• 한국환경과학회지
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• 제17권8호
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• pp.925-932
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• 2008

Manufactures of automotive repair finishes are tending to reduce more and more the level of volatile organic compounds (VOCs) in their paint processes in order to comply with increasingly strict environmental legislation. The production of high solids paints is a way to solve this problem. However, the application of high-solids paints is limited primarily by the viscosity of resin which is strongly related to painting ability: the higher solid content, the lower desired property. In this study, alkyl copolymer with low viscosity was synthesized by the introduction of the monomers with long-side chains and functional groups which improve flexibility and cross-linking density, respectively. The solid content of the paint prepared with the synthesized resin was 80wt% and its VOCs was reduced by 20%, compared to the commercialized paint. Also, the physical and mechanical properties of coatings on steel sheets were similar to commercialized one.

• 한국염색가공학회지
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• 제17권6호
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• pp.27-35
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• 2005

Conventional pad- dry-cure(thermo-fixation) process usually produces functional performance on both sides of a fabric. UV curing technique was applied to impart water- and oil-repellent finish effective only on the face of a PET knitted fabric. The preferential one-side coating, by virtue of the limited penetration of UV light, was achieved by W curing after padding of a fluorocarbon agent without special coating or printing equipments. The difference in the functional property of face and back sides was examined by measuring water and oil repellency at each side of the treated fabric. The influence of pre/post-irradiation dose and agent concentration on the performance of the finished fabrics were investigated. While increase in both resin concentration and post-irradiation did not have significant effect on the finish, UV pre-irradiation of PET fabrics caused remarkable influence presumably due to appropriate surface modification of PET fabrics required for facile wetting of the resin. The dimensional stability and color change of the UV cured fabrics measured by FAST and reflectance spectrophotometry showed significantly decreased color difference and increased percent extension compared with the samples pre-irradiated without agent application.

• 한국도로학회논문집
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• 제11권2호
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• pp.111-120
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• 2009

본 연구는 배수성 아스팔트 포장의 표면을 아크릴 수지로 코팅 처리할 경우 내구성 측면 및 기능적 측면에서 어떠한 효과가 있는가를 실내시험을 통해 평가하는 기초적인 연구이다. 포장의 내구성 측면에서는 칸타브로 및 휠트래킹, 수분손상 간접 인장 피로 시험 등을 실시하였다. 시험결과 시편을 수지로 코팅을 한 경우 칸타브로 손실률이 3배 정도 감소되었고 균열에 대한 저항성도 대폭 향상되었으나 수분손상 및 소성변형의 저항성은 큰 차이가 없는 것으로 나타났다. 기능적인 측면에서는 코팅 전 후의 투수계수 및 공극률 BPT(British Pendulum Tester)를 사용한 미끄럼 저항성의 변화를 측정하였다. 시험결과 공극률 및 투수계수는 약간 저하되나 기능상의 문제는 없을 것으로 판단되며, 미끄럼 저항성은 규사를 살포하지 않을 경우 미끄럼 저항성이 감소되나 규사를 살포할 경우 코팅 전 수준 이상의 미끄럼 저항성을 확보하는 것으로 나타났다.

• 자원리싸이클링
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• 제21권5호
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• pp.50-57
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• 2012

황산동 용액중에 불순물로 존재하는 Sb, Bi 및 As를 제거하기 위해 Aminophosphosphonic acid를 관능기로 함유한 이온교환수지를 사용하여 비교 실험을 실시하였다. 이들 불순물 제거 반응에 영향을 미칠 수 있는 반응온도, 반응시간, 이온교환수지양 등에 대하여 고찰하였다. 기초 실험 결과 약 88%의 Sb 및 94%의 Bi가 이온교환수지에 흡착되어 황산동용액으로부터 제거가 가능하였다. 그러나 As의 경우는 제거율이 10% 이하로 미미하였다. 한편, Bi 와 Sb가 흡착된 수지에서 황산과 염산용액을 이용하여 선택적으로 세출이 가능하였다. 연속흡착실험 결과 Sb 와 Bi의 경우는 2BV 후에는 98.1%와 96.6%의 높은 흡착율을 보였다.

• Composites Research
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• 제34권2호
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• pp.96-100
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• 2021

The lightweight industry continuously demands reliable near-net-shape fabrication where the preform just out-of-machine is close to the final shape. In this study, different half-finished preforms are made π-beams. Then the preforms are unfolded to make a 3D shape with integrated structure of fibers, providing easier handling in the further processing of composites. Several 3D textile preforms are made using weaving technique and are examined after resin infusion for mechanical properties such as inter-laminar shear strength, compressive strength and tensile strength. Considering that the time and labor are important parameters in modern production, 3D weaving technique reduces the manufacturing steps and therefore the costs, such as hand-lay up of textile layers, cutting, and converting into preform shape. Hence this 3D weaving technique offers many possibilities for new applications with efficient composite production.

• 한국의류학회지
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• 제34권11호
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• pp.1859-1869
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• 2010

This study provides improved wrinkle recovery and UV protection capabilities as well as an antibacterial and deodorizing function to linen fabrics for summer shirts. The results obtained from this study are as follows. By setting catalyst concentration to 1.2% and DMDHEU concentration to 6% respectively and applying a heat treatment to them at $160^{\circ}C$ for 5 minutes, the decrease of fabric strength could be minimized and the crease resistance of linen fabrics improved. Compared to the treatment with DMDHEU only, the crease resistance of linen fabrics could be maintained and degradation of their properties could be more effectively prevented by applying the mixture of the UV absorber and the nano silver to the DMDHEU resin. The UV protection of fabrics could be improved by adding the UV absorber. Although the separate treatment of resin or the nano silver had no effect on the improvement of the UV protection properties for treated fabrics, they could increase the UV protection capability when they were combined with the UV absorber. Linen fabrics could possess an antibiosis and deodorizing capability by applying the mixture of the UV absorber, the nano silver, and the resin. The UV protection, crease resistance and flexibility of finished fabrics were maintained even after laundering. Washed treated fabrics maintained excellent antibiosis and odor free capabilities compared to untreated fabrics.

• 한국정밀공학회:학술대회논문집
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• 한국정밀공학회 2000년도 춘계학술대회 논문집
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• pp.824-828
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• 2000

As production cycle has become more and more shorter, the demand of rapid prototyping technology has increased largely. There are many methods for rapid prototyping technology, such as SLA. SLS, FDM. INK JET, LOM and so on. Of all methods, SLA has been most widely used for fabricating precision parts. But products manufactured by this method have limitation of single color and single material. So the principal purpose of this study is to overcome the limit of single color product. If the internal structure of manufactured product is visible with multi-color characteristic, it is possible to check easily the designed model with reality. In order to give multi-color characteristic to the product, photocurable resin mixed with pigment is used in this study. First, transparency of photocurable resin without pigment is evaluated, and then color characteristic and curing characteristic of the mixture is evaluated changing mixing ratio. Through the basic experiments, it becomes possible to fabricate multi-color 3D prototype without assembly.

• 한국정밀공학회지
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• 제18권12호
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• pp.60-65
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• 2001

To simulate the real molding conditions, the effects of phase change and compressibility of the resin were considered in the present investigation. A modified Cross model with either an Arrhenius-type or WLF-type functional form was used for modeling viscosity of the resin. A double-domain Tait equation of state was employed to describe the compressibility of the resin during molding. The energy balance equation including latent-heat dissipation fur semi-crystalline materials was solved in order to predict the solidified layer and temperature profile. Injection molding experiments were carried out using polypropylene(PP) in the present study. Based on the comparison between experiments and simulations, it was found out the predicted pressure distributions and melt front propagations were accurate. Thus it was concluded that the program developed in this study was proved to be useful in simulations of injection molding process.

• Journal of the Korean Wood Science and Technology
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• 제31권6호
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• pp.83-88
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• 2003

The woodceramics are porous amorphous carbon and glassy carbon composite materials. Woodceramics attracted a lot of attention in recent years because they are environmentally friendly and because of their unique functional characteristics such as catalysis, moisture absorption, deodorization, purification, carrier for microbial activity, specific stiffness, corrosion and friction resistance, and their electromagnetic shielding capacity. In this paper, we made new products of clay-woodceramics to investigate the industrial analysis and ethylene gas adsorption for basic data of building- and packging- materials keeping fruit fresh for a long time. Clay-woodceramics were carbonized for 3 h of heating in a special furnace under a gas flow of nitrogen(15 ml/min.) from 3 layers-clay-woodparticleboard made from pallet waste wood, phenol- formaldehyde resin(hereafter PF, Non volatile content:52%, resin content 30%), and clay(10%, 20% and 30%). Carbonization temperature was 400℃, 600℃ and 800℃. Experimental results shows that the higher the carbonization temperature, the higher the fixed carbon and the lower the volatile contents. The higher the clay content, the more the ash content. The higher the carbonization temperature, the more the ethylene gas adsorption. Carbonization temperature of 800℃ gave the best reslts as same as that of white charcoal and activated carbon.(800℃-clay-woodceramic: 5.36 ppm, white charcoal: 5.66 ppm, activated carbon: 5.79 ppm) The clay contents did not make difference of ethylene gas adsoption.

• 한국복합재료학회:학술대회논문집
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• 한국복합재료학회 2002년도 춘계학술발표대회 논문집
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• pp.143-146
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• 2002

Unsized AS-4 carbon fibers were etched by RF plasma and then coated via plasma polymerization in order to enhance adhesion to vinyl ester resin. The gases utilized for the plasma etching were Ar, $N_2 and O_2$, while the monomers used for the plasma polymerization coating were acetylene, butadiene and acrylonitrile. The conditions for the plasma etching and the plasma polymerization were optimized by measuring interfacial adhesion with vinyl ester resin via micro-droplet tests. Among the treatment conditions, the combination of Ar plasma etching and acetylene plasma polymerization provided greatly improved interfacial shear strength (IFSS) of 69MPa compared to 43MPa with as-received carbon fiber. Based on the SEM analysis of failure surface and load-displacement curve, it was assume that the failure might be occurred at the carbon fiber and plasma polymer coating. The plasma etched and plasma polymer coated carbon fibers were subjected to analysis with SEM, XPS, FT-IR or Alpha-Step, and dynamic contact angles and tensile strengths were also evaluated. Plasma polymer coatings did not change tensile strength and surface roughness of fibers, but decreased water contact angle except butadiene plasma polymer coating, possibly owing to the functional groups introduced, as evidenced by FT-IR and XPS.