• Title/Summary/Keyword: GDL

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Effects of Ru/C Catalyst on the CO Tolerance of Anode and Durability of Membrane in PEMFC (PEMFC에서 전극의 CO 내성 및 막 내구성에 미치는 Ru/C 촉매의 영향)

  • Sim, Woo-jong;Kim, Dong-whan;Choi, Seo-hee;Kim, Ki-joong;Ahn, Ho-Geun;Jung, Min-chul;Park, Kwonpil
    • Korean Chemical Engineering Research
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    • v.46 no.2
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    • pp.286-290
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    • 2008
  • Small amounts of CO in reformate fuel gas effectively block platinum catalysts by strong adsorption on the platinum surface at the operation temperature of $60{\sim}80^{\circ}C$ in PEMFC. To oxidate CO, Ru/C layer (CO filter) was placed between Pt/C layer and GDL (gas diffusion layer) in this study. Ru/C filter provided good CO-tolerant PEMFC anode, but decreased the performance of unit cell about 10% at 0.6 V due to mass transfer resistance from Ru/C filter thickness and increase of charge transfer resistance. Membrane degradation is one of the most important factors limiting the life-time of PEMFCs. Membrane durability would be dependent on the electrode catalyst type. It seemed that Ru catalyst layer would shorten the life time of PEMFC as enhanced the fluoride emission rate of membrane in acceleration test.

Quality Characteristics of Tofu Added with Basil Water Extracts (바질 물추출물을 첨가한 두부의 품질특성)

  • 임정교;박인경;김순동
    • Korean journal of food and cookery science
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    • v.20 no.2
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    • pp.144-150
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    • 2004
  • This study was conducted to investigate the quality characteristics and shelf-life of tofu added with basil water extract (BWE). BWE was selected from 11 kinds of herbs based on estimations of antimicrobial activity, taste and flavor. The amount of waster was 7 times greater than that of raw soybean, BWE concentration against soybean juice was 20 mg% and GDL concentration was 0.3% as the optimal preparation conditions of tofu added with BWE (BWE-tofu). Color L*, a* and b* values of BWE-tofu were 78.11, 0.78 and 19.10, respectively, indicating that light green color was lower in the L* value, and higher in the at and b* values compared to control products. Savory taste and overall acceptability of the tofu were higher than those of control products evaluated by sensory test. Shelf-life of the tofu at 10$^{\circ}C$ was 8 days, which was prolonged by 4 days compared to control products evaluated by pH, titratable acidity and total microbes.

Rheological Studies of the Tofu upon the Processing Conditions (제조조건에 따른 두부의 물성연구)

  • Kim, Hag-Jung;Kim, Byung-Yong;Kim, Myung-Hwan
    • Korean Journal of Food Science and Technology
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    • v.27 no.3
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    • pp.324-328
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    • 1995
  • The changes in the rheological properties of soybean curd upon the processing conditions were measured by the failure test, and analyzed by the stress-relaxation data. Soybean curd coagulated with $CaCl_2$ showed a higher failure stress value than other coagulants such as $MgCl_2,\;CaSO_4\;and\;Glucono-{\delta}-lactone$ (GDL), whereas addition of 0.3% $CaCl_2$ produced higher failure stress value than other concentrations $0.2{\sim}0.6%)$. Also, maximum failure stress of soybean curd was shown at the higher heating temperatures$(95^{\circ}C)$ and greater molding pressures, respectively. Initial and equilibrium stress at the stress relaxation curves showed the same tendency as those of failure test, and magnitude of elastic elements$(E_0,\;E_e)$ and viscous element$({\eta})$ were numerically expressed through simple Maxwell model analysis.

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Rheological Properties of Soymilk and Curd Prepared with Micronized Full-fat Soyflour (콩미세분말로 제조된 두유 및 전두부의 물성)

  • 심재진;서지현;소한섭;유병승;이삼빈
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.32 no.1
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    • pp.75-81
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    • 2003
  • Rheological properties of micronized full-fat soyflour (MFS ) milk were determined according to solid content, heat-treatment and type of coagulants. Heat-treated MFS milk showed a pseudoplastic flow pattern. The consistency and flow index of heated MFS milk was greatly affected by increasing the concentration of MFS and/or soy protein isolate (SPI). Apparent viscosity of MFS milk was gradually decreased by heating below 6$0^{\circ}C$, but was drastically increased by raising temperature further. Addition of coagulants and SPI resulted in dropping the temperature that allows to increase apparent viscosity drastically. A coagulant for MFS tofu was formulated based on the gelling Property of a single coagulant. The textural properties of MFS tofu were improved using 7.1% total protein fortified with SPI.

Permeability Prediction of Gas Diffusion Layers for PEMFC Using Three-Dimensional Convolutional Neural Networks and Morphological Features Extracted from X-ray Tomography Images (삼차원 합성곱 신경망과 X선 단층 영상에서 추출한 형태학적 특징을 이용한 PEMFC용 가스확산층의 투과도 예측)

  • Hangil You;Gun Jin Yun
    • Composites Research
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    • v.37 no.1
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    • pp.40-45
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    • 2024
  • In this research, we introduce a novel approach that employs a 3D convolutional neural network (CNN) model to predict the permeability of Gas Diffusion Layers (GDLs). For training the model, we create an artificial dataset of GDL representative volume elements (RVEs) by extracting morphological characteristics from actual GDL images obtained through X-ray tomography. These morphological attributes involve statistical distributions of porosity, fiber orientation, and diameter. Subsequently, a permeability analysis using the Lattice Boltzmann Method (LBM) is conducted on a collection of 10,800 RVEs. The 3D CNN model, trained on this artificial dataset, well predicts the permeability of actual GDLs.

Dead-end Mode Operation of a Large Scale PEM Fuel Cell Stack (대면적 고분자전해질 연료전지의 데드엔드 운전)

  • Jeong, Jeehoon;Shin, Hyunkhil;Han, In-Su;Seo, Hakyu;Kim, Minsung;Cho, Sungbaek;Hur, Taeuk
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.11a
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    • pp.83.1-83.1
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    • 2010
  • A Dead-end mode operation is one of the best way to maximize the gas usage rate. But, some components of fuel cell stack like gas diffusion layer(GDL) or membrane can be damaged in dead-end mode operation. In this study, a Large Scale Polymer electrolyte membrane fuel cell(PEMFC) for a dead-end operation has been developed. The stack is composed with 4 cells which has over 400cm2 of active area. Hydrogen is used as a fuel, and oxygen is used as a oxidant. The dead-end operation performance was evaluated by a long-term dead-end mode operation. The fuel cell stack is operated over 1,500 hours in dead-end mode operating fuel cell test station. And the performance change of the fuel cell stack was investigated.

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Development of X-ray Micro Computed Tomography and Applications (미세 X선 단층촬영 기법의 개발과 적용)

  • Kim, Seung-Gon;Lim, Jae-Hong;Kim, Bo-Heum;Lee, Eui-Jae;Lee, Sang-Joon
    • Journal of the Korean Society of Visualization
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    • v.8 no.2
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    • pp.45-50
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    • 2010
  • The objective of this study is to elucidate the feasibility of synchrotron X-ray micro CT as a non-destructive imaging method to visualize the three-dimensional morphological structures of biological and non-biological samples. The experiments were conducted in 7B2 X-ray micro CT beamline in Pohang Accelerate Laboratory (PAL). A rotational 3-axis stage was specially designed for $0^{\circ}-180^{\circ}$ scanning of test samples. Preliminary tests were performed for opaque samples including a mosquito head, a plant seed and gas diffusion layer (GDL) of polymer electrolyte fuel cell to verify the feasibility of the X-ray micro CT. It visualized clearly the internal structure of all the test samples, supporting its usefulness.

Study of stress distribution on bipolar plate of PEM fuel cell (고분자 연료전지의 Bipolar Plate에서의 응력분포에 관한 연구)

  • Heo, Jeong-mu;Sohn, Young-Jun;Park, Gu-Gon;Kim, Min-jin;Yim, Sung-Dae;Nahm, Kee-suk
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.06a
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    • pp.389-391
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    • 2009
  • The performance loss as pressurized by inside components like GDL and bipolar plate happened when assembling the PEMFC stack with clamping force. Numerical analysis of Gasket was carried out to analyze distribution of clamping pressure about the inside components. In case of the gasket, Mooney-Rivlin model which is the Strain Energy Function was used for numerical analysis. This result made the stress distribution of bipolar plate to expect.

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Property changes of GDLs and water behaviors in PEFCs (고분자전해질 연료전지 체결조건에서 기체확산층의 특성변화 및 물거동 확인)

  • Park, Gu-Gon;Lim, Nam-Yun;Ahn, Eun-Jin;Park, Jin-Soo;Yoon, Young-Gi;Lee, Won-Yong;Lim, Tae-Won;Kim, Chan-Soo
    • 한국신재생에너지학회:학술대회논문집
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    • 2006.11a
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    • pp.313-315
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    • 2006
  • Proper water management is important to achieve high performance and durability of Polymer electrolyte fuel cell (PEFC). Among various stack components, gas diffusion layer (GDL) is considered as a core part to determine the gas and water transportation in a cell. To optimize the water management, the changes of properties as well as basic properties of GDLs were investigated before and after clamping of colls. Thickness, electric conductivity, porosity, hydroppobicity etc. were characterized by the same criteria. The amount of residual water after cell operation also was compared by direct measuring of weight. Based on the amount of residual water the endurance on the freeze condition was evaluated.

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Finite Element Analysis of Fuel Cell Stack with Orthotropic Material Model (직교이방성 연료전지 스택의 유한요소 해석)

  • 전지훈;황운봉;조규택;김수환;임태원
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2003.10a
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    • pp.175-178
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    • 2003
  • Mechanical behavior of a fuel stack was studied by the orthotropic material model. The fuel stack is mainly composed of bipolar plate (BP), gasket, end plate, membrane electrolyte assembly (MEA), and gas diffusion layer (GDL). Each component is fastened with a suitable pressure. It is very important to maintain a suitable contact pressure of BP, because it affects the efficiency of the fuel cell. This study compared mechanical behavior of various fastening types of the fuel cell stack. Bar, band, and modified band fastening type are used. The band fastening type showed that it reduces total volume of the cell, but it does not improve the contact pressure distribution of each BP. The modified band fastening type was designed by considering the deformations of band fastening type, and it showed a good enhancement of contact pressure distribution.

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