• Title/Summary/Keyword: Functional nanomaterials

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Status of nano-packaging and safety management of nanomaterials by migration (나노포장의 개발 및 나노물질 이행에 따른 안전관리 현황)

  • Lee, Jae Yeol;Jo, Yumi;Choi, Jae Chun;Park, Se-Jong;Kim, Jun Tae
    • Food Science and Industry
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    • v.50 no.2
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    • pp.52-59
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    • 2017
  • Nano-packaging is defined as food packages produced with nanoparticles or using nanotechnology in their process. Nano-packaging has become more available in the current market because of its enhanced functional properties such as antimicrobial and barrier properties. However, consumers have worried about toxicity by migration of nanomaterials from packaging to food. Currently, many commercialized products are coated or composited with inorganic nanomaterials such as nanosilver, nanoclay, zinc oxide, titanium dioxide, and so on. In this study, nanomaterials used in food packaging were classified and the commercially available nano-packaging were screened. Study on the migration of nanomaterials in various food simulants was also summarized.

Production of Functional Colloids and Fibers from Phase Separation During Electrohydrodynamic Process

  • Jeong, Un-Ryong
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2011.10a
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    • pp.1.2-1.2
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    • 2011
  • Electrohydrodynamics is a good approach to produce uniform-sized colloids and fibers in a continuous process. The dimension can be controlled from tens of nanometers to a few micrometers. The structure of the colloids and nanofibers from electrohydrodynamics has been diversified according to the uses. Especially, core-shell structure and hybridization with functional nanomaterials are fascinating due to their possible uses in drug-delivery systems, multifunctional scaffolds, organic/inorganic hybrids with new functions, and highly sensitive gas- or bio-sensors. This talk will present the structural variations in the colloids and fibers by simply employing phase separation during electrohydrodynamic process and demonstrate their possible applications.

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Atomic structure and crystallography of joints in SnO2 nanowire networks

  • Hrkac, Viktor;Wolff, Niklas;Duppel, Viola;Paulowicz, Ingo;Adelung, Rainer;Mishra, Yogendra Kumar;Kienle, Lorenz
    • Applied Microscopy
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    • v.49
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    • pp.1.1-1.10
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    • 2019
  • Joints of three-dimensional (3D) rutile-type (r) tin dioxide ($SnO_2$) nanowire networks, produced by the flame transport synthesis (FTS), are formed by coherent twin boundaries at $(101)^r$ serving for the interpenetration of the nanowires. Transmission electron microscopy (TEM) methods, i.e. high resolution and (precession) electron diffraction (PED), were utilized to collect information of the atomic interface structure along the edge-on zone axes $[010]^r$, $[111]^r$ and superposition directions $[001]^r$, $[101]^r$. A model of the twin boundary is generated by a supercell approach, serving as base for simulations of all given real and reciprocal space data as for the elaboration of three-dimensional, i.e. relrod and higher order Laue zones (HOLZ), contributions to the intensity distribution of PED patterns. Confirmed by the comparison of simulated and experimental findings, details of the structural distortion at the twin boundary can be demonstrated.

Inorganic nanomaterial-based biocatalysts

  • Lee, Soo-Youn;Lee, Ji-Ho;Chang, Jeong-Ho;Lee, Jin-Hyung
    • BMB Reports
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    • v.44 no.2
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    • pp.77-86
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    • 2011
  • Over the years, nanostructures have been developed to enable to support enzyme usability to obtain highly selective and efficient biocatalysts for catalyzing processes under various conditions. This review summarizes recent developments in the nanostructures for enzyme supporters, typically those formed with various inorganic materials. To improve enzyme attachment, the surface of nanomaterials is properly modified to express specific functional groups. Various materials and nanostructures can be applied to improve both enzyme activity and stability. The merits of the incorporation of enzymes in inorganic nanomaterials and unprecedented opportunities for enhanced enzyme properties are discussed. Finally, the limitations encountered with nanomaterial-based enzyme immobilization are discussed together with the future prospects of such systems.

MEMS/Nano-technologies for Smart Air Environmental Monitoring Sensors

  • Park, Inkyu;Yang, Daejong;Kang, Kyungnam
    • Journal of Sensor Science and Technology
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    • v.24 no.5
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    • pp.281-286
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    • 2015
  • The importance of air quality monitoring is rapidly increasing. Even though state-of-the-art air quality monitoring technologies such as mass spectrometry, gas chromatography, and optical measurement enable high-fidelity measurement of air pollutants, they cannot be widely used for portable or personalized platforms because of their high cost and complexity. Recently, personalized and localized environmental monitoring, rather than global and averaged environmental monitoring, has drawn greater attention with the advancement of mobile telecommunication technologies. Here, micro- and nano-technologies enable highly integrated and ultra-compact sensors to meet the needs of personalized environmental monitoring. In this paper, several examples of MEMS-based gas sensors for compact and personalized air quality monitoring are explained. Additionally, the principles and usage of functional nanomaterials are discussed for highly sensitive and selective gas sensors.

Molecular interactions between pre-formed metal nanoparticles and graphene families

  • Low, Serena;Shon, Young-Seok
    • Advances in nano research
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    • v.6 no.4
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    • pp.357-375
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    • 2018
  • Two dimensional (2D) atomic layered nanomaterials exhibit some of the most striking phenomena in modern materials research and hold promise for a wide range of applications including energy and biomedical technologies. Graphene has received much attention for having extremely high surface area to mass ratio and excellent electric conductivity. Graphene has also been shown to maximize the activity of surface-assembled metal nanoparticle catalysts due to its unique characteristics of enhancing mass transport of reactants to catalysts. This paper specifically investigates the strategy of pre-formed nanoparticle self-assembly used for the formation of various metal nanoparticles supported on graphene families such as graphene, graphene oxide, and reduced graphene oxide and aims at understanding the interactions between ligand-capped metal nanoparticles and 2D nanomaterials. By varying the functional groups on the ligands between alkyl, aromatic, amine, and alcohol groups, different interactions such as van der Waals, ${\pi}-{\pi}$ stacking, dipole-dipole, and hydrogen bonding are formed as the 2D hybrids produced.

Recent Advances in High-performance Functional Ceramics using 3D Nanostructuring Techniques (3차원 나노구조화 기술을 이용한 고성능 기능성 세라믹 연구개발 동향)

  • Ahn, Changui;Park, Junyong;Jeon, Seokwoo
    • Ceramist
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    • v.22 no.3
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    • pp.230-242
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    • 2019
  • Functional ceramics are widely utilized in a variety of application fields such as structural materials, sensors, energy devices, purification filter and etc due to their high strength, stability and chemical activity. With the breakthrough development of nanotechnology, many researchers have studied new types of nanomaterials including nanoparticle, nanorod, nanowire and nanoplate to realize high-performance ceramics. Especially several groups have focused on the 3D nanostructured ceramics because of their large surface area, efficient load transfer, ultra-fast ion diffusion and superior electrical (or thermal) conductivity. In this review, we introduce the reported fabrication strategies of the 3D nanostructured and functional ceramics, also summarized the 3D nanostructured ceramic based high-performance applications containing photocatalysts, structural materials, energy harvesting and storage devices.

Understanding the Structure-Property Relationship in Functional Materials Using 3D Atom Probe Tomography (3차원 원자단층현미경을 활용한 기능성 재료의 구조-특성 관계 해석)

  • Chanwon Jung
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.37 no.5
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    • pp.476-485
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    • 2024
  • Understanding the structure-property relationship in functional materials is crucial as microstructural features such as nano-precipitates, phase boundary, grain boundary segregation, and grain boundary phases play a key role in their functional properties. Atom probe tomography (APT) is an advanced analytical technique that allows for the three-dimensional (3D) mapping of atomic distributions and the precise determination of local chemical compositions in materials. Moreover, it offers sub-nanometer spatial resolution and chemical sensitivity at the tens of parts per million (ppm) level. Owing to its unique capabilities, this technique has been employed to uncover the 3D elemental distributions in a wide range of materials, including alloys, semiconductors, nanomaterials, and even biomaterials. In this paper, various kinds of examples are introduced for elucidating structure-property relationships on functional materials by utilizing the atom probe tomography.

Adhesion Properties between Polyimide Film and Copper by Ion Beam Treatment and Imidazole-Silane Compound (이온빔 및 이미다졸-실란 화합물에 의한 폴리이미드 필름과 구리의 접착 특성)

  • Kang, Hyung Dae;Kim, Hwa Jin;Lee, Jae Heung;Suh, Dong Hack;Hong, Young Taik
    • Journal of Adhesion and Interface
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    • v.8 no.1
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    • pp.15-27
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    • 2007
  • Polyimide (PI) surface modification was carried out by ion-beam treatment and silane-imidazole coupling agent to improve the adhesion between polyimide film and copper. Silane-imidazole coupling agent contains imidazole functional groups for the formation of a complex with copper metal through a coordination bonding and methoxy silane groups for the formation of siloxane polymers. The PI film surface was first treated by argon (Ar)/oxygen ($O_2$) ion-beam, followed by dipping it into a modified silane-imidazole coupling agent solution. The results of X-ray photoelectron spectroscopy (XPS) spectra revealed that the $Ar/O_2$ plasma treatment formed oxygen functional groups such as hydroxyl and carbonyl groups on the polyimide film surface and confirmed that the PI surface was modified by a coupling reaction with imidazole-silane coupling agent. Adhesion between copper and the treated PI film by ion-beam and coupling agent was superior to that with untreated PI film. In addition, adhesion of PI film treated by an $Ar/O_2$ plasma to copper was better than that of PI film treated by a coupling agent. The peeled-off layers from the copper-PI film joint were completely different in chemical composition each other. The layer of PI film side showed similar C1s, N1s, O1s spectra to the original Upilex-S and no Si and Cu atoms appeared. On the other hand the layer of copper side showed different C1s and N1s spectra from the original PI film and many Si and Cu atoms appeared. This indicates that the failure occurs at an interface between the imidazole-silane and PI film layers rather than within the PI layers.

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Mechanical Properties and Fabrication of Nanostructured Mg2SiO4-MgAl2O4 Composites by High-Frequency Induction Heated Combustion (기계적 활성화된 분말로부터 고주파유도 가열 연소합성에 의한 나노구조 Mg2SiO4-MgAl2O4 복합재료 제조 및 기계적 특성)

  • Shon, In-Jin;Kang, Hyun-Su;Hong, Kyung-Tae;Doh, Jung-Mann;Yoon, Jin-Kook
    • Korean Journal of Metals and Materials
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    • v.49 no.8
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    • pp.614-618
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    • 2011
  • Nanopowders of MgO, $Al_2O_3$ and $SiO_2$ were made by high energy ball milling. The rapid sintering of nanostructured $MgAl_2O_4-Mg_2SiO_4$ composites was investigated by a high-frequency induction heating sintering process. The advantage of this process is that it allows very quick densification to near theoretical density and inhibition of grain growth. Nanocrystalline materials have received much attention as advanced engineering materials with improved physical and mechanical properties. As nanomaterials possess high strength, high hardness, excellent ductility and toughness, undoubtedly, more attention has been paid for the application of nanomaterials. Highly dense nanostructured $MgAl_2O_4-Mg_2SiO_4$ composites were produced with simultaneous application of 80MPa pressure and induced output current of total power capacity (15 kW) within 2min. The sintering behavior, gain size and mechanical properties of $MgAl_2O_4-Mg_2SiO_4$ composites were investigated.