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Difference of the Chemical Compositions Between Petroleum Ether Extract and its Tall Oil in Pitch Pine, Pinus Rigida Mill (리기다소나무재(材)의 유기용매(有機溶媒) 추출물(抽出物)과 그 tall oil 간의 조성(組成)의 차이(差異))

  • Ko, Sang-Woon;Ahn, Won-Yung
    • Journal of the Korean Wood Science and Technology
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    • v.16 no.2
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    • pp.79-89
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    • 1988
  • This experiment was carried out to investigate the difference of compositions between petroleum ether extract and its tall oil in Pinus rigida Mill. xylem and to obtain the basic data on effective extraction and its utilization of by-product, resin and fatty acid, when pulp making. After both petroleum ether extract from wood meal and its tall oil in pitch pine were separated to the resin and fatty acid by using DEAE-Sephadex and aluminum oxide column, these were analyzed with gas chromatograph. The results obtained were as follows: 1. Fatty acids contained as ester form in living trees were varied by peroxide of organic solvent in petroleum ehter extraction and cooking chemicals in cooking. 2. Pimaric-type acid was eluted earlier than abietic-type acid in resin acids and the fewer the carbons, the earlier the elution in fatty acids. 3. The retention time of SE-30 column was even smaller than that of OV-101 column but the relative retention time obtained by using methyl pimarate and methyl stearate as internal standard was nearly identical. 4. Both petroleum ether extract and tall oil mainly consisted of resin acids, expecially abietic-type acid. 5. Tall oil had more fatty acid but less resin acid than petroleum ether extract. Also, the content of unidentified materials was increased owing to the isomerization and the shift of double bond position in unsaturated fatty acids by high temperature and cooking chemicals when cooking.

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Rotordynamic Analysis of a Dual-Spool Turbofan Engine with Focus on Blade Defect Events (블레이드 손상에 따른 이축식 터보팬 엔진의 동적 안정성 해석)

  • Kim, Sitae;Jung, Kihyun;Lee, Junho;Park, Kihyun;Yang, Kwangjin
    • Tribology and Lubricants
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    • v.36 no.2
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    • pp.105-115
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    • 2020
  • This paper presents a numerical study on the rotordynamic analysis of a dual-spool turbofan engine in the context of blade defect events. The blades of an axial-type aeroengine are typically well aligned during the compressor and turbine stages. However, they are sometimes exposed to damage, partially or entirely, for several operational reasons, such as cracks due to foreign objects, burns from the combustion gas, and corrosion due to oxygen in the air. Herein, we designed a dual-spool rotor using the commercial 3D modeling software CATIA to simulate blade defects in the turbofan engine. We utilized the rotordynamic parameters to create two finite element Euler-Bernoulli beam models connected by means of an inter-rotor bearing. We then applied the unbalanced forces induced by the mass eccentricities of the blades to the following selected scenarios: 1) fully balanced, 2) crack in the low-pressure compressor (LPC) and high pressure compressor (HPC), 3) burn on the high-pressure turbine (HPT) and low pressure compressor, 4) corrosion of the LPC, and 5) corrosion of the HPC. Additionally, we obtained the transient and steady-state responses of the overall rotor nodes using the Runge-Kutta numerical integration method, and employed model reduction techniques such as component mode synthesis to enhance the computational efficiency of the process. The simulation results indicate that the high-vibration status of the rotor commences beyond 10,000 rpm, which is identified as the first critical speed of the lower speed rotor. Moreover, we monitored the unbalanced stages near the inter-rotor bearing, which prominently influences the overall rotordynamic status, and the corrosion of the HPC to prevent further instability. The high-speed range operation (>13,000 rpm) coupled with HPC/HPT blade defects possibly presents a rotor-case contact problem that can lead to catastrophic failure.

개방계 측정시스템을 이용한 토마토 호흡속도의 자동측정

  • Lee, Hyun-Dong;Yoon, Hong-Sun;Lee, Won-Ok;Jung, Hoon;Cho, Kwang-Hwan
    • Proceedings of the Korean Society of Postharvest Science and Technology of Agricultural Products Conference
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    • 2003.04a
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    • pp.141-141
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    • 2003
  • 신선농산물의 호홉속도를 측정하는 방법 중 하나인 개방계(open system) 호흡속도 측정시스템은 소정의 농도로 조정된 혼합기체를 측정대상시료에 흘려 보내며 측정하는 방법이다. 개방계 측정법의 장점은 혼합 기체조성 영역에서 정확한 호흡속도를 얻을 수 있으며 방치시간이 필요 없으므로 반복 측정이 용이한 것 등이다. 그러나 개방계 측정법은 공급되는 혼합기체의 농도와 유속이 일정하여야 하며 연속으로 호흡속도 측정용 챔버의 혼합기체 공급측과 배기측에서 기체시료를 수집하여 매우 미세한 기체농도의 차이를 측정할 수 있어야 하고 기체 시료 수집에 상당한 주의가 요구된다. 이러한 문제를 개선하기 위하여 개방계 호흡속도 측정 시스템을 자동화하였다. 자동화된 호흡속도 측정 시스템은 혼합기체 발생장치, 온도조절이 가능한 기체기밀용 챔버와 G.C로 구성되어 있다. 환경기체조성을 위한 혼합기체발생장치는 $N_2$, $O_2$, $CO_2$ 압축 실린더에서 공급되는 기체를 압력 조절기를 통해서 일차압력을 조정하고 정밀 압력 조절기를 이용하여 0.1~0.2 kg/$\textrm{cm}^2$의 정압을 유지시켰다. 압력이 일정해진 기체는 metering valve를 이용하여 각 기체의 유량을 소정의 비율로 제어할 수 있도록 하였으며 각각의 기체는 gas mixed cell에서 실험 농도의 환경기체조성으로 혼합되어 항온기내의 호흡속도 측정 챔버($25^{\circ}C$)로 공급될 수 있도록 하였다. 호흡속도 측정용 챔버는 개스킷이 장착된 아크릴 재질이며 온도 조절이 가능한 항온기로 구성되어 있다. 호흡속도 측정용 챔버와 G.C간의 기체흐름은 three way solenoid valve에 의하여 제어되며 전원의 on/off에 따라 공급측의 가스와 배기측의 가스가 선택적으로 G.C에 공급될 수 있도록 구성하였다. 측정 대상 챔버의 기체는 제어된 유로를 따라 multi-position valve를 통과하여 G.C에서 분석되도록 하였다. 본 연구에서 개발된 개방계 호흡속도 자동 측정 시스템의 성능 실험에서 혼합기체발생장치에서 조제된 혼합 기체의 농도를 설정치와 비교한 결과 $O_2$$CO_2$의 농도에서 평균오차 0.2%로 정밀한 것으로 나타났으며 호흡속도 측정용 챔버의 혼합기체 공급측과 배기측의 가스 농도를 3회 반복 측정한 결과 재현성에서는 0.1%이하의 편차로 나타났다. 개방계 호흡속도 자동 측정 시스템을 이용하여 환경기체조성하에서 토마토의 호흡속도를 측정하는 실측 실험을 수행한 결과 2$0^{\circ}C$에서 12.7~42.1mg$CO_2$/kg.hr였으며 12$^{\circ}C$에서 2.5~8.2mg$CO_2$/kg.hr로 일반적으로 보고되고 있는 토마토 호흡속도와 일치하는 결과를 나타내었다.

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Korean Strategies for Establishing New MRV Schemes Applicable to Post-2020 Regime (Post-2020의 MRV 체계 수립을 위한 우리나라 대응 방향)

  • Kim, Seungdo;Ryu, SeungYun;Jung, Jaehyuk;Yoo, Beom-Sik
    • Journal of Environmental Policy
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    • v.14 no.4
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    • pp.3-21
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    • 2015
  • This paper attempts to determine the most reasonable and agreeable option for new MRV framework in Post-2020 Climate Regime as well as to develop South Korea strategies to reflect our national circumstances and capacities appropriately. The options for MRV framework considered here are 1) Dual MRV and 2) Unified MRV. We reached the conclusion that the Unified MRV framework may be the most reasonable option in the 2015 agreement in line with the objectives of MRV. To this end, it is essential to develop effective stepwise strategies consisted of: 1) reaching a consensus internally on the Unified MRV framework, 2) developing detailed procedures and methodologies to make the major elements of the Unified MRV framework understandable and predictable, 3) delivering an overview and blueprint to make sure of the flexibility of the Unified MRV framework to reflect the Parties' capacities and national circumstances, 4) ensuring the financial and technical support schemes for developing countries to improve the capacity-buildings of MRV, and 5) developing a realistic road map to successfully implement the Unified MRV scheme within the required time frame. Korea, as a rational mediator between developed and developing countries, should play a leading role in reaching post-2020 agreement.

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Damage Evaluation of Bi-directionally Prestressed Concrete Panels under Blast-fire Combined Loading (폭발 후 화재하중 시나리오에 따른 2방향 프리스트레스트 콘크리트 패널부재의 손상도 평가)

  • Choi, Ji-Hun;Choi, Seung-Jai;Kim, Tae-Kyun;Kim, Jang-Ho Jay
    • Journal of the Korea Concrete Institute
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    • v.29 no.3
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    • pp.237-248
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    • 2017
  • Frequent terror or military attack by explosion, impact, fire accidents have occurred recently. These attacks and incidents raised public concerns and anxiety of potential terrorist attacks on important infrastructures. However, structural behavioral researches on prestressed concrete (PSC) infrastructures such as Prestressed Concrete Containment Vessel (PCCV) and Liquefied Natural Gas (LNG) storage tanks under extreme loading are significantly lacking at this time. Also, researches on possible secondary fire scenarios after terror and bomb explosion has not been performed yet. Therefore, a study on PSC structural behavior from an blast-induced fire scenario was undertaken. To evaluate the blast-fire combined resistance capacity and its protective performance of bi-directional unbonded PSC member, blast-fire tests were carried out on $1,400mm{\times}1,000mm{\times}300mm$ PSC specimens. Blast loading tests were performed by the detonation of 25 kg ANFO explosive charge at 1.0 m standoff distance. Also, fire and blast-fire combined loading were tested using RABT fire loading curve. The test results are discussed in detail in the paper. The results can be used as basic research references for related research areas, which include protective design simulation under blast-fire combined loading.

A Study of Coffee Bean Characteristics and Coffee Flavors in Relation to Roasting (커피원두의 배전강도에 따른 품질특성 및 향기성분에 관한 연구)

  • Lee, Moon Jo;Kim, Sang Eun;Kim, Jong Hwan;Lee, Sang Won;Yeum, Dong Min
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.42 no.2
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    • pp.255-261
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    • 2013
  • This study investigated changes in the physicochemical characteristics and coffee flavors of coffee beans under different roasting conditions. Four different kinds of roasted coffees were analyzed using a headspace gas chromatographic technique. The moisture content and total acidity of roasted coffee decreased whereas the pH and weight loss (%) increased, as coffee beans were roasted at higher temperatures. The Hunter's color values of the roasted coffee (indicating L (lightness) and b (yellowness)) decreased as the roasting temperature of the coffee beans increased, but a (redness) value only increased with light roasting. We also noted that the color of the Arabica coffee was darker than that of the Robusta coffee. The aroma compounds, acetaldehyde, acetone, 2-methylfuran, 2-methylbutanol, 2-methylpyrazine, furfural, 2-propanone, furfuryl alcohol, 2,5-dimethylpyrazine and furfuryl acetate were mainly analyzed. A sensory evaluation of all light-roasted coffees had flavor and sourness and those of all medium-roasted coffees had heaviness and finishness.

Real-time Monitoring of Ammonia and Hydrogen Sulfide According to Workplace at Swine Farms (양돈장 작업장소별 암모니아 및 황화수소의 실시간 모니터링)

  • Park, Jihoon;Kang, Taesun;Seok, Jiwon;Jin, Suhyun;Heo, Yong;Kim, Kyungran;Lee, Kyungsuk;Yoon, Chungsik
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.23 no.4
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    • pp.402-411
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    • 2013
  • Objectives: This study aims to assess the concentrations of ammonia and hydrogen sulfide according to task unit area at swine farms. Methods: A total of six swine farms were selected for this study. Ammonia and hydrogen sulfide were monitored using a real-time multi-gas monitor which could sample the gases simultaneously. The sampling was done in the pig building, manure storage facility and composting facility of each farm. Results: The concentration of ammonia in the pig buildings(GM 22.6 ppm, GSD 2.3) was significantly higher(p<0.0001) than in the manure storage facilities(GM 10.4 ppm, GSD 2.7) and composting facilities(GM 8.6 ppm, GSD 2.8). The concentration of hydrogen sulfide in the manure storage facilities(GM 9.8 ppm, GSD 3.2) was higher(p<0.0001) than in the pig buildings(GM 2.3 ppm, GSD 2.3) and composting facilities(GM 1.9 ppm, GSD 2.5). In particular, the levels of hydrogen sulfide in the confined manure storage facilities were higher than those in open-type facilities and the peak concentration(98 ppm) in the confined facilities was approximate to 100 ppm, at the value of Immediately Dangerous to Life or Health(IDLH). Conclusions: Suffocation accidents caused by hazardous gases at a swine farm have occurred annually. Real-time monitoring of the hazards should be done in order to protect farm workers and livestock from the sudden accidents.

Utilization of Egg-shell for Bread-making (제빵시 난각의 이용에 관한 연구)

  • Kim, Joong-Man;Kim, Yong-Seob;Yang, Hee-Chon;Choi, Yong-Bae
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.18 no.2
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    • pp.160-166
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    • 1989
  • This study was conducted to investigate whether egg-shell may be used as a mineral sourceor leavening agent in breadmaking. In Korea the waste volume of egg shell has been estimated at about 28,694 tons per year. Carbon dioxide generation maxima were established for barking powder$(153{\pm}3ml/g)$, egg-shell(205in reaction with lactic acid) and yeast$(115{\pm}3ml/sugar\;g)$. Gas release time required for each substance to reach $CO_2$ maximum was, for baking powder 7 minutes, for egg-shell 45 mins and for yeast 240 mins. Particle size of egg-shell in breadmaking was suitable more than 20 mesh (-). When egg-shell only was added to the basic formular without including lactic acid, no leavening effect was observed. However, when lactic acid and egg-shell were used together, the leavening effect was more or less equivalent to that of yeast(control). Addition of egg-shell was found to increase calcium content of bread products without noticeable altering flavor, as compared with control. Joint use of egg-shell was organic acids in breadmaking was shown to have potential in time saving, volume increase and yeast saving.

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Economic Cooperation between Russia and Republic of Korea;Problems and Prospects (러-한 경제협력;과제와 전망)

  • Suslov, Denis V.
    • Journal of Arbitration Studies
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    • v.18 no.2
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    • pp.201-233
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    • 2008
  • 러시아와 한국간의 공식적인 접촉은 1990년 6월 샌프란시스코에서 개최된 정상회담이다. 동년 9월 뉴욕에서 개최된 양국의 외무장관 회담에서 러시아와 한국의 외교관계가 수립되었다. 그간 양국간에는 협정을 통한 협력의 법적기반이 조성되었는데 주요 분야를 보면 무역, 투자보장, 어업, 이중과세방지, 군사기술분야, 원자력의 평화적 이용, 문화교류에 관한 협정들이 있다. 역시 양국간의 주요 관심사항은 무역과 경제협력 분야이다. 2007년도 러시아와 한국의 무역액은 150억 달러를 초과함으로써 전년도에 비해 55.5% 증가하였다. 러시아의 한국으로의 수출은 약 70억 달러로서 전년도에 비해 52.6% 증가했고 한국으로부터의 수입은 80억 달러를 초과함으로써 전년도에 비해 56.1% 증가하였다. 그리하여 러시아는 한국의 10대 교역국으로 성장하였다. 가스와 오일 프로젝트 추진과 관련하여 사할린지역에서 사용하기 위해 한국으로부터 수입하는 드릴기계장비, 탱커, 자동차, 휴대전화는 한국과 러시아 양국간 경제성장의 주요요인이 되고 있다. 2008년 1/4 분기 양국간 무역액은 42억 달러를 초과했는데 이는 전년도 동기와 비교해서 72.1% 증가한 것이다. 이 중 한국에의 수출은 17억 달러를 초과했는데 이는 전년도 1/4분기에 비해 91.7% 성장한 것이다. 한국으로부터의 수입은 약 25억 달러로서 전년도 1/4 분기와 대비해서 60.6% 성장했다. 러시아와 한국간의 경제교류가 크게 증대하게 된 배경에는 러-한경제과학기술협력공동위원회가 큰 역할을 담당했다. 이 논문에서 필자는 무역과 투자측면에서 본 양국간 경제협력의 특징을 고찰하는 한편 러시아의 동부지역(러시아 극동 및 바이칼횡단지역)과 한국과의 협력과 관련된 역동성과 과제를 제시하는데 연구의 목적을 두었다. 한국은 외국기업과 함께 러시아 극동지역의 무역과 경제협력 증진에 상당한 공헌을 함으로써 러시아 극동경제권에서 주요 무역파트너가 되고 있다. 또한 본 연구에서는 한국과 러시아간의 주요 협력프로젝트에 관하여 고찰하는 한편 앞으로의 전망을 제시하였다. 이 문제는 무엇보다도 한-러간의 공동 에너지프로젝트 및 에너지자원의 무역과 관련되어 있다. 한국과 러시아는 이미 많은 분야에서 상당한 정도로 상호 협력관계를 발전시켜왔다. 여기에는 정책, 에너지, 경제, 문화, 과학기술 분야가 포함되어 있다. 현재 러시아와 한국간에는 에너지 분야에서의 전략적 대화채널 구축에 관한 문제와 함께 연료 및 에너지공단 건설과 관련하여 협력문제가 논의되고 있다. 에너지 분야에서의 전략적 대화개념 구축을 위해서는 전략, 예측 및 투자환경의 문제가 양국간에 집중논의 되어야 하고 법제상의 조화문제도 논의되어야 한다.

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Preparation of Hexaaluminate Phosphor Particles with Spherical Shape by Gas Phase Reaction Process (기상 공정에 의한 구형 형상의 헥사알루미네이트계 형광체 제조)

  • Jung, Dae Soo;Hong, Seung Kwon;Koo, Hye Young;Ju, Seo Hee;Kang, Yun Chan
    • Korean Chemical Engineering Research
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    • v.43 no.5
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    • pp.616-620
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    • 2005
  • The morphology and photoluminescence characteristics of green light emitting hexaaluminate phosphor particles prepared by high temperature spray pyrolysis from spray solution with and without ammonium dihydrogen phosphate flux were investigated. The particles prepared from spray solution without flux material had hollow morphology at preparation temperatures between $900^{\circ}C$ and $1,650^{\circ}C$. Ammonium dihydrogen phosphate flux added into spray solution enabled the formation of particles with spherical shape and filled morphology at preparation temperatures between $900^{\circ}C$ and $1,650^{\circ}C$. The hexaaluminate phosphor particles with magnetoplumbite structure were directly prepared by spray pyrolysis from spray solution with ammonium dihydrogen phosphate flux above $1,600^{\circ}C$. Ammonium dihydrogen phosphate flux was effective in improving the photoluminescence intensity of the phosphor particles at low preparation temperatures. The phosphor particles prepared from spray solution with and without flux material by spray pyrolysis under reducing atmosphere at $1,650^{\circ}C$ had comparable photoluminescence intensities with that of the phosphor particles optimized by post-treatment.