Zaidi, Jamshed Hussain
    • Bulletin of the Korean Chemical Society
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    • v.32 no.9
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    • pp.3295-3305
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    • 2011
  • Thermal behavior of poly (methyl methacrylate) was analyzed in the presence of tin (IV) chloride. Five different proportions - polymer to additive - were selected for casting films from common solvent. TG, DTG and DTA were employed to monitor thermal degradation of the systems. IR and py-GC-MS helped identify the decomposition products. The blends start degrading at a temperature lower than that of the neat polymer and higher than that of the pure additive. Complex formation between tin of additive and carbonyl oxygen (pendent groups of MMA units) was noticed in the films soon after the mixing of the components in the blends. The samples were also heated at three different temperatures to determine the composition of residues left after the expulsion of volatiles. The polymer, blends and additive exhibited a one step, two-step and three-step degradation, respectively. $T_0$ is highest for the polymer, lowest for the additive and is either $60^{\circ}C$ or $70^{\circ}C$ for the blends. The amount of residue increases down the series [moving from blend-1 (minimum additive concentration) to blend-5 (maximum additive concentration)]. For blend-1, it is 7% of the original mass whereas it is 16% for blend-5. $T_{max}$ also goes up as the concentration of additive in the blends is elevated. The complexation appears to be the cause of observed stabilization. Some new products of degradation were noted apart from those reported earlier. These included methanol, isobutyric acid, acid chloride, etc. Molecular-level mixing of the constituents and "positioning effect" of the additive may have brought about the formation of new compounds. Routes are proposed for the appearance of these substances. Horizontal burning tests were also conducted on polymer and blends and the results are discussed. Activation energies and reaction orders were calculated. Activation energy is highest for the polymer, i.e., 138.9 Kcal/mol while the range for blends is from 51 to 39 Kcal/mol. Stability zones are highlighted for the blends. The interaction between the blended parts seems to be chemical in nature.

Characteristics of $SiO_2$ Scale Removal by Chemical Cleaning in Reverse Osmosis Membrane Process (역삼투막 공정에서 화학적 세정에 의한 $SiO_2$ scale 제거특성)

  • DockKo, Seok;Lee, Hyung-Jib
    • Journal of Korean Society of Water and Wastewater
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    • v.24 no.1
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    • pp.93-101
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    • 2010
  • Reverse osmosis (RO) membranes have been widely used for desalination as well as water and wastewater treatment facilities. Cleaning process is important to maintain stable operation as well as prevention of membrane fouling. Purpose of this research is to analyze electrostatistic and chemical characteristics after cleaning of RO membrane against $SiO_2$ scale. Four RO membranes of polyamide are used and examined about effect of chemical cleaning. EDTA (ethylene diamine tetraacetic acid) and SDS (sodium dodecil sulfate) and NaOH are applied for cleaning process after operation in synthetic water. Then, cleaning was performed with chemicals such concentration as 6hr, 12hr and 24hr, respectively. As a result, transmittances of FT-IR of four membranes are compared at each cleaning concentration. Ta/Tv shows difference of chemical composition between new membrane and cleaning membrane after cleaning. Type B of RO membrane is turned out to be most vulnerable to cleaning among four membranes. In terms of zeta potential, new membrane has -16 mV to +6 mV on pH while scaled membrane has -18 mV to 2 mV. However, it changed -23mV to 0.9 mV after cleaning. In comparison with existing salt rejection of RO membranes after cleaning, the rejection of the membranes goes down 0.7% maximum. Though cleaning changes the characteristics of membrane surface, it does not greatly affect salt rejection. pH is a critical factor to flux change in PA (polyamide) membrane.