• 한국신재생에너지학회:학술대회논문집
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• 2006.06a
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• pp.59-62
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• 2006

Formability is requested to successfully develop of a metal bipolar plate for mass production. From this point of view, wider channel and land width is more helpful to improve formability. But the performance of the fuel cell can be affected by its channel and land shape. So it is very important to select proper channel and land shape not to deteriorate the fuel cell performance. In this work, 3-dimensional, non-isothermal numerical simulation was performed to analyse the effects of channel and land width on the fuel cell performance. 3 types of straight channel were selected for the numerical simulation. The simulation results reveal that wide channel and land width lower fuel cell performance and decrease voltage at a high current density region. Water activity, temperature, oxygen concentration distributions were investigated to find the reasons of performance degradation. The results show that wide channel and land width give an bad effect on fuel cell performance because of low cool ins efficiency and lack of oxygen gas under the land.

• Journal of Radiation Industry
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• v.6 no.4
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• pp.289-297
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• 2012

Since Nafion is very expensive and shows the decreased fuel cell performance over $80^{\circ}C$ operating temperature, much work has been carried out in the search for cheaper membrane with high fuel cell performance. Radiation is known to be very useful for the preparation of the polymer electrolyte membranes since it can be effectively used for the introduction of ion conducting functional groups into the commercial film with high mechanical and chemical properties. Here, we summarize the our recent progress in the development of fuel cell membranes by utilizing radiation.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.21 no.4
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• pp.517-529
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• 2023

The objectives of this paper are: (1) to conduct the thermal analyses of the disposal cell using COMSOL Multiphysics; (2) to determine whether the design of the disposal cell satisfies the thermal design requirement; and (3) to evaluate the effect of design modifications on the temperature of the disposal cell. Specifically, the analysis incorporated a heterogeneous model of 236 fuel rod heat sources of spent nuclear fuel (SNF) to improve the reality of the modeling. In the reference case, the design, featuring 8 m between deposition holes and 30 m between deposition tunnels for 40 years of the SNF cooling time, did not meet the design requirement. For the first modified case, the designs with 9 m and 10 m between the deposition holes for the cooling time of 40 years and five spacings for 50 and 60 years were found to meet the requirement. For the second modified case, the designs with 35 m and 40 m between the deposition tunnels for 40 years, 25 m to 40 m for 50 years and five spacings for 60 years also met the requirement. This study contributes to the advancement of the thermal analysis technique of a disposal cell.

• New & Renewable Energy
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• v.5 no.1
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• pp.11-17
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• 2009

To improve the performance of the anode-supported Solid Oxide Fuel Cell (SOFC) which can be operated at an intermediate temperature, the functional layer (FL) is introduced on a anode substrate. And the scandia-stabilized zirconia (ScSZ) and samaria-doped ceria (SDC) which have higher ionic conductivity and better chemical stability than yttria-stabilized zirconia (YSZ) are used as material for the anode FL with the Ni, The fabrication process of anode-supported single cell with the anode FL was established and the power density of those was evaluated. As a result, the sample with anode FL (Ni-YSZ) has higher power density than normal cell. The single cell which was composed of the FL (Ni-YSZ) and electrolyte (YSZ) showed about $550mW/cm^2$ of the maximum power density at $650^{\circ}C$ and $1430mW/cm^2$ at $750^{\circ}C$ respectively, In case of the single cell using the ScSZ and SDC as anode FL, the performance of samples decreased rapidly and those showed unstable voltage during long-term test. In case of using methane as a fuel, the cell performance with each FL decreased comparing with $H_2$ fuel. In the region of a high current density, there are large concentration polarizations.

• Transactions of the Korean hydrogen and new energy society
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• v.24 no.3
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• pp.230-236
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• 2013

In this study, successive coating and co-sintering techniques have been used to fabricate LSM/GDC based cathode supported direct carbon fuel cells. The porous LSM/GDC cathode substrate, dense, thin and crack free GDC and ScSZ layers as bi-layer electrolyte, and a porous Ni/ScSZ anode layer was obtained by co-firing at $1400^{\circ}C$. The porous structure of LSM/GDC cathode substrate, after sintering at $1400^{\circ}C$, was obtained due to the presence of GDC phase, which inhibits sintering of LSM because of its higher sintering temperature. The electrochemical characterization of assembled cell was carried out with air as an oxidant and carbon particles in molten carbonate as fuel. The measured open circuit voltages (OCVs) were obtained to be more than 0.99 V, independent of testing temperature. The peak power densities were 116, 195 and $225mWcm^{-2}$ at 750, 800 and $850^{\circ}C$, respectively.

• Bulletin of the Korean Chemical Society
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• v.25 no.6
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• pp.813-818
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• 2004

A systematic study of microbial fuel cells comprised of thermophilic Bacillus licheniformis and Bacillus thermoglucosidasius has been carried out under various operating conditions. Substantial amount of electricity was generated when a redox mediator was used. Being affected by operation temperature, the maximum efficiency was obtained at 50$^{\circ}C$ with an open circuit voltage of ca. 0.7 V. While a small change around the optimum temperature did not make much effect on the cell performance, the rapid decrease in performance was observed above 70$^{\circ}C$. It was noticeable that fuel cell efficiency and discharge pattern strongly depended on the kind of carbon sources used in the initial culture medium. In the case of B. thermoglucosidasius, glucose alone was utilized constitutively as a substrate in the microbial fuel cell irrespective of used carbons sources. When B. licheniformis was cultivated with lactose as a carbon source, best charging characteristics were recorded. Trehalose, in particular, showed 41.2% coulombic efficiency when B. thermoglucosidasius was cultured in a starch-containing medium. Relatively good repetitive operation was possible with B. thermoglucosidasius cells up to 12 cycles using glucose as a carbon source, when they were cultured with lactose as an initial carbon source. This study demonstrates that highly efficient thermophilic microbial fuel cells can be constructed by a pertinent modulation of the operating conditions and by carefully selecting carbon sources used in the initial culture medium.

• Journal of Energy Engineering
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• v.25 no.4
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• pp.176-183
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• 2016

This study relates to a polymer electrolyte membrane for improved performance fuel cell, were researched with respect to properties required for driving a fuel cell. The bis(4-fluorophenyl)phenyl phosphine oxide was sulfonated using fuming sulfuric acid. Synthetic hydrophilic oligomer and the hydrophobic oligomer and the block copolymers were prepared via aromatic nucleophilic substitution polycondensation. A block copolymer structure and degree of sulfonation was analyzed by $^1H$-NMR and gel permeation chromatography(GPC) analysis. Thermal stability was confirmed by thermogravimetric analysis(TGA), block copolymer was stable at high temperature(>$200^{\circ}C$), The ion conductivity was measured in order to demonstrate the performance of fuel cell. Synthesis membrane was the increase of temperature was improved conductivity up to 58 mS/cm due to the influence of the developed ion clusters. The phase separation of the polymer was observed to make AFM analysis.

• Transactions of the Korean hydrogen and new energy society
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• v.29 no.4
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• pp.386-392
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• 2018

Fuel cells are known as eco - friendly energy facilities that can use heat energy and electric energy at the same time. Fuel cells are classified according to the temperature and material used, and solid oxide fuel cell (SOFC) is relatively high temperature ($700-800^{\circ}C$). SOFC requires a hot box consisting of a high temperature stack, a reformer, a burner, and the heat exchangers in order to use energy efficiently. The hot box needs to maintain heat insulation performance at high temperature to reduce heat loss. However, Fibrous insulation, which is widely used, needs to be improved because it has a disadvantage that the thermal conductivity is rapidly increased due to the increase of temperature. Therefore, this study was carried out to develop a thermal insulation, which is applied to multiple layers insulation (MLI) technic, that can be used under SOFC operating conditions and prevent a drastic drop in thermal conductivity at high temperature. The developed insulation is consist of a thermally conductive material, a spacer, and a reflective plate. The thermal conductivity of the insulation was measured by in the thermal conductivity measuring device at high temperature range. As a result, it was confirmed that the developed layers insulation have an good thermal conductivity (0.116 W/mK) than fibrous insulation (0.24 W/mK) as a radiation shielding effect at a high temperature of 1,173 K.

• Proceedings of the KSME Conference
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• 2007.05b
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• pp.3423-3428
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• 2007

This paper shows that inlet humidity condition at cathode side is one of dominant parameters affecting the performance of PEMFC. To investigate effects of inlet humidity condition, the performance measurements were conducted for a single PEMFC with two operating variables : cathode relative humidity and dry condition in anode dry. The fuel cell employed for the experiments is a unit PEMFC with a 25$Cm^2$, Nafion$^(R)$112 membrane. As a result of this study, the cell performance is getting higher by increasing inlet humidity condition at cathode side. The cell performance is different from each operating temperature an it has maximum30% higher than dry condition at 60$^{\circ}C$ operating temperature with 80% relative humidity.

• Transactions of the Korean hydrogen and new energy society
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• v.20 no.3
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• pp.224-231
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• 2009

The improvement of cold start capability is one of the most challenging tasks to be solved for commercialization of fuel cell vehicle. In this study, cold start test and ice blocking test(IBT) of fuel cell stack were carried out under various operating conditions. This fuel cell stack can be thawed from -20$^{\circ}$C within 25s and the voltage change was found to be comprised of 4 steps; the first step is the voltage decrease by overpotential, the second step is the voltage increase by the cell temperature increase, the third step is the voltage decrease by ice blocking, and the last step is the voltage increase by thawing. Bootstrap startup was failed after shutdown at temperature under 40$^{\circ}$C because of much condensed water in the fuel cell. Quantitative estimation of cold start capability have been demonstrated by ice blocking test(IBT). In the results, it was found that cold start capability was improved double every 10$^{\circ}$C from 30$^{\circ}$C to 65$^{\circ}$C and enhanced by 30% at the condition of SR 3/4 compared to SR 1.5/2.0 and enhanced by 20% with dry purge condition compared to with RH 50% purge condition.