• Title/Summary/Keyword: Functional polymer

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A Study on Electrical Modeling for Charge/Discharge Analysis of Li-Polymer Battery (리튬폴리머전지의 충/방전 특성해석을 위한 진기적모델링에 관한 연구)

  • 최해룡;반한식;목형수;신우석;고장면
    • The Transactions of the Korean Institute of Power Electronics
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    • v.5 no.5
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    • pp.435-442
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    • 2000
  • Started upon Its discovery by Wright et al in 1773, studies on the solid polymer electrolyte are being carried out vigorously. So, models of Li-polymer battery have been developed through R-L-C components combination and PSpice functional block in this parer. The impedance characteristics of Li-polymer battery with R-L-C components are presented. Simulation results using PSpice functional model are compared with measured charge/discharge characteristics. Also, as to the number of cycle(charge/discharge), coulomb efficiency of Li-polymer is evaluated through experimental results.

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Morphology of Membranes Formed from Polysulfone/Polyethersulfone/N-methyl-2-pyrrolidone/Water System by Immersion Precipitation

  • Baik, Ki-Jun;Kim, Je-Young;Lee, Jae-Sung;Kim, Sung-Chul;Lee, Hwan-Kwang
    • Macromolecular Research
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    • v.9 no.5
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    • pp.285-291
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    • 2001
  • The polysulfone(PSf)/polyethersulfone(PES) blend membranes were prepared by an immersion precipitation method. N-methyl-2-pyrrolidone(NMP) was used as a solvent and water as a nonsolvent. The composition of the coagulation bath and the dope polymer concentration as well as the blend ratio of two polymers were varied. The membrane morphologies were interpreted on the basis of the phase diagram of the PSf/PES/NMP/water system. As the solvent content in the coagulation bath increased in the single polymer system, the number of macrovoids decreased and the morphology was changed from finger-like to cellular structure. In the given bath condition phase separation occurs earlier for the solutions of PSf/PES blend than for those of single polymer. A horizontally layered structure and horizontal protuberances inside the macrovoid were observed for the membranes formed from PSf/PES blend solutions. This peculiar structure formation can be interpreted by a PSf-rich/PES-rich phase separation followed by a polymer-rich/polymer-lean phase separation during the exchange of solvent and nonsolvent.

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Effects of Absorbent Polymer on the Moisture Resistance and Hydration Characteristics of Cement Pastes (시멘트 페이스트의 특성에 미치는 흡수성폴리머의 영향)

  • 나종균;김창은;이승규
    • Journal of the Korean Ceramic Society
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    • v.36 no.5
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    • pp.539-546
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    • 1999
  • Absorbent polymer-cement composites were fabricated by the semi-powder mixing OPC(ordinary Portland cement) with an absorbent polymer. The effects of absorbent polymer on the mechanical properties and the hydration characteristics were observed and the polymer-cement interaction also discussed. Absorbent polymer-cement composites showed the value of total porosity of 8vol% the value of 28 days flexural strength was up to 280 Kgf/cm2 in the case of absorbent polymer-cement composite at 1 wt% absorbent polymer content and microstructure of absorbent polymer-cement composite has been observed more dense than that of OPC paste. Accordingly the permeability of compositewas improved and so the moisture resistance was also increased. Adding polymer did not retard the hydration of OPC. It was considered from the results of IR(infrared) analysis that the functional group of absorbent polymer would be changed from unidentate to bidentate during by the hydration of cement minerals.

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Conducting Polymers with Functional Dopants and their Applications in Energy, Environmental Technology, and Nanotechnology

  • Kim, Sung Yeol;Song, Hyun-Kon
    • Clean Technology
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    • v.21 no.1
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    • pp.12-21
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    • 2015
  • Development of novel conducting polymers (CPs) is expected to facilitate the advancement of functional materials used for energy, environmental, and nanotechnology. Recent research efforts are focused on doping CPs with functional dopants to enhance their performance or add additional functions that are not inherent in CPs. This review surveys literatures about the doped CPs focusing on the roles of functional dopants, unlike other reviews focusing on the development of new conducting polymer backbones. The functional dopants presented in this review include redox active molecules, carbon nanomaterials, biopolymers, and chelating molecules. Depending on the dopants and their physicochemical properties, the doped CPs can be used for a variety of applications such as polymer batteries, membranes for waste water treatment, and chemical sensors. A major challenge of the CPs is presented and the ways to overcome the challenge is also suggested for the future development of stable, high performance CPs.

Organic Solvent Absorption characteristics of Split-type micro fiber fabrics

  • Lee, Kwang-Ju;Kim, Seong-Hun
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.10a
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    • pp.95-95
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    • 2003
  • In this study, the influences of organic solvent viscosity on absorption properties of split-type micro fiber fabrics is examined with real time absorption measurement device built by our research group recently. And the absorption behavior of these fabrics is analyzed by material, fineness, construction, weight, thickness, and density of fabrics.

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Fibrillation in TLCP/Polyester Binary Blends

  • Kim, Jun-Young;Kim, Seong-Hun
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.10a
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    • pp.101-101
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    • 2003
  • TLCP/Polyester binary blends were prepared by melt blending. Rheological, morphological, and thermal properties of of TLCP/polyester blends were investigated with viscosity ratio. Diameter of TLCP fibrils decreased with viscosity ratio. More and smaller TLCP fibrils were obtained at higher shear rate. Lower viscosity ratio was necessary for the fibrillation of TLCP in the binary blends.

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Structure and Properties of TLCP/Polyester Composite Fibers

  • Kim, Jun-Young;Kim, Seong-Hun
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.10a
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    • pp.102-102
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    • 2003
  • TLCP/polyester composite fibers (TPCFs) based on melt blends of PEN, PET, and TLCP were prepared by melt blending and spinning process to achieve high performance fibers. Reinforcement effect and TLCP fibrillar structure resulted in improvement of mechanical properties for TPCFs. The increase in the apparent crystallite size was attributed to the development of larger crystallites and more ordered crystalline structures in the annealed TPCFs. Molecular orientation was an important factor to determine mechanical property of TPCFs.

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Preparation of polyaniline/cyanoethyl resin blends

  • Kim, Tae-Kyun;Kim, Seong-Hun;Oh, Kyung-Wha
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.10a
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    • pp.93-93
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    • 2003
  • Electrically conducting polyaniline/cyanoethyl resin (PANI/Cyan) blends were prepared by in situ polymerization. The mechanical properties of the blend films increased with increasing cyanoethyl resin and the blend films have moderate conductivity.

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Preparation and Properties of Hyperbranched Polymers

  • Kakimoto, Masa-Aki
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.97-98
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    • 2006
  • After general introduction for hyperbranched polymers, hyperbranched polysiloxysilanes (HBPS) were introduced as new functional polymers. Vinyl terminated HBPS was synthesized starting from AB2 type monomer by hydrosilylation reaction. Vinyl group can be converted various functional groups such as carboxylic acid and alcohol. HBPS had strong interaction to inorganic surface. As an example of this phenomenon, silica gel bead for HPLC was modified with thermo sensitive polymers. The resulting bead was successfully applied to Green Chronatography.

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