• Title/Summary/Keyword: GAs analysis

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Analysis of Benzophenone in Sediment and Soil by Gas Chromatography/Mass Spectrometry (기체크로마토그래피/질량분석기에 의한 저질 및 토양시료 중 벤조페논의 분석법 연구)

  • 권오승;김은영;류재천
    • Environmental Analysis Health and Toxicology
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    • v.16 no.3
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    • pp.121-126
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    • 2001
  • Analytical method of benzophenone (BP) in sediment and soil was developed by gas chromatography/mass selective detector/selected ion monitoring (GC/MSD/SIM). The ultrasonic extraction of US EPA (method 3550B) method and liquid-liquid extraction for sediment and soil samples were used for the analysis of BP from sediment and soil. BP was extracted with n-hexane. Organic layer was washed with 5% sodium chloride solution. 1∼2 l of the concentrated solution of organic layer was applied to GC/MSD. The retention time of BP peak was 11.10 min. Recovery (%) of BP by ultrasonication from sediment and soil samples was 96.0∼100.6% and 40.0∼83.0%, respectively. Recovery of BP by liquid-liquid extraction was 51∼59% in soil samples. The detection limit of BP in sediment and soil samples were determined to 0.1 ng/g.

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A Study on the Vibration Reduction of Flue Gas Cooler Using Modal Analysis (모드해석을 이용한 플루가스 냉각기의 진동 저감 방법에 관한 연구)

  • Lee, Boo-Youn;Kim, Won-Jin
    • Journal of the Korean Society for Precision Engineering
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    • v.29 no.6
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    • pp.664-670
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    • 2012
  • In this work, vibration characteristics of a flue gas cooler(FGC) for a heavy oil upgrading are experimentally analyzed and an effective method is proposed to reduce the vibration level. Firstly, the vibration under the operation condition of the FGC is measured and analyzed to identify the generation phenomena of vibration. And the displacement of the outer wall of the FGC is also analyzed to identify dominant frequencies of vibration. Secondly, an effective design to reduce the vibration is suggested by using the modal analysis. Consequently an improved design of the FGC gas cooler, which has lower vibration level, is obtained and then verified though the analysis and test.

Investigation Between Gas in Oil Analysis and the Source of Trouble in Transformer (변압기 절연유 가스분석과 고장원인 검토)

  • Kweon Dong-Jin;Kwak Joo-Sik;Eun Jong-Young;Min Byeong-Moon;Yu Dong-Gyon
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.54 no.8
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    • pp.343-349
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    • 2005
  • The gas in oil analysis of transformer is the most widely used technology for diagnosis of transformer in the world. It has brought excellent results to prevention of transformer failure. The criteria for maintenance and judgement, however, is still required continuous supplement to improve the accuracy of the diagnosis on the basis of accumulated data of gas analysis and investigations in the transformer In this study, the relationship between the detection rate of the defects and the source of troubles are analyzed according to the investigation in the transformer, which was conducted by KEPCO in 2004. As a result, the validity of the criteria being used at present was examined thoroughly.

Transient Multicomponent Mixture Analysis Based On an ICE Numerical Technique for the Simulation of an Air Inggess Accident in an HTGR

  • Lim, Hong-Sik;No, Hee-Cheon
    • Nuclear Engineering and Technology
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    • v.36 no.5
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    • pp.375-387
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    • 2004
  • This paper presents a transient multicomponent mixture analysis tool developed to analyze the molecular diffusion, natural convection, and chemical reactions related to air ingress phenomena that occur during a primary-pipe rupture of a high temperature gas-cooled reactor (HIGR). The present analysis tool solves the one-dimensional basic equations for continuity, momentum, energy of the gas mixture, and the mass of each gas species. In order to obtain numerically stable and fast computations, the implicit continuous Eulerian scheme is adopted to solve the governing equations in a strongly coupled manner. Two types of benchmark calculations were performed with the data of prerious Japanese inverse U-tube experiments. The analysis program, based on the ICE technique, runs about 36 times faster than the FLUENT6 for the simulation of the two experiments. The calculation results are within a 10% deviation from the experimental data regarding the concentrations of the gas species and the onset times of natural convection.

Installation and Test Run of Comprehensive Analysis System for SF6 in Power Equipment

  • Lee, Jeong Eun;Kim, Kwang Sin;Kim, Ah Reum;Park, Seoksoon;Kim, Kyeongsook
    • KEPCO Journal on Electric Power and Energy
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    • v.3 no.1
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    • pp.41-47
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    • 2017
  • After $SF_6$, which is being used in power equipment as an insulating material, is classified as one of the 6 major greenhouse gases, the maintenance and the refinement of used $SF_6$ started to get attention. In regard to this, KEPCO Research Institute (KEPRI) is developing $SF_6$ recovery and refinement technology starting with establishing a comprehensive $SF_6$ analysis system. With the analysis system, qualitative and quantitative analyses of the purity and the impurities of $SF_6$ before and after recovery, and before and after refinement have been carried out. The analysis system is comprised of GC-DID (Gas Chromatograph -Discharge Ionization Detector) for trace impurities analysis, GC-TCD (Thermal Conductivity Detector) for analyses of $SF_6$ purity and major impurities concentration from several hundred ppm up to percent range, GC-MSD (Mass Selective Detector) for analyses of impurities not included in standard gas, FT-IR (Fourier Transform-Infrared) Spectrometer for analysis of HF and $SO_2$, and moisture analyzer for analysis of moisture below 100 ppm. With this analysis system, complete analysis method of $SF_6$ has been established. This analysis system is being used in the maintenance of power equipment and the development of $SF_6$ recovery and refinement technologies. In this paper, the analysis results of four samples - gas and liquid phase $SF_6$ samples from a $SF_6$ refinement system before and after refinement are presented.

Scientometric Analysis for Unconventional Tight Gas (비전통 치밀 가스 학술정보 분석)

  • Lee, Su-Jin;Kil, Sang-Cheol;Kim, Young-In;Oh, Mihn-Soo
    • Economic and Environmental Geology
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    • v.47 no.5
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    • pp.551-561
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    • 2014
  • Natural gas is the world's fastest-growing fossil fuel, with consumption increasing from 113 trillion cubic feet(Tcf) in 2010 to 185Tcf in 2040. While conventional natural gas streams from the earth relatively easily, unconventional gas finds are more difficult to develop and more costly to produce. Right now, there are six main types of unconventional gas, including deep gas, gas-containing shale, coalbed methane(CBM), geopressurized zones, Arctic and subsea hydrates, and tight gas. Tight gas refers to natural gas reservoirs locked in extraordinarily impermeable, hard rocks(sandstone, siltstone or carbonate sedimentary rocks). In this study, we analyzed total 375 papers(2000-2014) of tight gas by country, institution, international cooperation etc.

Gas Accident Analysis and Suggestion of Countermeasure at Thawing Season (해빙기 가스사고분석 및 사고예방 대책 제시)

  • Park Kyo-Shik;Kim Eun-Jung
    • Journal of the Korean Institute of Gas
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    • v.4 no.2 s.10
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    • pp.46-51
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    • 2000
  • It is required that fuel gas accidents should be managed carefully along with the increase of fuel gas consumption. Factors to cause accidents were investigated through a systematic analysis of gas accidents during recent 4 years, which could be applied to prepare countermeasures to reduce gas accidents. The thawing season is found to be weak to gas accidents, showing a slightly higher rate of accident occurring than average. During this term although the number of LPG accident is similar to that of yearly average, countermeasures are required for LPG facilities since the portion of accident is large; in detail, user's carelessness, defective facility, or instrument failure are major causes. The number of city gas accident facility is larger than that of yearly average; particularly, defective facilities, third-party work, and appliance failure are major causes. As a result, countermeasures have been suggested for the accident of large portion or above yearly average.

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Proposal and Implementation of Emergency Response System of Gas Shut-off in Earthquake (지진시 도시가스 공급정지를 위한 긴급대응시스템의 제안 및 적용)

  • Jung, Hyo-Soon;Kim, Ick-Hyun;Lee, Jong-Seok
    • Journal of the Earthquake Engineering Society of Korea
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    • v.12 no.6
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    • pp.25-33
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    • 2008
  • Fires that result from the excessive leakage of gas due to earthquakes cause enormous loss of property as well as numerous human casualties. To prevent such disasters, an emergency gas shut-off system is considered to be one of the effective and rational methods. Considering the seismicity, the earthquake frequency and the gas-supply system of Korea, mass gas shut-off by a gas company is determined to be more cost-effective than individual gas shut-off by customers. In this study, an emergency response system was proposed that would shut off the gas supply immediately. Two different reference seismicities were proposed, to specify rapid response according to the measured seismicity. The gas supply area was divided into several gas shut-off blocks in order to facilitate the shut-off of gas supply in damaged blocks. This proposed system was implemented in the actual gas supply area with reference seismicities on the basis of seismic damage analysis.

Analysis of Experimental Results on Hydrogen Generator for HCNG (HCNG용 수소제조장치 실험 및 결과분석)

  • Lee, Youngchul;Han, Jeongok;Lee, Joongseong;Kim, Yongcheol;Cho, Youngah;Kim, Sangmin;Kim, Heongtae
    • Transactions of the Korean hydrogen and new energy society
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    • v.26 no.2
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    • pp.89-95
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    • 2015
  • Pollution emission control of the 20th century, for transportation energy, are being enhanced, and then as alternative to this, because hydrogen emit only water gas emissions to be environmentally friendly energy, so hydrogen as a sustainable clean energy is in the limelight. Used in compressed natural gas engines to mix hydrogen and natural gas in both domestic and international technology development and demonstration is being carried out. The hydrogen-compressed natural gas(HCNG) charging infrastructure can be used to build a hydrogen infrastructure in the transitional aspects of a future hydrogen economy society. In this paper, for a demonstration of HCNG charging infrastructure we made and operated a $30Nm^3/h$ hydrogen generating unit and analyzed the result of the operation. We was identified the operating conditions of a reforming reactor and water gas shift reactor from an analysis result, the thermal efficiency was calculated according to the operating conditions of the total hydrogen production process.