• Fibers and Polymers
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• v.2 no.2
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• pp.98-107
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• 2001

The phase transition behavior isothermal micro-phase separation kinetics of polyester-based thermoplastic elastomer were studied using the synchrotron X-ray scattering(SAXS) method. The structural changes occurring during heating period were investigated by determining the changes of the one-dimensional correlation function, interfacial thickness and Porod constant. Based on the abrupt increases of the domain spacing and interfacial thickness, a major structural change occurring well below the melting transition temperature is suggested. Those changes are explained in terms of melting of the thermodynamically unstable hard domains or/and the interdiffusion of the hard and soft segments in the interfacial regions. SAXS profile changes during the micro-phase separation process were also clearly observed at various temperatures and the separation rate was found to be sensitively affected by the temperature. The peak position of maximum scattering intensity stayed constant during the entire course of the phase separation process. The scattering data during the isothermal phase separation process was interpreted with the Cahn-Hilliard diffusion equation. The experimental data obtained during the early stage of the phase separation seems to satisfy the Cahn-Hilliard spinodal mechanism. The transition temperature obtained from the extrapolation of the diffusion coefficient to zero value turned out to be about 147$\pm$$2^{\circ}$, which is close to the order-disorder transition temperature obtained from the Porod analysis. The transition temperature was also estimated from the inveriant growth rate. By extrapolating the inveriant growth rate to zero, a transition temperature of about 145$\pm$$\pm$$2^{\circ}$ was obtained.

• Proceedings of the Korean Operations and Management Science Society Conference
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• 2002.05a
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• pp.1044-1051
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• 2002

This paper proposes a two-phase mathematical programming approach by considering classification gap to solve the proposed credit scoring problem so as to complement any theoretical shortcomings. Specifically, by using the linear programming (LP) approach, phase 1 is to make the associated decisions such as issuing grant of credit or denial of credit to applicants. or to seek any additional information before making the final decision. Phase 2 is to find a cut-off value, which minimizes any misclassification penalty (cost) to be incurred due to granting credit to 'bad' loan applicant or denying credit to 'good' loan applicant by using the mixed-integer programming (MIP) approach. This approach is expected to and appropriate classification scores and a cut-off value with respect to deviation and misclassification cost, respectively. Statistical discriminant analysis methods have been commonly considered to deal with classification problems for credit scoring. In recent years, much theoretical research has focused on the application of mathematical programming techniques to the discriminant problems. It has been reported that mathematical programming techniques could outperform statistical discriminant techniques in some applications, while mathematical programming techniques may suffer from some theoretical shortcomings. The performance of the proposed two-phase approach is evaluated in this paper with line data and loan applicants data, by comparing with three other approaches including Fisher's linear discriminant function, logistic regression and some other existing mathematical programming approaches, which are considered as the performance benchmarks. The evaluation results show that the proposed two-phase mathematical programming approach outperforms the aforementioned statistical approaches. In some cases, two-phase mathematical programming approach marginally outperforms both the statistical approaches and the other existing mathematical programming approaches.

• Journal of Multimedia Information System
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• v.1 no.1
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• pp.87-93
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• 2014

The aim of microscopic image restoration is to recover the image by applying the inverse process of degradation, and the results facilitate automated and improved analysis of the image. In this work, we consider the problem of image restoration as a minimization problem of convex cost function, which consists of a least-squares fitting term and regularization terms with non-negative constraints. The finite step method is proposed to solve this constrained convex optimization problem. We demonstrate the convergence of this method. Efficiency and restoration capability of the proposed method were tested and illustrated through numerical experiments.

• Macromolecular Research
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• v.13 no.2
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• pp.141-146
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• 2005

Calix[4]crown-6-2,4-bis(4-aminobutyl ether), which has a crown-6 moiety at the 1,3-position and amino function at the 2,4-position, was prepared as an intermediate for the subsequent synthesis of calix[4]crown-6-containing polyamide and polyimide using adipoyl chloride and 1,2,4,5-benzenetetracarboxylic dianhydride. The chemical structures were characterized by IR, $^{1}H NMR$ spectroscopy and elemental analysis, and some of their physical properties, including their thermal behavior, were examined. The ion binding characteristics of the monomer and polymers for alkali metal and alkali earth metal ions were measured by liquid-liquid extraction from the aqueous phase into the organic phase. It has been observed that polyamide has a high binding ability towards various metal cations as compared to polyimide, which showed cesium ion selectivity.

• Journal of the Korean Ceramic Society
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• v.43 no.3 s.286
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• pp.152-155
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• 2006

Silicon carbide ceramics seeded with 10-30 wt% SiC whiskers are fabricated by hot pressing and annealing. A quantitative texture analysis including calculation of the Orientation Distribution Function (ODF) is used for obtaining the degrees of preferred orientation of the fabricated samples. The microstructure and crystallographic texture are discussed with respect to the effect of ${\beta}-SiC$ whisker seeds on the resulting fracture toughness values. The SEM microstructures and the texture data reveal a correlation between texture and fracture toughness anisotropy.

• Journal of Mechanical Science and Technology
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• v.17 no.12
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• pp.1867-1875
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• 2003

In exhaust pipes of automotive engines, the pulsating pressure waves are composed of fundamental frequency and high order harmonics. The nonlinearities in the exhaust pipe is caused by their interactions. The error between prediction and measurement is induced by the nonlinearities. We can not explain this phenomenon using linear acoustics theory. So power spectrum, which is used in linear theory, is not useful. This paper is concerned with the development of useful engineering techniques to detect and analyze nonlinearity in exhaust pipe of automotive engines. The study of higher order statistics has been dominated by work on the bispectrum. The bispectrum can be viewed as a decomposition of the third moment (skewness) of a signal over frequency and as such is blind to symmetric nonlinearities. The phenomenon of quadratic phase coupling (QPC) can be analyzed by the bicoherence function. Finally the application of these techniques to data from actual exhaust pipe systems is performed.

• Journal of Power System Engineering
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• v.10 no.2
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• pp.16-21
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• 2006

On this study, numerical analysis was performed for the 3 dimensional flow field of gas and particle phase for axial inlet cyclone, a part of dust collector. We applied FVM to visualize the gas phase. The flow was solved using ${\kappa}-{\varepsilon}$ turbulence model. The major parameters considered in this study were helical guide vane, inner diameter, length. Particle trajectory calculations were performed for the particle sizes of $5{\mu}m{\sim}75{\mu}m$. The distribution curve of particle sizes was made of Rosin-Rammler function. The simulation results show various gas flows, particle trajectories on numerical models.

• Journal of the Korean Ceramic Society
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• v.25 no.3
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• pp.277-283
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• 1988

Extremely fine $TiO_2$ powders were synthesized from titanium chloride by the precipitation and freeze drying method. The phase transformation and electrical conductivity were investigated as a function of temperature. X-ray analysis showed that the phase transformation of the synthesized powder from the anatase to rutile occured at 64$0^{\circ}C$ and finished at 92$0^{\circ}C$ due to small particle size and large specific surface area. The activation energy obtained from electrical conductivity vs. temperature was about 1.63eV. This relatively large value was due to porosity in the specimen.

• Journal of the Korean Ceramic Society
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• v.44 no.4 s.299
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• pp.224-229
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• 2007

To evaluate the cooling rate of clinker quantitatively, several clinkers with different cooling rate were made in the laboratory. The X-ray diffraction pattern of Ferrite 002 reflection were measured and the parameters were calculated by using split type pseudo-Voigt function. The X-ray diffraction patterns of the Ferrite phase in the clinkers from cement manufacturing plant were analyzed by using the parameters and the analysis program was developed to calculate the cooling rate quantitatively. The cooling rate coefficients of the clinkers were calculated by using the profile fitting method of the program and the influence of cooling rate on strength was evaluated. The results show that there is a close relation between the cooling rate of clinker and the strength of cement.

• Journal of Power Electronics
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• v.17 no.5
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• pp.1278-1287
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• 2017

Inverters are widely used in distributed power generation and other applications. However, their lack of inertia and variable impedance may cause system instability and power transfer inaccuracy. This paper proposes a control scheme for a single phase voltage-controlled inverter with some grid-friendly characteristics. The proposed control algorithm enables the inverter to function as a voltage source with an inner output impedance in both the islanded and grid-connected modes. Virtual inertia and rotor equations are embedded in the PLL part. Thus, the frequency stability can remain. The inner output impedance can be adjusted freely, which helps to accurately decouple and transmit the output active and reactive power. The proposed inverter operates like a traditional synchronous generator. Simulations and experiments are designed and carried out to verify the proposed control strategy.