• Proceedings of the Korean Nuclear Society Conference
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• 1998.05a
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• pp.719-724
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• 1998

A preliminary fuel channel analysis for 35% reactor inlet header (RIH) break in CANDU reactor loaded with the CANFLEX-RU fuel bundles has been performed. The predicted results are compared with those for the reactor compared with those for the reactor loaded with standard 37-element bundles. The maximum fuel centerline and sheath temperatures for the CANFLEX-RU bundle channel were lower by 338 and 122 $^{\circ}C$, respectively, than those for the standard bundle because of the Bower maximum linear power of the CANFLEX-RU bundle In spite of the 0.4 FPS higher power pulse of the CANFLEX-RU bundle case. Fuel integrity margin to fuel breakup for the CANFLEX-RU bundle is about 50 J/g higher than that for the standard bundle. The PT/CT contact for the CANFLEX-RU bundle occurred 2 s later than that for the standard bundle. The PT/CT contact temperature for the CANFLEX-RU bundle was 2 $^{\circ}C$ lower than that for the standard bundle. These provide the CANFLEX-RU bundle with the negligibly enhanced safety margin for the fuel channel integrity in CANDU 6 reactor, compared with the standard bundle.

• Nuclear Engineering and Technology
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• v.48 no.1
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• pp.1-15
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• 2016

For a long time, a top priority in the nuclear industry was the safe, reliable, and economic operation of light water reactors. However, the development of accident-tolerant fuel (ATF) became a hot topic in the nuclear research field after the March 2011 events at Fukushima, Japan. In Korea, innovative concepts of ATF have been developing to increase fuel safety and reliability during normal operations, operational transients, and also accident events. The microcell $UO_2$ and high-density composite pellet concepts are being developed as ATF pellets. A microcell $UO_2$ pellet is envisaged to have the enhanced retention capabilities of highly radioactive and corrosive fission products. High-density pellets are expected to be used in combination with the particular ATF cladding concepts. Two concepts-surface-modified Zr-based alloy and SiC composite material-are being developed as ATF cladding, as these innovative concepts can effectively suppress hydrogen explosions and the release of radionuclides into the environment.

• Nuclear Engineering and Technology
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• v.40 no.2
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• pp.139-146
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• 2008

This paper presents two of the fuel channel designs being considered for the CANDU-SCWR, a pressure-tube type supercritical water cooled reactor. The first is an insulated pressure tube design. The pressure tube is thermally insulated from the hot coolant by a porous ceramic insulator. Each pressure tube is in direct contact with the moderator, which operates at an average temperature of about $80^{\circ}C$. The low temperature allows zirconium alloys to be used. A perforated metal liner protects the insulator from being damaged by the fuel bundles and erosion by the coolant. The coolant pressure is transmitted through the perforated metal liner and insulator and applied directly to the pressure tube. The second is a re-entrant design. The fuel channel consists of two concentric tubes, and a calandria tube that separates them from the moderator. The coolant enters between the annulus of the two concentric fuel channel tubes, then exits the fuel channel through the inner tube, where the fuel bundles reside. The outer tube bears the coolant pressure and its temperature will be the same as the coolant inlet temperature, ${\sim}350^{\circ}C$. Advantages and disadvantages of these designs and the material requirements are discussed.

• 한국신재생에너지학회:학술대회논문집
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• 2011.05a
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• pp.159.1-159.1
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• 2011

Partial oxidation reformer was fabricated and operated using commercial transportation fuels. Fuel injector and heating coil were used for fuel atomization and startup, respectively. The reformer was designed to produce syngas for $150{\sim}200W_e$ class solid oxide fuel cell. The reformer was operated in the $O_2$/C range between 0.6 and 0.8 while the capacity was fixed at $150W_e$. The temperature range in catalyst bed was between $500^{\circ}C$ and $900^{\circ}C$. Only 83% fuel was converted to $H_2$, CO, $CO_2$ and $CH_4$ at the operating conditions. The lowest temperature increase to $700^{\circ}C$ when the reformer was operated at $200W_e$, Although the temperature profiles was improved, fuel conversion was 88%. On the other hand, fuel was completely converted when micro-reactor operated at the same condition. This difference maybe due to aromatic compounds formation at homogeneous region. In addition, a significant amount of coke deposition was observed at vent line. Homogeneous reaction depends on the degree of mixing. For this purpose, two fluid nozzle and Ultra sonic injector were compared to investigate the effect of atomization. Sauter mean diameter(SMD) of Ultra sonic injector was lower than two-fluid nozzle at test condition. However, conversion efficiency and fuel conversion were not improved by using two-fluid nozzle. these results imply that the temperature of homogeneous reaction region should be controlled to prevent coke formation.

• Bulletin of the Korean Chemical Society
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• v.35 no.1
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• pp.231-235
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• 2014

Rh doped Ni and Co catalysts, Rh-M/$CeO_2$(20 wt %)-$Al_2O_3$ (0.2 wt % of Rh; M = Ni or Co, 20 wt %) were synthesized to produce hydrogen via autothermal reforming (ATR) of commercial gasoline at $700^{\circ}C$ under the conditions of a S/C ratio of 2.0, an O/C ratio of 0.84, and a gas hourly space velocity (GHSV) of $20,000h^{-1}$. The Rh-Ni/$CeO_2$(20 wt %)-$Al_2O_3$ catalyst (1) exhibited excellent activities, with $H_2$ and ($H_2$+CO) yields of 2.04 and 2.58 mol/mol C, respectively. In addition, this catalyst proved to be highly stable over 100 h without catalyst deactivation, as evidenced by energy dispersive spectroscopy (EDX) and elemental analyses. Compared to 1, Rh-Co/$CeO_2$(20 wt %)-$Al_2O_3$ catalyst (2) exhibited relatively low stability, and its activity decreased after 57 h. In line with this observation, elemental analyses confirmed that nearly no carbon species were formed at 1 while carbon deposits (10 wt %) were found at 2 following the reaction, which suggests that carbon coking is the main process for catalyst deactivation.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2010.11a
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• pp.795-796
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• 2010

Interest has been increasing worldwide in Fischer-Tropsch synthesis (F-T) as a method of producing synthetic liquid fuels from biomass. Hydroisomerization of $C_7-C_{15}$ paraffins applies to production of diesel fuel with high cetane number and improved cold flow properties, such as viscosity, pour point and freezing point. The commercial products such as fuel jet produced from F-T synthesis should have low freezing and pour points. In this study, our major aim is to develop a catalyst for hydroisomerization of synthesis-oil for bio-jet fuel. Effects of zeolites and platinum loading on hydroisomerization of dodecane were investigated as a model reaction in a batch reactor.

• Nuclear Engineering and Technology
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• v.50 no.2
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• pp.218-222
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• 2018

An oxide-dispersion-strengthened (ODS) layer was formed on Zircaloy-4 tubes by a laser beam scanning process to increase mechanical strength. Laser beam was used to scan the yttrium oxide ($Y_2O_3$)-coated Zircaloy-4 tube to induce the penetration of $Y_2O_3$ particles into Zircaloy-4. Laser surface treatment resulted in the formation of an ODS layer as well as microstructural phase transformation at the surface of the tube. The mechanical strength of Zircaloy-4 increased with the formation of the ODS layer. The ring-tensile strength of Zircaloy-4 increased from 790 to 870 MPa at room temperature, from 500 to 575 MPa at $380^{\circ}C$, and from 385 to 470 MPa at $500^{\circ}C$. Strengthening became more effective as the test temperature increased. It was noted that brittle fracture occurred at room temperature, which was not observed at elevated temperatures. Resistance to dynamic high-temperature bursting improved. The burst temperature increased from 760 to $830^{\circ}C$ at a heating rate of $5^{\circ}C/s$ and internal pressure of 8.3 MPa. The burst opening was also smaller than those in fresh Zircaloy-4 tubes. This method is expected to enhance the safety of Zr fuel cladding tubes owing to the improvement of their mechanical properties.

• Journal of the Korea Organic Resources Recycling Association
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• v.31 no.2
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• pp.53-61
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• 2023

Most of the sewage sludge is organic waste containing a large amount of organic substances decomposable by microorganisms by biological treatment. As for existing sewage sludge treatment methods, reduction and fuel conversion are being carried out using technologies such as drying, incineration, torrefaction, carbonization. However, the disadvantage of high energy consumption has been pointed out as latent heat of 539 kcal/kg is consumed based on drying. Therefore, in this study, we intend to produce solid fuel through hydrothermal carbonization(HTC), which is a thermochemical treatment. To evaluate the value of solid fuel, the characteristics of carbonization and fuel ratio were analyzed. As a result, as the hydrothermal carbonization reaction temperature increased, the lower heating value also increased by about 500 kcal/kg due to the increase in the degree of carbonization. H/C, O/C, ratio showed a decreasing trend from 1.78, 0.46 to 1.57, 0.32. When the ratio of ash to combustible content (fixed carbon + volatile) of dry sludge was 0.25 or more, it was derived that the degree of carbonization and calorific value did not increase even when hydrothermal carbonization was performed.

• New & Renewable Energy
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• v.17 no.2
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• pp.50-58
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• 2021

We proposed an MEA development methodology that accurately measures intrinsic MEA performance while considering the uneven reaction environments formed inside a large-area BP. To facilitate measurement of the inherent MEA performance, we miniaturized the active area of the MEA to 3 cm², and prepared two MEAs with different ionomer contents of 0.65 and 0.80 (I/C). By simulating the operating conditions of a 100 cm² BP at the inlet (I), center (C), and outlet (O), the oxygen concentration and relative humidity were determined to be 20.7, 13.8, 11.7%, and 50, 66.1, and 70.1% respectively. We measured the performance and electrochemical analysis of the prepared MEAs under the three simulated conditions. Based on the results of statistical analysis of the evaluated MEA performance data, I/C 0.65 MEA had a higher average performance and lower performance deviation than I/C 0.80 MEA. Hence, it can be concluded that an I/C 0.65 MEA is a more effective MEA for large-area BP. Based on the above research process, we confirmed the effectiveness of the proposed MEA development methodology.

• Korean Journal of Metals and Materials
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• v.47 no.7
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• pp.454-459
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• 2009

In order to commercialize Polymer Electrolyte Fuel Cell (PEFC), the cathode catalyst such as Platinum supported Carbon (Pt/C) need to have a high activity of Oxygen Reduction Reaction (ORR). In this study, the 20% Pt/C was synthesized using the chemical reduction method while the crystallinity of Platinum (Pt) particles were controlled under heat treatment conditions. The activity of synthesized Pt catalysts was evaluated using electrochemical measurement. Compared with the $i_{ORR}$ at 0.8 V of 20% Pt/C heat-treated at $500^{\circ}C$ and the 20% Pt/C that were not heated and commercial 20% Pt/C, the $i_{ORR}$ at 0.8 V of 20% Pt/C heattreated at $500^{\circ}C$ was 9.5 and 1.7 times higher than those of the 20% Pt/C and commercial 20% Pt/C that were not heated. It was considered that the crystallinity and particle size affect the ORR activity of the Pt/C catalysts.