• Title/Summary/Keyword: Functional polymer

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Synthesis of Amphiphilic Block Copolymers having controlled structures via ATRP (원자이동 라디칼 중합을 이용한 분자구조가 제어된 양친매성 고분자의 합성)

  • An, Sung-Guk;Cho, Chang-Gi
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.04a
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    • pp.1-4
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    • 2003
  • The design and synthesis of new polymers is desirable to obtain materials with novel physical properties. Generally, these new polymers have their well-defined nature with the number of functional groups, molecular weight, polydispersity, and the presence or absence of branching being precisely controlledl. These polymers are mainly synthesized by living polymerizations to control of their structures. Among of various living polymerization Atom transfer radical polymerization (ATRP) has been a field of intensive research in recent years1. (omitted)

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Stacking of functional inks for organic solar cell using inkjet printing (잉크젯 프린팅을 이용한 유기태양전지용 기능성 잉크의 적층)

  • Kim, Myong-Ki;Hwang, Jun-Young;Lee, Sang-Ho;Kang, Heui-Seok;Kang, Kyung-Tae;Kim, Jong-Seok;Cho, Young-Joon
    • 한국신재생에너지학회:학술대회논문집
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    • 2008.05a
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    • pp.398-401
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    • 2008
  • Inkjet printing is commonly used in the controlled deposition of solutions of functional materials in specific locations on a substrate, and it can provide easy and fast deposition of polymer films over a large area. which could become a way to manufacturer low cost solar cells. In the present study, inkjet printing technology is adopted to deposit functional layers of PEDOT/PSS solutions and P3HT/PCBM blends for organic solar cell. The results show that merging of separately deposited ink droplets into a continuous, pinhole-free organic thin film could be achieved by a balance between ink property and substrate treatment. As a result, a power conversion efficiency of 2.0% has been accomplished a solar cells applying inkjet technology.

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Functional Prototype Development (기능성 시작품 개발)

  • 정해도;임용관;조진구;정은수;양동열
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2000.11a
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    • pp.755-758
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    • 2000
  • Rapid prototyping is one of the most important technology for 21th century industry. To overcome the limitation of the material and function, Functional Prototype Development(FPD) concept is newly proposed. Wide function is necessary such as mechanical, optical, chemical and electrical property in order to solve broad requirements of the industry. The process of FPD has more than two conventional processes based on fusion technology and the FPD system is integrated with the interdisciplinary, interfacing and intelligent concepts. This paper shows some representative achievements such as optic coloring prototypes, electric multi layer printed circuit broad(MLB) and MEMS using electrostrictive polymer. Finally, we confirmed that FPD has a great possibility which can be applied in broad industry and will be a powerful tool in near future.

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Synthesis and Characterization of 1,2,4-Oxadiazole-Based Deep-Blue and Blue Color Emitting Polymers

  • Agneeswari, Rajalingam;Tamilavan, Vellaiappillai;Hyun, Myung Ho
    • Bulletin of the Korean Chemical Society
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    • v.35 no.2
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    • pp.513-517
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    • 2014
  • Two donor-acceptor-donor monomers such as 3,5-bis(4-bromophenyl)-1,2,4-oxadiazole (BOB) and 3,5-bis(5-bromothiophen-2-yl)-1,2,4-oxadiazole (TOT) incorporating electron transporting and hole blocking 1,2,4-oxadiazloe moiety were copolymerized with light emitting fluorene derivative via Suzuki polycondensation to afford two new polymers, PFBOB and PFTOT, respectively. The optical studies for polymers PFBOB and PFTOT revealed that the band gaps are 3.10 eV and 2.72 eV, respectively, and polymer PFBOB exhibited a deep-blue emission while polymer PFTOT showed blue emission in chloroform and as thin film. The photoluminescence quantum efficiencies (${\Phi}_f$) of polymers PFBOB and PFTOT in chloroform calculated against highly blue emitting 9,10-diphenylanthracene (DPA, ${\Phi}_f=0.90$) were 1.00 and 0.44, respectively.

Fabrication of Conducting Polymer Nanowires using Block Copolymer Nano-porous Templates for Photovoltaic Device

  • Lee, Jeong-In;Yu Jae-Woong;Kim, Jin-Kon;Russell Thomas P.
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.312-312
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    • 2006
  • Block copolymers with well-defined nanoscopic structures have recently gained much attention for their potential uses as functional nanostructures. Here, we show that nanoporous templates made from polystyrene-block-poly (methyl methacrylate) (PS-b-PMMA) satisfy a novel design concept. At first, arrays of nanoscopic cylindrical microdomains oriented normal to the surface can easily be prepared. Then, we fabricated ultra high density arrays of conducting polymer as poly(pyrrole) (Ppy) and poly(3,4-ethylenedioxythiophene) (PEDOT) nanowires with diameters of $25{\sim}40\;nm$ on the ITO glass by electropolymerization of the monomers inside nanoholes. These high density arrays of conducting polymer nanowires could be used as P-type materials for photovoltaic devices.

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Progress of Study on Mesogen-Jacketed Liquid Crystalline Polymers at Peking University

  • Fan, Xing-He;Chen, Xiao-Fang;Wan, Xin-Hua;Chen, Er-Qiang;Zhou, Qi-Feng
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.90-90
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    • 2006
  • Mesogen-Jacketed Liquid Crystalline Polymers, MJLCPs, are polymers with mesogenic side groups directly attached to main-chains without using flexible connecting spacers and are able to form liquid crystalline structures. Later work on structure-property of the polymers revealed that the side groups are not necessarily mesogenic for the polymers to form a mesophase so long as that the side groups are directly attached to the backbones and the side groups are large enough. Because of its inherent chain stiffness and that the monomers of MJLCPs are readily polymerizable by "living" free radical polymerizations, MJLCP offered a unique handy tool for making block copolymers. In addition, MJLCP offered also new opportunities for novel functional materials.

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