• 한국막학회:학술대회논문집
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• 한국막학회 2005년도 학술대회지
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• pp.21-37
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• 2005

• 한국전기화학회:학술대회논문집
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• 한국전기화학회 2003년도 연료전지심포지움 2003논문집
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• pp.147-150
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• 2003

• 한국전기화학회:학술대회논문집
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• 한국전기화학회 2004년도 수소연료전지공동심포지움 2004논문집
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• pp.181-184
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• 2004

• 한국전기화학회:학술대회논문집
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• 한국전기화학회 2004년도 수소연료전지공동심포지움 2004논문집
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• pp.211-214
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• 2004

• 한국항공우주학회지
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• 제39권9호
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• pp.858-865
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• 2011

본 논문은 연료전지 항공기를 위한 고체상태 $NaBH_4$의 수소발생 및 연료전지 구동 특성에 대해서 기술하고 있다. 수소 저장밀도를 높이기 위해서 고체상태 $NaBH_4$와 염산을 반응시켜 수소를 발생시키는 방법을 사용하였다. 다양한 반응 조건에서 고체상태 $NaBH_4$의 수소 발생률을 측정하였다. 고체 $NaBH_4$의 수소 발생률은 염산의 주입속도와 농도에 영향을 받지만, 환경온도에 영향을 받지 않는 것을 확인하였다. 연료전지를 고체 $NaBH_4$ 수소 발생기에 연결하였다. 전기적 부하가 서서히 혹은 급격히 증가하여도 안정적인 출력을 유지하는 것을 확인하였다.

• 한국수소및신에너지학회논문집
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• 제2권1호
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• pp.57-67
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• 1990

This study is proposed to investigate the effect of electrode preparation method for Alkaline Fuel Cell using NaOH as an electrolyte on the Fuel Cell performance. The materials used for the preparation of electrode are Pt and Ag on Vulcan XC-72. Surface area of Vulcan XC-72 have different values according to the pretreatment conditions and the dispersion of Pt is dependent on the impregnation Particle size of Pt impregnated on unpretreated carbon was observed to be $20{\sim}40{\AA}$ and that on pretreated carbon in $N_2$ stream at $950^{\circ}C$ was found to be finely dispersed less then $15{\AA}$. The electrode performance was affected by the particle size of metals and operating temperature. It was revealed from this study that the optimum particle size about $30{\AA}$ and optimum temperature range is between $90{\sim}100^{\circ}C$.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2008년도 춘계학술대회 논문집
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• pp.61-64
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• 2008

$Pr_{0.3}Sr_{0.7}Co_{0.3}Fe_{0.7}O_{3-\delta}$ (PSCF3737) was prepared and characterized as a cathode material for intermediate temperature-operating solid oxide fuel cell (IT-SOFC). X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), extended X-ray absorption fine structure (EXAFS), and electrical property measurement were carried out to study cathode performance of the material. XPS and EXAFS results proved that oxygen vacancy concentration was decreased and lattice constants of the perovskite structure material were increased by doping Fe up to 70 mol% at B-site of the crystal structure, which also extended the distance between oxygen and neighbor atoms. Thermal expansion coefficient (TEC) of PSCF3737 is smaller than that of $Pr_{0.3}Sr_{0.7}CoO_{3-\delta}$(PSC37) due to lower oxygen vacancy concentration. PSCF3737 showed better cathode performance than PSC37. It might be due good adhesion by a smaller difference of TEC between $Gd_{0.1}Ce_{0.9}O_2$ (CGO91) and electrode. Composite material PSCF3737-CGO91 showed better compatibility of TEC than PSCF3737. However, PSCF3737-CGO91 did not represent higher electrochemical property than PSCF3737 due to decreased reaction sites by CGO91.

• 한국환경과학회지
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• 제5권4호
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• pp.535-544
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• 1996

In the development of Molten Carbonate Fuel Cell, one of the serious problems is the dissolution of cathode material. Therefore, the development of the alternative cathode which is stable in molten carbonate is needed. In this research, the licoo, was chosen as alternative cathode material. $LiCoO_2$ powder was synthesized by high temperature calcination method and by citrate sol-gel method. And its structure and physical iharacteristics were analyzed by XRD, 1 R, TCA and porosimeter. The conductivity and solubility of $LiCoO_2$ electrode were also measured. Homogeneous $LiCoO_2$ Powder was obtained by citrate sol-Rel method at 445$^{\circ}C$, however, obtained above 75$0^{\circ}C$ by high temperature calcination method. Homogeneous particle size distribution and fine powder were obtained by the citrate sol-Rel method. $LiCoO_2$ electrode showed higher electric conductivity ($1.7 $\Omega$^{-1}cm^{-1}$) than NiO (0.1 $\Omega$^{-9} cm^{-1}) at $650^{\circ}C$. The solubilities of $LiCoO_2$ electrode in electrolyte were varies 0.6 to 1.0 ppm during 200 hours. So, the solubilities of $LiCoO_2$ were much lower than that of NiO.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2007년도 춘계학술대회
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• pp.133-136
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• 2007

Perovskite-structured samarium strontium cobaltite (SSC), which is mixed ionic electronic conductor (MIEC), is considered as a promising cathode material for intermediate temperature-operating solid oxide fuel cell (SOFC) due to its high electrocatalytic property. Cathode material containing cobalt (Co) is unstable at high temperature and has a relatively high thermal expansion property. In this paper, Sm-Sr-(Co,Fe,Ni)-O system with perovskite and spinel structures was investigated in terms of electrochemical property and thermal expansion property, respectively. Area specific resistance (ASR) was measured by ac impedance spectroscopy to investigate the electrochemical property of cathode, and thermal expansion coefficient (TEC) was measured by using dilatometer. Micro structure of cathode was observed by scanning electron microscopy. Perovskite-structured $Sm_{0.5}Sr_{0.5}CoO_{3-\delta}$ showed the ASR of $0.87{\Omega}/cm^{2}$, and $Sm_{0.5}Sr_{0.5}NiO_{3-\delta}$, which actually has a spinel structure, showed the lowest TEC value of $13.3{\times}10^{-6}/K$.

• 한국추진공학회:학술대회논문집
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• 한국추진공학회 2009년도 제33회 추계학술대회논문집
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• pp.278-281
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• 2009

소형 정찰 UAV의 새로운 동력원으로 적용하고자 하는 연료전지 시스템의 경량화를 위한 연구로 알루미늄 분리판의 성능을 측정하였다. 흑연 분리판과의 성능 비교를 통해 알루미늄 분리판이 흑연 분리판에 비해 무게 대비 높은 성능을 보이는 것을 확인하였다. 작동온도에 따른 성능 변화를 확인하기 위해 40 / 50 / $60^{\circ}C$의 작동온도에서 알루미늄 단위 전지의 성능을 측정한 결과 건조한 반응기체의 경우 일반적인 작동온도 보다 비교적 낮은 $40^{\circ}C$에서 가장 좋은 성능을 보이는 것을 확인하였다.