• Title/Summary/Keyword: Functional polymer

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Study on the IPMC electrical characteristic change For the utilization of Ocean Current Energy (IPMC 해양 발전 플랜트 모니터링 시스템)

  • Son, Kyung-Min;Kim, Min;Kim, Hyun-jo;Park, Gi-Won;Byun, Gi-Sik
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2013.10a
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    • pp.914-916
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    • 2013
  • Renewable energy from the environment in a variety of ways to obtain various forms of energy. Recent functional polymer composites (EAP) to take advantage of the pressure and vibration of physical energy into electrical energy storage, to take advantage of current collector technology is attracting attention. EAP, a type of IPMC (Ionic exchange Polymer Composite) got a hydrophilic properties, marine power plants is being studied as a source of energy. Studies using IPMC marine power plant because there is a constraint on the time, IPMC in real time, which can measure the power generated by the system is required, Due to the nature of the power plant to be floating in the sea through the power cable and data transmission measurement system is hard drive self-generation and wireless data transmission system is required. In this study, IPMC marine power plant is to develop a system of monitoring. IPMC for several power plants to build individual current-voltage measurement system, CAN communication with the main system to collect all the information and wireless data transmission to occur, and Generation of electricity using solar energy to building systems in real-time without an external power supply to drive the measuring system is to develop a monitoring system.

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Enhanced Properties of Epoxy Molding Compound by Plasma Polymerization Coating of Silica (실리카의 플라즈마 중합 코팅에 의한 에폭시 봉지재의 물성 향상 연구)

  • Roh, J.H.;Lee, J.H.;Yoon, T.H.
    • Journal of Adhesion and Interface
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    • v.2 no.2
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    • pp.1-10
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    • 2001
  • Silica for Epoxy Molding Compound (EMC) was coated via plasma-polymerization with RF plasma (13.56 MHz) as a function of treatment time, power and pressure. 1,3-diaminopropane, allylamine, pyrrole, 1,2-epoxy-5-hexene, allylmercaptan or allylalcohol were utilized for plasma polymerization coating and adhesion of coated silica was evaluated by measuring flexural strength. CTE and water absorption of EMC were also measured, and fracture surface of flexural specimen was analyzed by SEM in order to elucidate the failure mode. The plasma polymer coated silica was analyzed by FT-IR and reactivity of plasma polymer coating with epoxy resin was evaluated with DSC in order to investigate the adhesion mechanism. The EMC prepared from the silica coated with 1,3-diaminopropane or allylamine exhibited high flexural strength, low CTE, and low water absorption compared with the control sample, and also exhibited 100% cohesive failure mode. These results can be attributed to the chemical reaction between the functional groups in the plasma polymer coating and epoxy resin, and also consistent with the results from FT-IR and DSC analysis.

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Surface Modification of PET Irradiated by Ultra-Violet (Part I) -Transformation of Chemical Structure and Surface Properties- (UV조사를 통한 PET의 표면개질 (제1보) -화학구조 변화 및 표면특성 변화-)

  • Choi Hae Young;Lee Jung Soon
    • Journal of the Korean Society of Clothing and Textiles
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    • v.29 no.3_4 s.141
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    • pp.561-568
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    • 2005
  • The irradiation of Ultra-Violet (UV) is an efficient treatment for polymer to improve hydrophilic properties. 4-Channel PET knit fabrics were treated with UVA and UVC to develop functional and environment-friendly fabric. The fabric was treated with various treatment times and distances from UV lamps having different wavelength. FT-IR and XPS investigated the chemical changes. To confirm the change of surface properties, contact angle, surface energy and SEM were examined. The study of UV as a treatment for PET knit fabric shows significant changes in chemical and surface properties, which is proved by analyses. FT-IR and XPS analyses prove the augmentation of carboxylic, Hydrophilic groups on the surfaces treated by UV. The increase of water contact angle and surface energy means more water wettable and surface energy of PET film was substantially increased by UV irradiation time. The ageing after surface treatment had little influence on the surface energy of the irradiated PET film. SEM proves the surface modification of PET such as etching, bubble and crack. The negative effects are increased in accordance with increasing treatment time.

Synthesis, and Structural and Thermal Characterizations of Tetrasulfonated Poly(arylene biphenylsulfone ether) Copolymer Ion Conducting Electrolytes

  • Yoo, Dong-Jin;Hyun, Seung-Hak;Kim, Ae-Rhan;Kumar, G. Gnana;Nahm, Kee-Suk
    • Bulletin of the Korean Chemical Society
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    • v.32 no.11
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    • pp.4041-4048
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    • 2011
  • High molecular weight tetrasulfonated poly(arylene biphenylsulfone ether) (TsPBPSEH) copolymers containing up to four pendant sulfonate groups per repeat unit were synthesized via aromatic nucleophilic displacement condensation from 4,4'-bis(4-chloro-3-sulfonatophenylsulfonyl)biphenyl-2,2'-disulfonate (SBCSBPD), 4,4'-dichlorodiphenylsulfone (DCDPS) and 4,4'-(hexafluoroisopropylidene)diphenol (6F-BPA). The synthesized copolymers were structurally characterized using $^1H$ NMR and FT-IR techniques. They were analytically pure, amorphous and were readily soluble in a wide range of organic solvents. Electrolyte membranes were successfully cast using the synthesized polymers with various sulfonation levels and N-methyl-2-pyrrolidinone. This new class of polymer membranes exhibited elevated thermal and physical stabilities and reduced swelling at high temperatures. An increase of acidic functional groups in the copolymer yielded high ion exchange capacity and moderate ionic conductivity values even at higher temperatures, which makes them potential ion conducting candidates.

Improvement of Weldlines of an Injection Product in Using Movement of a High Temperature Gas (고온기체 유동을 이용한 사출성형품의 웰드라인 개선)

  • Jung, Jae-Sung;Lee, Young-Joo;Min, Kyung-Bae;Song, Bo-Keun;Kim, Hee-Sung;Kim, Sun-Kyung
    • Design & Manufacturing
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    • v.8 no.1
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    • pp.19-22
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    • 2014
  • Today, looking at the trend of product development, interests of injection technology to reduce weldline are growing because of increases of polymer composite materials that containing functional elements and demand of no-painted injection in accordance with environmental regulations. In this paper, surface temperatures of mold increased using high temperature gas for elimination of weldline and characteristics of weldline are analyzed according to mold temperature($60^{\circ}C{\sim}120^{\circ}C$).

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Synthesis of Poly(epoxy-imide)-Nano Silica Hybrid Film via CS Sol-gel Process and Their Dielectric Properties (CS졸을 이용한 Poly(epoxy-imide)-나노 Silica 하이브리드 필름의 합성과 유전특성)

  • Han, Se-Won;Han, Dong-Hee;Kang, Dong-Pil;Kang, Young-Taec
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.20 no.1
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    • pp.35-40
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    • 2007
  • The new PEI(poly(epoxy-imide))-nano Silica film has been synthesized via in situ CS sol process, and the chemical bonding and microstructure of nano silica dispersed in resin were examined by FT-IR, TAG and SEM. The dielectric properties of these hybrid films over a given temperature and frequency ranges have been studied in a point of view of stable chemical bonding of nano Silica filler. The results from IR spectra and SEM photograph indicated that PEI-Silica hybrid film prepared with nano CS sol process has been synthesized in uniform and chemical bonding. The decrease property of dielectric constant with CS content, tangent loss consistent of given frequency and temperature has been explained in terms of the chain movement of polymer through chemical bonging and size effect of nano silica. The new PEI-CS sol hybrid film with such stable chemical and dielectric properties was expected to be used as a high functional coating application in ET, IT and electric power products.

Strategy for enhancing Production of recombinant Protein in tobacco's suspension culture

  • Lee, Dong-Geun;Lee, Jae-Hwa
    • Proceedings of the Korean Society of Life Science Conference
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    • 2002.12a
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    • pp.48-60
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    • 2002
  • Granulocyte-macrophage colony-stimulating factor (GM-CSF) is a cytokine that stimulates the production of granulocytes, macrophages, and white blood cells. The effects of osmotic pressure on secretion of human GM-CSF into the culture medium were investigated in suspension cultures of transgenic tobacco cells. An increase in osmotic pressure caused by the addition of mannitol decreased the cell size index, with the effect being more pronounced when cells were measured wet rather than dry. Increased osmotic pressure enhanced the secretion of hGM-CSF. At 90 g/L mannitol, the maximum concentration tested, hGM-CSF was present in the culture medium at 980 ug/L. As the concentration of mannitol increased, the total amount of protein secreted also increased, but was disproportionately enriched in GM-CSF NaCl, another osmoticum, had very similar effects on cell growth and hGM-CSF production, but did not cause enrichment for hGM-CSF Additionally, protein-stabilizing polymer was added to culture broth to enhance stability of secreted recombinant protein. Finally, above two method were applied together to maximize the productivity.

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Fiber Orientation distribution of Injection Molded Product on the Fiber-Reinforced Polymeric Composites (섬유강화 복합재료 사출성형품의 섬유배향상태)

  • Lee, J.J.;Kim, J.W.;Kim, H.;Han, G.Y.;Sim, J.K.;Lee, D.G.
    • Proceedings of the Korean Society of Machine Tool Engineers Conference
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    • 2004.04a
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    • pp.76-81
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    • 2004
  • Injection molding is the most widely used process fir the industrial forming of plastic articles. During an injection molding process of composites, the fiber-matrix separation and fiber orientation are caused by the flow of molten polymer/fiber mixture. As a result. the product tends to be nonhomogeneous and anisotropic. Hence, it is very important to clarify the relations between separation orientation and injection molding conditions. So far, there is no research on the measurement of fiber orientation using image processing. In this study, the effects of fiber content ratio and molding condition on the fiber orientation-angle distributions are studied experientially. Using the image processing method, the fiber orientation distribution of welding pars in injection-molded products is assessed. And the effects of fiber content and injection mold shapes on the fiber orientation in case of fiber reinforced polymeric composites are studied experimentally.

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Fabrication of a Parallel Polymer Cantilever to Measure the Contractile Force of Drug-treated Cardiac Cells (약물처리된 심장세포의 세포 수축력 측정을 위한 병렬 폴리머 캔틸레버 제작)

  • Kim, Dong-Su;Lee, Dong-Weon
    • Journal of Sensor Science and Technology
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    • v.29 no.2
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    • pp.100-104
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    • 2020
  • Thus far, several in vivo biosensing platforms have been proposed to measure the mechanical contractility of cultured cardiomyocytes. However, the low sensitivity and screening rate of the developed sensors severely limit their practical applications. In addition, intensive research and development in cardiovascular disease demand a high-throughput drug-screening platform based on biomimetic engineering. To overcome the drawbacks of the current state-of-the-art methods, we propose a high-throughput drug-screening platform based on 16 functional high-sensitivity well plates. The proposed system simulates the physiological accuracy of the heart function in an in vitro environment. We fabricated 64 cantilevers using highly flexible and optically transparent silicone rubber and placed in 16 independent wells. Nanogrooves were imprinted on the surface of the cantilever to promote cell alignment and maturation. The adverse effects of the cardiovascular drugs on the cultured cardiomyocytes were systematically investigated. The 64 cantilevers demonstrated a highly reliable and reproducible mechanical contractility of the drug-treated cardiomyocytes. Real-time high-throughput screening and simultaneous evaluation of the cardiomyocyte mechanical contractility under multiple drugs verified that the proposed system could be used as an efficient drugtoxicity test platform.

Fluorescence Microscopy of Condensed DNA Conformations of Bacterial Cells

  • Suleymanoglu, Erhan
    • Journal of Microbiology
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    • v.40 no.4
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    • pp.319-326
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    • 2002
  • Cellular DNA in prokaryotes is organized in nucleic acid-protein self-assemblies referred to as the nucleoid. The physical forces responsible for its stability inside the poor solvent properties of the cytoplasm and their functional implications are not understood. Studies on the organisation and functioning of the cytosol of cells largely rely on experimental protocols performed in highly dilute solutions using biochemically purified molecules, which is not a reliable substitute for the situation existing in vivo. Our current research interest is focused on the characterization of biological and physical forces determining the compaction and phase separation of DNA in Escherichia coli cytoplasm. We have emphasized the effect of excluded volume in solutions with high macromolecular concentrations (macromolecular crowding) upon self-association patterns of reactions. The prokaryotic cytosol was simulated by addition of inert polymer polyethylene glycol (PEG) (average molecular weight 20000), as an agent which afterwards facilitates the self-association of macromolecules. Fluorescence microscopy was used for direct visualization of nucleoids in intact cells, after staining with DAPI (4',6-diamidino-2-phenylindole dihydrochloride). Addition of the crowding agent PEG 20,000, in increasing concentrations generated progressively enhanced nucleoid compaction, the effect being stronger in the presence of 0.2 M NaCl and 5 mM MgCl$\_$2/. Under these conditions, the nucleoids were compacted to volumes of around 2 ㎛$\^$3/ or comparable sizes with that of living cells.