• Title/Summary/Keyword: Fuel Film

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Electrical Characterization of Ultrathin Film Electrolytes for Micro-SOFCs

  • Shin, Eui-Chol;Ahn, Pyung-An;Jo, Jung-Mo;Noh, Ho-Sung;Hwang, Jaeyeon;Lee, Jong-Ho;Son, Ji-Won;Lee, Jong-Sook
    • Journal of the Korean Ceramic Society
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    • v.49 no.5
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    • pp.404-411
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    • 2012
  • The reliability of solid oxide fuel cells (SOFCs) particularly depends on the high quality of solid oxide electrolytes. The application of thinner electrolytes and multi electrolyte layers requires a more reliable characterization method. Most of the investigations on thin film solid electrolytes have been made for the parallel transport along the interface, which is not however directly related to the fuel cell performance of those electrolytes. In this work an array of ion-blocking metallic Ti/Au microelectrodes with about a $160{\mu}m$ diameter was applied on top of an ultrathin ($1{\mu}m$) yttria-stabilized-zirconia/gadolinium-doped-ceria (YSZ/GDC) heterolayer solid electrolyte in a micro-SOFC prepared by PLD as well as an 8-${\mu}m$ thick YSZ layer by screen printing, to study the transport characteristics in the perpendicular direction relevant for fuel cell operation. While the capacitance variation in the electrode area supported the working principle of the measurement technique, other local variations could be related to the quality of the electrolyte layers and deposited electrode points. While the small electrode size and low temperature measurements increaseed the electrolyte resistances enough for the reliable estimation, the impedance spectra appeared to consist of only a large electrode polarization. Modulus representation distinguished two high frequency responses with resistance magnitude differing by orders of magnitude, which can be ascribed to the gadolinium-doped ceria buffer electrolyte layer with a 200 nm thickness and yttria-stabilized zirconia layer of about $1{\mu}m$. The major impedance response was attributed to the resistance due to electron hole conduction in GDC due to the ion-blocking top electrodes with activation energy of 0.7 eV. The respective conductivity values were obtained by model analysis using empirical Havriliak-Negami elements and by temperature adjustments with respect to the conductivity of the YSZ layers.

Study on the Heat Flux Using Instantaneous Temperature as Height of Probe in the Combustion Chamber (연손실 순간온도 측저에 있어서 돌출높이에 따른 실험적 연구)

  • 이치우;김지훈;김시범
    • Journal of Advanced Marine Engineering and Technology
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    • v.25 no.2
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    • pp.395-402
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    • 2001
  • The gasoline engine tends to high performance, fuel economy, small-sized. Therefore, it is necessary to solve the problems on thermal load, abnormal combustion, etc, in the engine, Thine film instantaneous temperature measurement probe was made. And the manufactural method of probe was established. The instantaneous surface temperatures in the constant volume combustion chamber were measured by this probe and the heat flux was obtained by Fourier analysis. The authors measured the wall temperature of combustion chamber and computed the heat flux through the cylinder wall in order to understand the combustion characteristics depending on height of probe. For achieving this goal, the thin film instantaneous temperature probe was developed for analyzing the instantaneous surface wall temperature and unsteady heat flux on the constant volume combustion chamber.

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A Study of Hear Flux and Instantaneous Temperature According to the Initial Tamperature of Combustion Chamber in a Constant Volume Combustion Chamber (연소실 초기온도 변화에 따른 순간열유속에 관한 연구)

  • Lee, Chi-Woo
    • Journal of the Korean Society of Industry Convergence
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    • v.6 no.3
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    • pp.193-200
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    • 2003
  • In the production of internal combustion engines, there has been a move towards the development of high performance engines with improved fuel efficiency, lighter weight and smaller sizes. These trends help to answer problems in engines related to thermal load and abnormal combustion. In order to investigate these problems, a thin film-type probe for instantaneously measuring temperatures has been suggested. A method for manufacturing such a probe was established in this study. The instantaneous surface temperature of a constant volume combustion chamber was measured by this probe and the heat flux was obtained through Fourier analysis. In order to thoroughly understand the characteristics of combustion, the authors measured the wall temperature of the combustion chamber and computed heat flux through a cylinder wall while varying the protrusion height of the probe. For achieving the above goals, a instantaneous temperature probe was developed, thereby making possible the analysis of the instantaneous temperature of wall surface and the detection of unsteady heat flux in the constant volume combustion chamber.

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On the Proper Use of Char Reaction Kinetic Model in CFD Code for Oxy-PC Combustion (순산소 미분탄 연소 CFD 연구에 사용되는 촤 반응속도 모델의 적절한 사용에 대한 연구)

  • Kim, Daehee;Choi, Sangmin
    • 한국연소학회:학술대회논문집
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    • 2012.11a
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    • pp.67-70
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    • 2012
  • Many computational fluid dynamic (CFD) simulations have treated the coal kinetics poorly due to large physical domain sizes and high computational complexity, particularly for the recent oxy-coal boilers. Furthermore, some modelers' lack of understanding of the kinetic rate model seems to worsen the simulation accuracy. This study is to suggest the importance of proper use of single-film global kinetic model generally used in CFD code to describe the oxy-fuel combustion of coal char through simple char burnout calculation.

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Surface Roughness Effects on the Lubrication Characteristics of the Engine Piston Ring Pack

  • Yun, Jeong-Eui
    • KSTLE International Journal
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    • v.1 no.2
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    • pp.83-90
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    • 2000
  • The surface roughness between a piston ring pack and a cylinder liner directly affects the fuel economy, the oil consumption, and the emission of the engine so that it is very important to clarify the surface roughness effects on the lubrication characteristics. The friction characteristics of the piston ring during engine operations are known to as mixed lubrication experimentally. In this study to simulate the effects of the surface roughness of the piston ring pack on the lubrication characteristics, the mixed lubrication analysis of piston rings was performed using the simplified average Reynolds equation. From the results the surface roughness was found be considerably affects minimum oil film thickness as well as FMEP(Friction Mean Effective Pressure). Especially, the oil ring was the most sensitive on the surface roughness.

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An Overview of Liquid Spray Modeling Formed by High-Shear Nozzle/Swirler Assembly

  • Koo, Ja-Ye
    • Journal of Mechanical Science and Technology
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    • v.17 no.5
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    • pp.726-739
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    • 2003
  • A multi-dimensioanl model is being increasingly used to predict the thermo-flow field in the gas turbine combustor. This article addresses an integrated survey of modeling of the liquid spray formation and fuel distribution in gas turbine with high-shear nozzle/swirler assembly. The processes of concern include breakup of a liquid jet injected through a hole type orifice into air stream, spray-wall interaction and spray-film interaction, breakup of liquid sheet into ligaments and droplet,5, and secondary droplet breakup. Atomization of liquid through hole nozzle is described using a liquid blobs model and hybrid model of Kelvin-Helmholtz wave and Rayleigh-Taylor wave. The high-speed viscous liquid sheet atomization on the pre-filmer is modeled by a linear stability analysis. Spray-wall interaction model and liquid film model over the wall surface are also considered.

Study on the Heat Flux Using Instantaneous Temperature in the Constant Volume Combustion Chamber (정적연소기에서 순간온도를 이용한 열유속에 관한 연구)

  • 이치우;김지훈;하종률;김시범
    • Transactions of the Korean Society of Automotive Engineers
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    • v.9 no.4
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    • pp.103-111
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    • 2001
  • In the present study, the internal combustion engine tends to high performance, fuel economy, small-sized. Therefore, it is necessary to solve the problems on thermal load, abnormal combustion, etc in the engine. Thin film instantaneous temperature probe was made, and the measuring system was established. The instantaneous surface temperatures in the constant volume combustion chamber were measured with this system and the heat flux was obtained by Fourier analysis. Maximum instantaneous temperatures were obtained after 55∼60ms from ignition and they increased as equivalence ratio and varied differently as the position of probe. Total heat loss during combustion time was affected by the equivalence ratio and differed widely as the position of probe.

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A Study on Interdisciplinary Education Model of Using Climate Change Film-Focusing on Documentary An Inconvenient Truth (기후변화 영화를 활용한 융합교육 모형연구: 다큐멘터리 <불편한 진실>을 중심으로)

  • Hwang, Young-mee;Oh, Jung-jin
    • Journal of Engineering Education Research
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    • v.19 no.5
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    • pp.57-64
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    • 2016
  • This study is about interdisciplinary education model of using Davis Guggenheim's documentary film on global warming which is a big concern in climate change issues, An Inconvenient Truth. It based on Al Gore's slide speech. Through a course student analyzed the cause and phenomenon of global warming resulted from increase of $CO_2$ by using fossil fuel and its environmental science effects-heat wave, desertification, tornado, hurricane, sea level rise caused by melting glaciers, destroying ecosystem like habitat degradation of wild animals, for example polar bear, extreme cold wave caused by change of ocean currents- of global warming. After, student discussed of efforts to prevent global warming. This educational model is appropriate for lower grade student of environmental engineering and also available for converged majors or general education class.

CHARACTERISTICS OF WALL IMPINGEMENT AT ELEVATED TEMPERATURE CONDITIONS ON GDI SPRAY

  • Park, J.;Im, K.S.;Kim, H.;Lai, M.C.
    • International Journal of Automotive Technology
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    • v.5 no.3
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    • pp.155-164
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    • 2004
  • The direct injection gasoline spray-wall interaction was characterized inside a heated pressurized chamber using various visualization techniques, including high-speed laser-sheet macroscopic and microscopic movies up to 25,000 frames per second, shadowgraph, and double-spark particle image velocimetry. Two hollow cone high-pressure swirl injectors having different cone angles were used to inject gasoline onto a heated plate at two different impingement angles. Based on the visualization results, the overall transient spray impingement structure, fuel film formation, and preliminary droplet size and velocity were analyzed. The results show that upward spray vortex inside the spray is more obvious at elevated temperature condition, particularly for the wide-cone-angle injector, due to the vaporization of small droplets and decreased air density. Film build-up on the surface is clearly observed at both ambient and elevated temperature, especially for narrow cone spray. Vapor phase appears at both ambient and elevated temperature conditions, particularly in the toroidal vortex and impingement plume. More rapid impingement and faster horizontal spread after impingement are observed for elevated temperature conditions. Droplet rebounding and film break-up are clearly observed. Post-impingement droplets are significantly smaller than pre-impingement droplets with a more horizontal velocity component regardless of the wall temperature and impingement angle condition.

Anode-supported Solid Oxide Fuel Cells Prepared by Spin-coating (Spin-coating 공정에 의해 제조된 음극 지지형 고체산화물 연료전지)

  • Yu, Ji-Haeng;Lee, Hee-Lak;Woo, Sang-Kuk
    • Journal of the Korean Ceramic Society
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    • v.44 no.12
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    • pp.733-739
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    • 2007
  • NiO-YSZ anode-supported single cell was prepared by spin-coating YSZ and LSM slurries as electrolyte and cathode, respectively. Dense YSZ electrolyte film was successfully prepared on the porous NiO-YSZ anode substrate by tuning pre-sintering temperature of NiO-YSZ and co-firing temperature. The thickness of YSZ film was controlled by the solid content of slurry and coating cycles. The experimental conditions affecting on the thickness of YSZ film was discussed. Single cells with the active electrode area ${\sim}0.8\;cm^2$ were prepared by spin-coating the cathode layers of LSM-YSZ mixture and LSM consequently as well. The effects of the pre-sintering temperature and thus the microstructure of NiO-YSZ substrate on the current-voltage characteristics of co-fired cell were investigated.