• 한국산업보건학회지
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• 제22권3호
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• pp.184-190
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• 2012

Objectives: This study aimed to characterize the nanoparticles produced by welding and grinding processes. Methods: The number concentrations of particles were mapped to determine the distribution of welding fumes in a workplace atmosphere using a hand-held condensation particle counter. An electrical low-pressure impactor was used for measuring the number concentration and particle size distribution. Results: High number concentrations were found around arc cutting and welding (grinding) processes. In the worker's breathing zone, the mean number concentration was 655,000 particles/cm3 and the count median diameter (CMD) was 84 nm with several multi peak distributions (~20, 70, 300 nm). However, at a distance of 3 m from the welding position, the number concentration decreased to 153,000 particles/cm3 with a 70 nm single peak size distribution. During a grinding process, peaks with high concentrations of nanoparticles were temporarily observed. The mean number concentration was 1,520,000 particles/cm3, and the CMD was 30 nm. Nanoparticles (<100 nm) made up 58% and 92% of the aerosols produced by welding and grinding processes, respectively.

• Safety and Health at Work
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• 제7권2호
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• pp.150-155
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• 2016

Background: Shipbuilding involves intensive welding activities, and welders are exposed to a variety of metal fumes, including manganese, that may be associated with neurological impairments. This study aimed to characterize total and size-fractionated manganese exposure resulting from welding operations in shipbuilding work areas. Methods: In this study, we characterized manganese-containing particulates with an emphasis on total mass (n = 86, closed-face 37-mm cassette samplers) and particle size-selective mass concentrations (n = 86, 8-stage cascade impactor samplers), particle size distributions, and a comparison of exposure levels determined using personal cassette and impactor samplers. Results: Our results suggest that 67.4% of all samples were above the current American Conference of Governmental Industrial Hygienists manganese threshold limit value of $100{\mu}g/m^3$ as inhalable mass. Furthermore, most of the particles containing manganese in the welding process were of the size of respirable particulates, and 90.7% of all samples exceeded the American Conference of Governmental Industrial Hygienists threshold limit value of $20{\mu}g/m^3$ for respirable manganese. Conclusion: The concentrations measured with the two sampler types (cassette: total mass; impactor: inhalable mass) were significantly correlated (r = 0.964, p < 0.001), but the total concentration obtained using cassette samplers was lower than the inhalable concentration of impactor samplers.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2008년도 춘계 학술발표회 제20권1호
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• pp.441-444
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• 2008

본 연구에서의 초고성능 콘크리트(Ultra High Performance Concrete, UHPC)는 모래, 시멘트, 실리카퓸, 석영미분말, 강섬유 및 고성능감수제 등으로 구성되며, 평균입경 약 0.5mm이하의 아주 작은 입자들로 구성된다. 일반적으로 석영미분말는 일정크기 이상의 공극을 메움으로써 물리적 성능개선의 효과가 있으며 또한 높은 $SiO_2$함량을 가지므로 고온 또는 고압의 양생조건에서 시멘트 수화물과의 화학반응을 통해서도 성능 향상효과가 있는 것으로 알려져 있다. 본 연구에서는 상압, $90^{\circ}C$ 증기양생 조건에서 석영미분말의 입자크기가 초고성능 콘크리트의 역학적 특성에 어떠한 영향을 미치는지에 대해 알아보고자 하였으며, 평가항목으로는 굳지 않은 상태에서의 유동성과 굳은 상태에서의 압축강도, 극한변형률, 탄성계수 및 휨강도를 평가하였다. 석영미분말의 입경크기의 영향은 약 $2{\mu}m$에서 $26{\mu}m$까지의 범위에서 고려하였으며, 입경 크기가 작을수록 유동성 및 강도특성이 모두 향상되는 것으로 나타났다.

• 한국안전학회지
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• 제16권1호
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• pp.65-72
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• 2001

Portland cement concrete is made with coarse aggregate, fine aggregate, portland cement, water and, in some cases, selected chemical admixture such as air-entraining agents, water reducer, superplasticizer, and so on, and mineral admixture such as fly ash, silica fume, slags, etc. Typically, in the concrete, the coarse aggregate and fine aggregate will occupy approximately 80 percent of the total volume of the finished mixture. Therefore, the coarse and fine aggregates affect to the properties of the portland cement concrete. As the deposits of natural sands have slowly been depleted, it has become necessary and economical to produce crushed sand(manufactured fine aggregate). It is reported that crushed sand differs from natural sands in gradation, particle shape and texture, and that the content of micro fines in the crushed sand affect to the quality of the portland cement concrete. Therefore, the purpose of this paper is to investigate the characteristics of fresh and hardened concrete with higher micro fines. This study provides a firm data to apply crushed sand with higher micro fines.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2001년도 가을 학술발표회 논문집
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• pp.73-78
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• 2001

Portland cement concrete is made with coarse aggregate, fine aggregate, portland cement, water and, in some cases, selected chemical admixtures such as air-entraining agents, water reducer, superplasticizer, and so on, and mineral admixtures such as fly ash, silica fume, slags, etc. Typically, in the concrete, the coarse aggregate and fine aggregate will occupy approximately 80 percent of the total volume of the final mix. Therefore, the coarse and fine aggregates affect to the properties of the portland cement concrete. As the natural sands are drained, it is necessary and economical to utilize crushed sands(manufactured fine aggregate). It is reported that crushed sands differ from natural sands in gradation, particle shape and texture, and the micro fines in the crushed sands affect to the quality of the portland cement concrete. Therefore, the purpose of this paper is to investigate the characteristics of fresh and hardened concrete with high content of micro fines. This study provides firm data for the use of crushed sands with higher micro fines.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2008년도 춘계 학술발표회 제20권1호
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• pp.1041-1044
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• 2008

The addition of chemical inert filler in blended cement, such as limestone or chemical inert silica fume, will produce a physical effect on cement hydration. Due to the high surface area of inert filler in the mixtures, it provides sites for the nucleation and growth of hydration products, thus improving the hydration rate of cement compounds and consequently increasing the strength at early age. This paper proposes a model of hydration of Portland cement blended with chemical inert filler. This model considers the influence of water to cement ratio, cement particle size, cement composition and addition of chemical inert filler on hydration. The heat evolution, degree of hydration and porosity are obtained as accompanied results in hydration process. The prediction results agree well with experiment results.

• 한국구조물진단유지관리공학회 논문집
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• 제27권6호
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• pp.111-119
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• 2023

최근 다양한 시멘트 기반 재료들이 새롭게 개발되고 있으며, 이에 새롭게 개발된 재료들의 물성을 예측하려는 시도도 증가하고 있다. 본 연구에서는 시멘트계 재료로 구성된 2성분계 페이스트의 유변특성을 정량적으로 예측하고자 하였다. 사용된 시멘트계 재료는 포틀랜드 시멘트(PC), 플라이애시(FA), 고로슬래그(BS), 실리카퓸(SF)이 사용되었으며, 시멘트를 기반으로 나머지 3가지의 결합재를 혼합하였다. 페이스트의 항복응력과 소성점도는 각각 YODEL(Yield stress mODEL)과 Krieger-Dougherty's equation을 사용하여 예측하였으며, Rheometer를 사용한 실험 결과를 통해 예측 모델의 성능을 확인하였다. 개별 재료의 예측에 사용된 물성과 매개변수를 재구성하여 2성분계 페이스트의 유변특성을 예측하였을 때, 제안된 방법에 따른 예측의 경향이 실험 결과와 잘 일치하는 것으로 나타났다.

• 한국산업보건학회지
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• 제25권4호
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• pp.472-481
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• 2015

Objectives: Welding is a major task in shipbuilding yards that generates welding fumes. A significant amount of welding in shipbuilding yards is done on steel. Inevitably, manganese is present in the base metals being joined and the filler wire being used and, consequently, in the fumes to which workers are exposed. The objective of this work was to characterize manganese exposure associated with work area, total and particle size-selective mass concentration, and compare the mass concentrations obtained using a three-piece cassette sampler, size-selective impactor sampler and blood manganese concentrations. Materials: All samples were collected from the main work areas at one shipbuilding yard. We used a three piece cassette sampler and the eight stage cascade impactor sampler for the airborne manganese mass concentration of total and all size fractions, respectively. In addition, we used the results of health examination of workers sampled for airborne manganese. Results: The oder of high concentration of airborne manganese in shipbuilding processes was as follows; block assembly, block erection, outfitting installation, steel cutting, and outfitting preparation. The percentages of samples that exceeded the OES of the ministry of employment and labor by the cassette sampling method was 12.5%, however 59.1% of sampled workers by the impactor sampling method exceeded the TLV of the ACGIH. Conclusions: Even though the manganese concentrations in blood of workers exposed to higher airborne manganese concentration were higher than among those exposed to lower concentrations, there was no difference in blood manganese concentrations among work duration. The data analyzed here by characterizing size-selective mass concentrations indicates that the inhaled manganese of welders in shipbuilding yards could be mostly manganese-containing respirable particle sizes.

• Advances in concrete construction
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• 제16권3호
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• pp.169-176
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• 2023

The aim of the study was to establish the influence of particle size, chemical and phase composition of fine microspherical high-calcium fly ash (HCFA), as well as superplasticizer content on the strength of cementless composite materials based on 100% HCFA and mixtures of HCFA with Portland cement (PC). For the initial HCFA fractions, the particle size distribution, chemical and quantitative phase composition were determined. The compressive strength of cured composite materials obtained at W/B 0.4 and 0.25 was determined at a curing time of 3-300 days. For cementless materials, it was found that a change in the particle size d90 from 30 ㎛ (fraction 3) to 10 ㎛ (fraction 4) leads to an increase in compressive strength by more than 2 times. Compressive strength increases by at least another 2.2 times with the addition of Melflux 5581F superplasticizer (0.12%) and at W/B 0.25. The HCFA-PC blends were investigated in the range of 60-90% HCFA and the maximum compressive strength was found at 80% HCFA. On the basis of 80% HCFA-20% PC blend, the samples of ultra-high strength (108 and 150 MPa at 28 and 100 days of hardening) were obtained with the addition of 0.3% Melflux 5581F and 5% silica fume. The quantitative phase composition was determined for composite materials with a curing age of 28 days. It has been established that in a sample with ultra-high strength, a more complete transformation of the initial phases of both HCFA and PC occurs as compared to their transformation separately.

• 대한전자공학회:학술대회논문집
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• 대한전자공학회 2001년도 The 6th International Symposium of East Asian Resources Recycling Technology
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• pp.9-18
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• 2001

1. EAF Dust in Japan - Generation and Characteristics. The quantity of dust generated from EAF shops in Japan was estimated to be 520,000 tons/year in 1999. Extremely fine dust (or fume) is formed in the EAF by metal vaporization. Its characteristics such as chemical compositions, phases, particle size, leaching of heavy metal are mentioned. 2. EAF Dust Treatment Methods in Japan. In 1999, 61% of EAF dust was treated by regional zinc recovery processing routes, 25% went to landfill disposal, 4% was reused as cement material, and 10% was treated by on-site processing routes. The problems of EAF dust treatment methods in Japan are: (1) very high treatment cost, and (2) heavy environmental load (leaching of heavy metal, emission of dioxins, depletion of disposal sites, etc). It has been much hoped for that new dust management technology would be developed. 3. New technology of EAF dust treatment in Japan. In Japan, some new technologies of EAF dust treatment have been developed, and some others are in the developing stages. Following five processes are mentioned:. (1) Smelting reduction process by Kawasaki Steel, (2) DSM process by Daido Steel, (3) VHR process by Aichi Steel, (4) On-site dust direct recycling technology, and (5) Process technology of direct separation and recovery of iron and zinc metals contained in high temperature EAF off gas by the Japan Research and Development Center fur Metals.