• Title/Summary/Keyword: GCIMSD

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Distribution of Certain Chlorobenzenes in Seawater from Youngil Bay, Korea

  • Moon, Hyo-Bang;Park, Hee-Gu;Kim, Sang-Soo;Jeong, Seung-Ryul;Lee, Pil-Yong
    • Environmental Sciences Bulletin of The Korean Environmental Sciences Society
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    • v.10 no.S_3
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    • pp.107-111
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    • 2001
  • Surface seawater was sampled from 20 stations in Youngil Bay, Korea in November 2000. The samples were analyzed for eight chlorobenzenes(CBs) out of a total of 12 in the congener series using a gas chromatography coupled to a mass spectrometer detector(GC/MSD). The total CB levels varied from 1.3 to 6.1 ng/L with a mean of 4.0 ng/L. Trichlorobenzene groups (sum of 1,3,5-, 1,2,4-, and 1,2,3-trichlorobenzene) were the predominant class among the four congener groups, while tetrachlorobenzenes(sum of 1,2,3,5-, 1,2,4,5-, and 1,2,3,4- tetrachlorobenzene) and pentachlorobenzene showed a low presence. The total CB levels exhibited similar patterns for all the stations. A significant positive correlation was observed between the individual CB compounds in the particulate samples, while the dissolved samples revealed a strong correlation between the heavier molecular weight CBs.

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Studies on the Quantitative analysis and the Health Effect of VOCs in Environment - Analysis for THMs of tap water in six cities of Korea - (VOCs 측정 및 VOCs가 인체에 미치는 영향에 관한 연구 - 우리나라 6개 대도시 수도수 중 THMs 분석 -)

  • Kim, Mi-Kyoung;Park, Yuon-Sin;Chung, Yong
    • Analytical Science and Technology
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    • v.13 no.1
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    • pp.55-65
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    • 2000
  • In this study, we collected the tap water that treated from water plant in Seoul, Incheon, Taejon, Kwangju, Taeku and Pusan and supplied each house. The sampling period was June and September, 1997. The concentration of THMs formed by chlorination in drinking water was determined with the purge and trap method with GC/MSD recommended by the us EPA 542.2 method. Chloroform is the most of THMs (47.43%~93.11%) and the content order is bromodichloromethane > chlorodibromomethane > bromoform. In Incheon, Taejon, Kwangju, Taeku and Pusan, the content of bromodichloromethane, chlorodibromomethane and bromoform was higher than Seoul. But, in June and September, the concentration of THMs in six cities is not over Korea Drinking Water Regulation $100{\mu}g/L$. The calculated human exposure for each substances were chloroform $6.14{\times}10^{-4}mg/kg/day$, bromodichloromethane $1.01{\times}10^{-4}mg/kg/day$, chlorodibromomethane $0.29{\times}10^{-4}mg/kg/day$, bromoform $0.01{\times}10^{-4}mg/kg/day$ and THMs $7.98{\times}10^{-4}mg/kg/day$.

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