• Title/Summary/Keyword: Functional nanofiber

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Fabrication and Characterization of Ag Nanoparticle Dispersed Polymer Nanofiber and Ag Nanofiber Using Electrospinning Method (전기방사법을 이용한 Ag 나노입자 분산 고분자 나노파이버와 Ag 나노파이버 제조 및 특성 평가)

  • Kim, Hee-Taik;Hwang, Chi-Yong;Song, Han-Bok;Lee, Kun-Jae;Joo, Yeon-Jun;Hong, Seong-Jei;Kang, Nam-Kee;Park, Seong-Dae;Kim, Ki-Do;Cho, Yong-Ho
    • Journal of Powder Materials
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    • v.15 no.2
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    • pp.114-118
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    • 2008
  • Functional nanomaterial is expected to have improved capacities on various fields. Especially, metal nanoparticles dispersed in polymer matrix and metal nanofiber, one of the functional nanomaterials, are able to achieve improvement of property in the electric and other related fields. In this study, the fabrication of metal (Ag) nanoparticle dispersed nanofibers were attempted. The Ag nanoparticle dispersed polymer nanofiber and Ag nanofiber were fabricated by electrospinning method using electric force. First, PVP/$AgNO_3$ nanofibers were synthesized by electrospinning in $18{\sim}22kV$ voltage with the starting materials (Ag-nitrate) added polymer (PVP; poly (vinylpyrrolidone)). Then Ag nanoparticle dispersed polymer nanofibers were fabricated to reduce hydrogen reduction at $150^{\circ}C$ for 3hr. And Ag nanofibers were synthesized by the decomposited of PVP at $300{\sim}500^{\circ}C$ for 3hr. The nanofibers were analyzed by XRD, TGA, FE-SEM and TEM. The experimental results showed that the Ag nanofibers could be applied in many fields as an advanced material.

Current R&D Trend of Nanofiber Membranes (나노섬유 분리막의 최근 연구개발동향)

  • Kim, Tae Heon
    • Membrane Journal
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    • v.22 no.6
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    • pp.395-403
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    • 2012
  • R&D of Nanofiber membrane has been carried out in the various fields, gas, water treatment, energy, and etc, with the continuous growth of membrane technology. There are several preparation methods for nanofiber, i.e. drawing, template synthesis, phase separation, self-assembly, and electrospinning. However, an electrospinning has many advantages such as high productivity, low production cost, easy to select law material, high relative surface area, and easy to functionalize. Nanofiber has been used in the field of membrane technologies such as secondary battery and water treatment fields. For the secondary battery separator, the separators having a high power and high thermal stability can be developed with spread of nanofiber on the commercial PP or PE/PP separators. High functional membranes can be also developed by adding the functional additives like antibacterial materials in the nanofiber membrane. It can be expected the high value added with nanofiber membrane because of its diverse applications from the water treatment to the energy field and because of its various functional advantages.

Conductivity stability of carbon nanofiber/unsaturated polyester nanocomposites

  • Wu, Shi-Hong;Natsuki, Toshiaki;Kurashiki, Ken;Ni, Qing-Qing;Iwamoto, Masaharu;Fujii, Yoshimichi
    • Advanced Composite Materials
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    • v.16 no.3
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    • pp.195-206
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    • 2007
  • Carbon nanofiber (CNF)/unsaturated polyester resin (UPR) was prepared by a solvent evaporation method, and the temperature dependency of electrical conductivity was investigated. The CNF/UPR composites had quite a low percolation threshold due to CNF having a larger aspect ratio and being well dispersed in the UPR matrix. The positive temperature coefficient (PTC) was found in the CNF/UPR composites and it showed stronger effect around the percolation threshold. The electrical resistance of the CNF/UPR composites decreased and had lower temperature dependency with increasing numbers of thermal cycles.

Improvement of PCR Preprocessing Efficiency through PEO-controlled Synthesis of Silica Nanofibers (PCR 전처리 효율 향상을 위한 PEO 제어 실리카 나노섬유 제작)

  • Seung-Min Lee;Hyeon-Ho Choi;Kwang-Ho Lee
    • Journal of Biomedical Engineering Research
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    • v.44 no.6
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    • pp.465-475
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    • 2023
  • In this study, we demonstrated a silica nanofibrous membrane based on the electrospinning process and evaluated its DNA isolation and purification performance in PCR pretreatment. Generally, silica membranes made of non-woven fabric are used for PCR pretreatment, but this study aimed to improve the efficiency of the pretreatment process by developing a nanofiber-type silica membrane with high specific surface area and porosity. In order to manufacture a nanofiber-shaped silica film while maintaining the original physical properties of silica, nanofiber membranes produced by adding various concentrations of PEO (5 wt%, 8 wt%, and 10 wt%) to silica prepared by the sol-gel method were compared. In terms of nanofiber membrane production, the higher the PEO concentration, the more effective it was in producing nanofiber membranes. The produced silica nanofiber membrane was inserted to a pretreatment device used in commercial PCR equipment, and the pretreatment performance was compared and verified using Salmonella bacteria. When Salmonella was used, samples containing 5 wt% PEO showed superior PCR efficiency compared to samples containing 8 wt% and 10 wt% PEO. These results show that adding 5 wt% of PEO can effectively improve DNA purification and separation by producing a nanofiber-shaped silica film while maintaining the physical properties of silica. We expect that this study will contribute to the development of effective PCR pretreatment technology essential for various molecular biology applications.

Myocardial tissue engineering using electrospun nanofiber composites

  • Kim, Pyung-Hwan;Cho, Je-Yoel
    • BMB Reports
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    • v.49 no.1
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    • pp.26-36
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    • 2016
  • Emerging trends for cardiac tissue engineering are focused on increasing the biocompatibility and tissue regeneration ability of artificial heart tissue by incorporating various cell sources and bioactive molecules. Although primary cardiomyocytes can be successfully implanted, clinical applications are restricted due to their low survival rates and poor proliferation. To develop successful cardiovascular tissue regeneration systems, new technologies must be introduced to improve myocardial regeneration. Electrospinning is a simple, versatile technique for fabricating nanofibers. Here, we discuss various biodegradable polymers (natural, synthetic, and combinatorial polymers) that can be used for fiber fabrication. We also describe a series of fiber modification methods that can increase cell survival, proliferation, and migration and provide supporting mechanical properties by mimicking micro-environment structures, such as the extracellular matrix (ECM). In addition, the applications and types of nanofiber-based scaffolds for myocardial regeneration are described. Finally, fusion research methods combined with stem cells and scaffolds to improve biocompatibility are discussed. [BMB Reports 2016; 49(1): 26-36]

Development of the Three-Dimensional Perfusion Culture Technology for the Salivary Ductal Cells (타액선 도관세포의 관류 배양 기술 개발)

  • Kim, Ji Won;Kim, Jeong Mi;Choi, Jeong-Seok
    • International journal of thyroidology
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    • v.11 no.2
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    • pp.160-166
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    • 2018
  • Background and objectives: Salivary hypofunction is one of the common side effects after radioiodine therapy, and its pathophysiology is salivary ductal stenosis resulting from ductal cell injury. This study aimed to develop the functional culture environment of human parotid gland ductal cells in in vitro three-dimensional perfusion culture system. Materials and Methods: We compared plastic dish culture method and three-dimensional culture system containing Matrigel and nanofiber. Morphogenesis of reconstituted salivary structures was assessed by histomorphometry. Functional characteristics were assessed by immunohistochemistry and reverse transcription polymerase chain reaction (aquaporin 5, CK7, CK18, connexin 43, and p21). In addition, we designed the media perfusion culture system and identified higher rate of cell proliferation and expression of connexin 43 in perfusion system comparing to dish. Results: Human parotid ductal cells were well proliferated with the ductal cell characters under environment with Matrigel. In the presence of Matrigel, aquaporin 5, CK18 and connexin 43 were more expressed than 2D dish and 3D nanofiber setting. In the media perfusion culture system, ductal cells in 3D culture media showed higher cells count and connexin 43 expression compared to 2D dish. Conclusion: This in vitro ductal cell perfusion culture system using Matrigel could be used to study for radioiodine induced sialadenitis model in vivo.

Nanofiber Membrane based Colorimetric Sensor for Mercury (II) Detection: A Review (나노 섬유 멤브레인을 기반으로 한 수은(II) 색변화 검출 센서에 대한 총설)

  • Bhang, Saeyun;Patel, Rajkumar
    • Membrane Journal
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    • v.31 no.4
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    • pp.241-252
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    • 2021
  • Rapid industrialization with growing population leads to environmental water pollution. Demand in generation of clean water from waste water is ever increasing by scarcity of rain water due to change in weather pattern. Colorimetric detection of heavy metal present in clean water is very simple and effective technique. In this review membrane based colorimetric detection of mercury (II) ions are discussed in details. Membrane such as cellulose, polycaprolactone, chitosan, polysulfone etc., are used as support for metal ion detection. Nanofiber based materials have wide range of applications in energy, environment and biomedical research. Membranes made up of nanofiber consist up plenty of functional groups available in the polymer along with large surface area and high porosity. As a result, it is easy for surface modification and grafting of ligand on the fiber surface enhanced nanoparticles attachment.

The Effect of the Core-shell Structured Meta-aramid/Epoxy Nanofiber Mats on Interfacial Bonding Strength with an Epoxy Adhesive in Cryogenic Environments (극저온 환경에서 에폭시 접착제의 물성 향상을 위한 나노 보강재의 표면 개질에 관한 연구)

  • Oh, Hyun Ju;Kim, Seong Su
    • Composites Research
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    • v.26 no.2
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    • pp.129-134
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    • 2013
  • The strength of adhesive joints employed in composite structures under cryogenic environments, such as LNG tanks, is affected by thermal residual stress generated from the large temperature difference between the bonding process and the operating temperature. Aramid fibers are noted for their low coefficient of thermal expansion (CTE) and have been used to control the CTE of thermosetting resins. However, aramid composites exhibit poor adhesion between the fibers and the resin because the aramid fibers are chemically inert and contain insufficient functional groups. In this work, electrospun meta-aramid nanofiber-reinforced epoxy adhesive was fabricated to improve the interfacial bonding between the adhesive and the fibers under cryogenic temperatures. The CTE of the nanofiber-reinforced adhesives were measured, and the effect on the adhesion strength was investigated at single-lap joints under cryogenic temperatures. The fracture toughness of the adhesive joints was measured using a Double Cantilever Beam (DCB) test.

$CO_2$ Sensing Characteristics of Carbon-nanofibers Based on Effects of Porosity and Amine Functional Group (다공성 및 아민 작용기에 따른 탄소나노섬유의 $CO_2$ 감응특성)

  • Kim, Jong Gu;Kang, Seok Chang;Shin, Eunjeong;Kim, Da Young;Lee, Jin Hee;Lee, Young-Seak
    • Applied Chemistry for Engineering
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    • v.23 no.1
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    • pp.47-52
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    • 2012
  • Porous carbon nanofibers were prepared as a gas sensor electrode to study the $CO_2$ sensing property based on effects of porosity and introduced amine functional groups. Electrospun fibers were obtained by using electrospinning method with polyacrylonitrile precursor and they were treated by the thermal treatment and chemical activation. Amine functional groups were introduced by the liquid state treatment using diethylenetriamine. The specific surface area increased up to $2000m^2/g$ by the chemical activation. The Introduced amine functional group was identified using FT-IR spectroscopy. $CO_2$ gas sensing property was improved as four folds via introduced amine functional groups on the activated carbon nanofiber. In conclusion, the gas sensing property was improved based on the developed porosity by the chemical activation and the chemical attraction of $CO_2$ gas by introduced functional groups.