• Title/Summary/Keyword: Fuel reforming

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Numerical Analysis of the Gas Flow Distribution Characteristics in the Anode Flow Channel of Molten Carbonate Fuel Cell (MCFC) (용융탄산염 연료전지 Anode 유로 채널에서의 가스 유동 분포에 관한 수치해석적 연구)

  • Cho, Jun-Hyun;Ha, Tae-Hun;Kim, Han-Sang;Min, Kyoung-Doug;Park, Jong-Hoon;Chang, In-Gab;Lee, Tae-Won
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.33 no.11
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    • pp.834-839
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    • 2009
  • A three-dimensional computational fluid dynamics (CFD) analysis is performed to investigate flow characteristics in the anode channels and manifold of the internal reforming type molten carbonate fuel cell (MCFC). Considering the computational difficulties associated with the size and geometric complexity of the MCFC system, the polyhedral meshes that can reduce mesh connectivity problems at the intersection of the channel and the manifold are adopted and chemical reactions inside the MCFC system are not included. Through this study, the gas flow rate uniformity of the anode channels is mainly analyzed to provide basic insights into improved design parameters for anode flow channel design. Results indicate that the uniformity in flow-rate is in the range of ${\pm}$1% between the anode channels. Also, the mal-distributed inlet flow-rate conditions and the change in the size of the manifold depth have no significant effect on the flow-rate uniformity of the anode channels.

Viscosity Characteristics of Waste Cooking Oil with Ultrasonic Energy Irradiation

  • Kim, Tae Han;Han, Jung Keun
    • Journal of Biosystems Engineering
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    • v.37 no.6
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    • pp.429-433
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    • 2012
  • Purpose: While rapeseed oil, soy bean oil, palm oil and waste cooking oil are being used for biodiesel, the viscosity of them should be lowered for fuel. The most widely used method of decreasing the viscosity of vegetable oil is to convert the vegetable oil into fatty acid methyl ester but is too expensive. This experiment uses ultrasonic energy, instead of converting the vegetable oil into fatty acid methyl ester, to lower the viscosity of the waste cooking oil. Methods: For irradiation treatment, the sample in a beaker was irradiated with ultrasonic energy and the viscosity and temperature were measured with a viscometer. For heating treatment, the sample in a beaker was heated and the viscosity and temperature were measured with a viscometer. Kinematic viscosity was calculated by dividing absolute viscosity with density. Results: The kinematic viscosity of waste cooking oil and cooking oil are up to ten times as high as that of light oil at room temperature. However, the difference of two types of oil decreased by four times as the temperature increased over $83^{\circ}C$. When the viscosity by the treatment of ultrasonic energy irradiation was compared to one by the heating treatment to the waste cooking oil, the viscosity by the treatment of ultrasonic energy irradiation was lower by maximum of 22% and minimum of 12%, than one by the heating treatment. Conclusions: Ultrasonic energy irradiation lowered the viscosity more than the heating treatment did, and ultrasonic energy irradiation has an enormous effect on fuel reforming.

Modeling for the Performance Analysis of a Tubular SOFC/MGT Hybrid Power System (원통형 고체산화물 연료전지와 마이크로 가스터빈 하이브리드 시스템의 성능해석을 위한 모델링)

  • Song, T.W.;Sohn, J.L.;Kim, J.H.;Kim, T.S.;Ro, S.T.;Suzuki, K.
    • Proceedings of the KSME Conference
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    • 2004.04a
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    • pp.2070-2075
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    • 2004
  • Performance of a solid oxide fuel cell (SOFC) can be enhanced by converting thermal energy of its high temperature exhaust gas to mechanical power using a micro gas turbine (MGT). A MGT plays also an important role to pressurize and warm up inlet gas streams of the SOFC. In this study, the influence of performance characteristics of the tubular SOFC on the hybrid power system is discussed. For this purpose, detailed heat and mass transfer with reforming and electrochemical reactions in the SOFC are mathematically modeled, and their results are reflected to the performance analysis. The analysis target is 220kWe SOFC/MGT hybrid system based on the tubular SOFC developed by Siemens-Westinghouse. Special attention is paid to the ohmic losses in the tubular SOFC counting not only current flow in radial direction, but also current flow in circumferential direction through the anode and cathode.

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Numerical analysis of the gas flow distribution characteristics in the anode flow channel of the molten carbonate fuel cell (MCFC) (용융탄산염 연료전지 anode 유로 채널에서의 가스 유동 분포에 관한 수치해석적 연구)

  • Cho, Jun-Hyun;Ha, Tae-Hun;Kim, Han-Sang;Min, Kyoung-Doug;Park, Jong-Hoon;Chang, In-Gab;Lee, Tae-Won
    • Proceedings of the KSME Conference
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    • 2008.11b
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    • pp.3120-3124
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    • 2008
  • A three-dimensional computational fluid dynamics (CFD) analysis is performed to investigate flow characteristics in the anode channels and manifold of the internal reforming type molten carbonate fuel cell (MCFC). Considering the computational difficulties associated with the size and geometric complexity of the MCFC system, the polyhedral meshes that can reduce mesh connectivity problems at the intersection of the channel and the manifold are adopted and chemical reactions inside the MCFC system are not included. Through this study, the gas flow rate uniformity of the anode channels is mainly analyzed to provide basic insights into improved design parameters for anode flow channel design. Results indicate that the uniformity in flow-rate is in the range of ${\pm}1%$ between the anode channels. Also, the mal-distributed inlet flow-rate conditions and the change in the size of the manifold depth have no significant effect on the flow-rate uniformity of the anode channels.

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Exhaust and Combustion Characteristics of Premixed Swirl Burner for Steam Reforming System (선회류 예혼합버너를 적용한 개질기용 연소시스템의 배기 및 연소특성)

  • Cha, Chun Loon;Hwang, Sang Soon
    • Journal of the Korean Society of Combustion
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    • v.19 no.3
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    • pp.34-43
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    • 2014
  • The reformer system is a method for hydrogen production from hydrocarbon fuels such as natural gas under high temperature environment($about{\sim}1,000^{\circ}C$). The premixed swirl burner with mixing swirler and combustion swirler designed to deliver fuel cell electric output from 0.5 kW to 1.5 kW. Premixed swirl burner experiments using natural gas and mixture of natural gas and anode off gas were carried out to analyse flame patterns and stability by equivalence ratio respectively. The results show that the stable swirl flame can be established for all cases of fuels type using the premixed swirl burner. The swirl flame had a wide stability region and it showed very low CO(50 ppm) and $NO_x$(20 ppm) emission at different fuel type and various equivalence ratio conditions. The operating range of premixed swirl burner for stable swirl flame is found to exist between equivalence ratio of 0.70 to 0.90 for turn down ratio of 3:1.

System Development of a 100 kW Molten Carbonate Fuel Cell IV(System commisioning for operation (100 kW급 용융탄산염 연료전지 시스템 개발 IV(MCFC 시스템 시운전))

  • Lim, Hee-Chun;Ahn, Kyo-Sang
    • Proceedings of the KIEE Conference
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    • 2005.07b
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    • pp.1681-1683
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    • 2005
  • The molten carbonate fuel tell(MCFC) is endowed with the high potential especially in future electric power generation industry by its own outstanding characteristics. KEPCO(KEPRI) started a 100 kW MCFC system development program in 1993 and has been executed 100kW system develpilot plant successfully completed first phaseopment by 2005 on the basis of successful results of 25kW system development. In this program, the components and mechanical structure for 100 kW stack and system construction were completed on last year and now system pre-commissioning was being executed. A 100 kW MCFC power plant was constructed at the site of Boryeong Thermal Power Plant. A 100 kW MCFC system has characterized as a high pressure operation mode, $CO_2$ recycle, and externally reforming power generation system. The 100 kW MCFC system consisted with stacks which was made by two 50 kW sub-stacks, 90 cells with 6,000 cm2 active area and BOP including a reformer, a recycle blower, a catalytic burner, an inverter, and etc. The system will be operated under 3 atm pressure condition and expected to last over 5,000 hours by the end of this year.

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A simulation study on synthesis gas process optimization for GTL (Gas-to-Liquid) pilot plant (GTL 합성유 제조용 파일럿 플랜트 최적 운전 변수 도출을 위한 합성가스 공정 시뮬레이션 연구)

  • Kim, Yong Heon;Bae, Ji Han;Park, Myoung Ho
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.05a
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    • pp.74.2-74.2
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    • 2011
  • A simulation study on synthesis gas process in GTL process was carried out in order to find optimum operation conditions for GTL (gas-to-liquid) pilot plant design. Optimum operating conditions for synthesis gas process were determined by changing reaction variables such as feed temperature and pressure. During the simulation, overall synthesis process was assumed to proceed under steady-state conditions. It was also assumed that physical properties of reaction medium were governed by RKS (Redlich-Kwong-Soave) equation. The effect of temperature and pressure on synthesis gas process $H_2$/CO ratio were mainly examined. Simulation results were also compared to experimental results to confirm the reliability of simulation model. Simulation results were reasonably well matched with experimental results.

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The corrosion-resistant of Al-coated xstainless in molten carbonate (알루미늄 코팅처리 스테인레스강의 융탄산염 내부식성)

  • 조남웅;장세기;전재호;신정철
    • Journal of the Korean institute of surface engineering
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    • v.31 no.1
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    • pp.3-11
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    • 1998
  • Molten Carbonate Fuel cell is a promising new type electric power generation system which can achieve high efficiency, lower matrrial cost and high operating temperature Making internal reforming possible. Although the development of the MCEC is progressing rapidly toward commercialization, two important tchological problems such as dissolution of NiO cathode and not corrosion of metallic separator plate must be resolved. Because MCFC is operated at $650^{\circ}C$ and the electrolyte is very corrosive, corrosion-resistance of separator plated against oxidation abd molten carbonate is required. Al-coating on separator material for corrosion-resistance was carried out by painting, thermal spraying. hot dipping and vacuum vapour deposition. The corrosion of Al-coated STS 316S and 316L in molten carbonate at $700^{\circ}C$was studied. Vacuum vapour deposition and thermal spraing for Al-coating on STS 310S and 316L were the most effective methods for protecting thestainless steel corrosion in molten carbonate.

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Characteristics of Low NOx Plasma Burner Incorporating with Rotating Arc Plasma (회전 아크 적용 플라즈마 저 NOx 버너 연소특성)

  • Kim, Kwan-Tae;Kang, Hee-Seok;Lee, Dae-Hoon;Song, Young-Hoon;Park, Jae-Eon
    • Transactions of the Korean hydrogen and new energy society
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    • v.22 no.6
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    • pp.934-941
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    • 2011
  • Characteristics of low NOx burner is investigated. Low NOx burner introduced in this paper adopts two staged combustion with plasma burner for the 1st stage combustion. Extensive parametric tests were done to figure out the effect of burner stoichiometry, staged thermal load, electric power for plasma generation. Overall NOx production by burner shows effective reduction by adopting plasma staged burner. and the aspects depends on the fuel stoichiometry of 1st stage burner or operating condition of plasma burner. It is promising to use plasma burner as an alternative tools of low NOx burner technology.

Characteristics of Chemical Reactions in Coal Gasification Processes (석탄가스화 화학반응의 기본 특성 분석 연구)

  • Baek, Seung-Chul;Sohn, Jeong-L.;Song, Seung-Jin
    • Proceedings of the KSME Conference
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    • 2008.11b
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    • pp.3125-3130
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    • 2008
  • Coal is one of the most abundant and cheapest energy sources in the earth, but its typical combustion product, $CO_2$, is related with serious recent environmental issues such as global warming. The Integrated Coal Gasification Combined Cycle (IGCC) with $CO_2$ sequestration is one of the most promising options to produce electricity using a relatively cheap fuel (coal) with minimum impact on environment. In IGCC power generation systems, some chemical reactions are required to gasify coal to produce syngases such as $H_2$ and CO, which would be burnt in the combustor to produce heat for power generation, with a penalty of additional energy consumption. In this paper, several chemical reactions for the gasification of coal are considered and their characteristics are investigated.

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