• Bulletin of the Korean Chemical Society
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• v.34 no.7
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• pp.2041-2043
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• 2013

A layered perovskite of Dion-Jacobson phase, $RbLaTa_2O_7$, was successfully exfoliated into colloidal suspension via successive ion-exchange and intercalation reaction. The pristine perovskite $RbLaTa_2O_7$ was synthesized by conventional solid-state reaction, and then, it was ion-exchanged with hydrochloric acid to obtain a protonic form of perovskite. The resulting proton-exchanged perovskite was reacted with ethylamine to increase interlayer spaces for further intercalation reaction. Finally, the ethylamine-intercalated form was exfoliated into nanosheets via an intercalation of bulky organic cations (tetrabutylammonium). According to X-ray diffraction (XRD) analysis, the TBA-intercalated form showed remarkably increased interlayer spacing (${\Delta}d$ = 1.67 nm) in comparison with that of the pristine material. Transmission electron microscopic image of exfoliated perovskite clearly revealed that the present exfoliated perovskite were composed of very thin layers. This exfoliated perovskite nanosheets could be applicable as building blocks for fabricating functional nanocomposites.

• Korean Institute of Interior Design Journal
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• no.11
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• pp.45-56
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• 1997

In the process of modermization the problem of environment destruction has become a worldwide issue. And now this problem is a concern for all branches of science, including that of architectural desigv. This thesis tries to find the meaning of ecological architectural space, one that encreases the organic relationship, and communication, between architectrual space and urban environmental space, between human beings and architecture, and between human beings and their environment. As an example, we will take a look at the architectural space-design of Frei Otto, who offers diverse creative ecological architectural forms. His concept of architecture has the critical character when compared with the traditionan conventional concept of architecture. The ecological characteristics of his architectural spacedesign can be summarized as follows: The first characteristic is his ample use of natural objects in the architectural structure. An ample use of living things like trees and plants as well as of inanimate thing like water, wind as architectural elements enhances the functional efficiency of architecture. The second characteristic is its ecological architectural system, which saves energy faciliates ventilation by changing the position and direction of the building, by systematically applying the materials, and by efficiently arranging the inner space. The third characteristic is the dematerialization of architecture and the use of materials that are economical and appropriate for the circulation system of nature. The use of natural elements and recycling natural objects, makes it possible to reuse materials of the destroyed building. In short, the ecological architecture of Frei Otto, which shows the relation between human beings and architecture, presents diverse possibilities of the archtectural space as a complex natural system, which is more than a simple combination of separatge elements.

• Proceedings of the Materials Research Society of Korea Conference
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• 2011.05a
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• pp.40.2-40.2
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• 2011

As the old saying 'nothing is complete unless you put it in final shape', although nanosheets (NSs) are a promising functional building block for various electrochemical applications, their true value cannot be realized until they are well woven into electrical conducting materials. As an effort to determine their ideal shape, in this study, a unique manufacturing route to build a layer-by-layer (LBL) structure of two-dimensionally ordered, free-standing ${\beta}$-nickel hydroxide nanosheets (${\beta}$-NHNSs) that are fully electrically addressed with single-wall carbon nanotube fabrics was demonstrated, and its capabilities were verified through a comparative study on the differences between a simple bulky and LBL-structured electrochemical cathode, representing two extreme cases. The LBL-structured cathode showed a discharging current peak that was 25 times larger than the bulky structured one measured in cyclic voltammetry, which implies that the LBL structure is near an ideal electrode configuration for NS-based electrochemical applications.

• Proceedings of the Korean Society of Dyers and Finishers Conference
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• 2011.11a
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• pp.35-35
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• 2011

Phase change material(PCM) has thermal energy storage and been attracted attention. Latent heat of the organic PCM can keep maintaining temperature when the change of outside energy conditions influence to PCM. Thus, many researchers have interested to thermal energy storage ability and investigated to applications such as thermal storage of solar energy, bioclimatic building, icebank, medical application, clothing industry and so on. Among the many applications, investigation of the PCM in clothing industry is also important because the people has interest functional factor called health-care in the clothing. In addition, PCM can give them mild environment condition such suitable temperature control or humidity. To fabrics, the PCM has various methods such as microcapsule, padding and modified cross-section formation(Sheath/core). Sheath core PCM fabric has a better benefit of durability than other method. However, PCM sheath/core spinning is difficult. In addition, dyeing property is important to use clothing industry due to visual images. In this study, we investigated dyeing properties of Nylon/PCM sheath/core fabrics. Especially, we observed the relation between dyeing property and PCM including ratio. Various temperature and pH conditions were also studied to optimize dyeing properties as acid dye.

• Journal of the Korean Wood Science and Technology
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• v.31 no.6
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• pp.83-88
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• 2003

The woodceramics are porous amorphous carbon and glassy carbon composite materials. Woodceramics attracted a lot of attention in recent years because they are environmentally friendly and because of their unique functional characteristics such as catalysis, moisture absorption, deodorization, purification, carrier for microbial activity, specific stiffness, corrosion and friction resistance, and their electromagnetic shielding capacity. In this paper, we made new products of clay-woodceramics to investigate the industrial analysis and ethylene gas adsorption for basic data of building- and packging- materials keeping fruit fresh for a long time. Clay-woodceramics were carbonized for 3 h of heating in a special furnace under a gas flow of nitrogen(15 ml/min.) from 3 layers-clay-woodparticleboard made from pallet waste wood, phenol- formaldehyde resin(hereafter PF, Non volatile content:52%, resin content 30%), and clay(10%, 20% and 30%). Carbonization temperature was 400℃, 600℃ and 800℃. Experimental results shows that the higher the carbonization temperature, the higher the fixed carbon and the lower the volatile contents. The higher the clay content, the more the ash content. The higher the carbonization temperature, the more the ethylene gas adsorption. Carbonization temperature of 800℃ gave the best reslts as same as that of white charcoal and activated carbon.(800℃-clay-woodceramic: 5.36 ppm, white charcoal: 5.66 ppm, activated carbon: 5.79 ppm) The clay contents did not make difference of ethylene gas adsoption.

• Journal of the Korean housing association
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• v.19 no.4
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• pp.41-48
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• 2008

In this study, an analysis is carried out on the acoustic design for an indoor gymnasium scheduled to be built at Buan County, Chonbuk Province. By way of background, the study examines the case of a large-scale indoor gymnasium that has been constructed in the local area of Hangan-myeon. There are many examples whereby this gymnasium could be used not only as a sporting facility for the residents, but also as a multipurpose space for public performances such as leisure activities, lectures, assembling activities, theatre and concerts etc. In order to maximize the functional utilization of such an indoor gymnasium, it is important to simultaneously verify the acoustic capabilities of the space in terms of Definition of both Voice and Music. However, as a large-scaled athletic facility, the building was designed with a high ceiling-height to accommodate its functional characteristics. The space forms a Sound Focus whereby the sound is concentrated at a specific part, and because the vibration of sound is too loud due to its broad volume, acoustic defects arise such as a significant number of Echoes. Using this gymnasium as a precedent, this study proposes an acoustic design based on the drawings of the indoor gymnasium that is scheduled to be built at B County, Chonbuk Province. The gymnasium is equipped with an optimized acoustic condition passing through the Acoustic Simulation Phase. From the results of an Acoustic Simulation, we can design an indoor gymnasium that is equipped with a considerably satisfying and improved acoustic performance compared with the building before it was reformed. It is also considered that the use of such materials can fundamentally reduce construction costs and can improve acoustic performance, at the planning and design stages for similar sporting facilities in the future.

• International conference on construction engineering and project management
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• 2022.06a
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• pp.1249-1249
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• 2022

The facade, an exterior material of a building, is one of the crucial factors that determine its morphological identity and its functional levels, such as energy performance, earthquake and fire resistance. However, regardless of the type of exterior materials, huge property and human casualties are continuing due to frequent exterior materials dropout accidents. The quality of the building envelope depends on the detailed design and is closely related to the back frames that support the exterior material. Detailed design means the creation of a shop drawing, which is the stage of developing the basic design to a level where construction is possible by specifying the exact necessary details. However, due to chronic problems in the construction industry, such as reducing working hours and the lack of design personnel, detailed design is not being appropriately implemented. Considering these characteristics, it is necessary to develop the detailed design process of exterior materials and works based on the domain-expert knowledge of the construction industry using artificial intelligence (AI). Therefore, this study aims to establish a detailed design automation algorithm for AI-based condition-responsive exterior wall panels and their back frames. The scope of the study is limited to "detailed design" performed based on the working drawings during the exterior work process and "stone panels" among exterior materials. First, working-level data on stone works is collected to analyze the existing detailed design process. After that, design parameters are derived by analyzing factors that affect the design of the building's exterior wall and back frames, such as structure, floor height, wind load, lift limit, and transportation elements. The relational expression between the derived parameters is derived, and it is algorithmized to implement a rule-based AI design. These algorithms can be applied to detailed designs based on 3D BIM to automatically calculate quantity and unit price. The next goal is to derive the iterative elements that occur in the process and implement a robotic process automation (RPA)-based system to link the entire "Detailed design-Quality calculation-Order process." This study is significant because it expands the design automation research, which has been rather limited to basic and implemented design, to the detailed design area at the beginning of the construction execution and increases the productivity by using AI. In addition, it can help fundamentally improve the working environment of the construction industry through the development of direct and applicable technologies to practice.

• The Transactions of The Korean Institute of Electrical Engineers
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• v.61 no.6
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• pp.916-921
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• 2012

Sealant paste with silica immersed in cross-linked epoxy-acrylate polymer resin was prepared by thermal and UV curing process. The curing mechanism of polymer resin resulted from 2 functional groups of epoxy and acrylic structure. The properties of microstructure, thermal conductivity and mechanical strength were investigated for its various applications. The adhesion strength is increased by increasing the thermal curing time until 15 minutes, and curing efficiency is saturated over 20 minutes. The increase rate per day of pot life and viscosity is 4.8%, indicating it has excellent storage stability. It is found that the formulation of silica pastes can be applied to heavy industries, building materials, display and various industries.

• Journal of the Korea Concrete Institute
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• v.21 no.2
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• pp.179-186
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• 2009

The peculiarity pointed out for high strength concrete is the occurrence of spalling during a fire. Recently, there are many efforts such as development of all types of spalling reducing materials and other innovative materials in various fields. Need is now to examine the adequate mixing proportions of these materials. This study intended to derive experimentally and statistically mix proportions that can represent the basic quality requirements as well as the optimal effects on the fire-resistance for 4 types of functional materials that are metakaolin, waste tire chip, polypropylene fiber and steel fiber. Here, the tests were planned through an optimal test method using an orthogonal array table with 4 parameters and 3 levels. The statistical analysis adopted the response surface analysis method. Results verified mutual complementary contribution between the materials when using a combination of the functional materials selected as parameters for the strengthening of the fire-resistance of 80 MPa-class high strength concrete. Besides, the optimal conditions of the fire-resistance strengthening materials derived through response surface analysis were a volumetric replacement of silica fume by 80% of metakaolin, a volumetric replacement of fine aggregates by 3% of tire waste chip, and an addition of 0.2% of the whole volume by polypropylene fiber without mixing of steel fiber. In such cases, the basic characteristics as well as the fire-resistant characteristics of high strength concrete were also satisfied.

• Korean Journal of Materials Research
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• v.33 no.6
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• pp.236-241
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• 2023

Solar cells based on p-conjugated donor-acceptor (D-A) organic molecular systems are a promising alternative to conventional electrical energy generation. D-A molecular systems, which have a triphenylamine (TPA) moiety linked with a benzothiadiazole (BTD) moiety, open the potential development of new small molecule donors for bulk heterojunction (BHJ) solar cells. Here, a series of donor-acceptor-π-acceptor (D-A-π-A) small molecule donors (SMD) derived from triphenylamine (TPA) donor and benzothiadiazole (BTD) acceptor building blocks, were designed for BHJ organic solar cells. The small molecule donors SMD1-4 were studied using density functional theory (DFT) and time dependent-DFT (TDDFT) methods, to understand the effect of cyano and fluorine group functionalization on their properties. The effect of structure alteration by cyano and fluorine group functionalization on the optoelectronic properties, the calculated highest occupied molecular orbitals (HOMOs) and lowest unoccupied molecular orbitals (LUMOs) and the HOMO-LUMO gaps were theoretically explored. The V_oc (open-circuit photovoltage) and fill factor (FF) for SMD1-4 were obtained with a PC₇₁BM acceptor, which showed that these organic small molecules are potential small molecule donors for organic bulk heterojunction solar cells.