• 제목/요약/키워드: Freezing point

검색결과 208건 처리시간 0.022초

Experimental study on freezing point of saline soft clay after freeze-thaw cycling

  • Wang, Songhe;Wang, Qinze;Qi, Jilin;Liu, Fengyin
    • Geomechanics and Engineering
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    • 제15권4호
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    • pp.997-1004
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    • 2018
  • The brine leakage is a tough problem in artificial freezing engineering. This paper takes the common soft clay in Wujiang District as the study object, and calcium chloride solutions with six salinity levels were considered. The 'classic' cooling curve method was employed to measure the freezing point of specimens after freeze-thaw. Results indicate that four characteristic stages can be observed including supercooling, abrupt transition, equilibrium and continual freezing, strongly dependent on the variation of unfrozen water content. Two characteristic points were found from the cooling curves, i.e., freezing point and initial crystallization temperature. A critical value for the former exists at which the increment lowers. The higher the saline content approximately linearly, lower the freezing point. In the initial five cycles, the freezing point increases and then stabilizes. Besides, the degree of supercooling was calculated and its correlations with water, salt and freeze-thaw cycles were noted. Finally, an empirical equation was proposed for the relationship of freezing point and three main factors, i.e., water content, saline content and freeze-thaw cycles. Comparison of calculated and measured data proves that it is reliable and may provide guidance for the design and numerical analysis in frozen soil engineering.

유한차분법을 이용한 깐밤의 동결시간 예측 (Prediction of Freezing Time for Peeled Chestnut using Finite Difference Method)

  • 이충호;김종훈
    • Journal of Biosystems Engineering
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    • 제33권1호
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    • pp.21-29
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    • 2008
  • In this study, the thermal properties of peeled chestnuts were measured, and the mathematical prediction model of freezing time was also developed for various interior positions from center to rind (surface). The measured thermal properties were showed that heat conductivity is $0.43W/m^{\circ}C$, specific heat is $2.7206J/m^3^{\circ}C$, latent heat is $216.9{\times}10^6J/m^3$ and freezing point is $-2.8^{\circ}C$. The entire process about reaching to the freezing time of peeled chestnuts was analyzed with its each regular depth position using the finite difference method (FDM) based on computer simulation. In case of regular freezing temperature, it was showed an that surface (rind) position is more rapidly reached into the freezing point rather than the center position, and also reaching time to the freezing point is more fast at the lower freezing temperature. Comparison results between simulation and experiments showed linear relationship. In regularly varying condition for freezing temperature, this method would give an information to predict a freezing time of the interior points for peeled chestnuts and more similar agricultural products.

빙점강하제를 이용한 수삼의 선도연장 (Freshness Extension of Ginseng with Freezing Point Depressing Agents)

  • 남궁배;정문철;김동만;문광덕;최종욱
    • 한국식품저장유통학회지
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    • 제7권1호
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    • pp.57-62
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    • 2000
  • Ginseng was stored at a temperature lower than the freezing point after a treatment of freezing point depressing agents to extend its freshness. Respiration rate at freezing point of ginseng, -1.7${\pm}$0.1$^{\circ}C$, was inhibited 92% and 97% compared with those stored at 5$^{\circ}C$or 20$^{\circ}C$ , respectively. Sorbitol solution chosen as a freezing point depressing agent lowered the freezing point of ginseng to about -3.0$^{\circ}C$. Ginsengs treated with the sorbitol solution and packaged with 0.06mm LDPE was stored at -2$^{\circ}C$ , and the quality change was then compared with ginsengs stored at 0$^{\circ}C$ and 5$^{\circ}C$. Weight loss of ginsengs stored at -2$^{\circ}C$ for 100days was 1.5%, which is about 2.6times less than those stored at 5$^{\circ}C$. However, there were no significant difference between the ginsengs stored at -2$^{\circ}C$ and at 0$^{\circ}C$(1.9%). Spoilage rate of the ginsengs was 100% after 50 days of storage at 5$^{\circ}C$ and 25% after 100days at 0$^{\circ}C$respectively. but that of ginsengs stored at -2$^{\circ}C$ was 13%, which was half than that of ginsengs stored at 0$^{\circ}C$. Firmness and amount of monoscaccharides in ginsengs were decreased during storage at 5 or 0$^{\circ}C$ but ginsengs stored at -2$^{\circ}C$ showed better firmness and an increase in monosaccharides such as fructose and glucose. From above, when ginseng treated with freezing pont depressing agents were stored at -2$^{\circ}C$, the shelf life was extended to 2 or 3 times longer than those that were stored at 5 or 0$^{\circ}C$, respectively.

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전기로 및 봉입형 응고점 셀 내의 온도구배가 미치는 표준백금저항온도계 온도측정의 불확도 요소 평가 (Evaluation of Uncertainty Sources in Temperature Measurement Using Platinum Resistance Thermometer Caused by Temperature Gradient in Furnace and Sealed-type Freezing Point Cells)

  • 강기훈;감기술;김용규;송창호
    • 센서학회지
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    • 제13권6호
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    • pp.411-416
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    • 2004
  • In the international temperature scale of 1990 (ITS-90), standard platinum resistance thermometer (SPRT) is a defining standard thermometer used in the temperature range from 13.8033 K to $961^{\circ}C$. Uncertainty of SPRT is about several mK and uncertainty of defining fixed points of the ITS-90 which is used for calibrating SPRT is about several tenth of mK. Above $0^{\circ}C$. the defining fixed points are gallium melting point and indium, tin, zinc, aluminium and silver freezing points which are all realized using an electric furnace or a liquid bath. To realize freezing point of tin ($231.928^{\circ}C$) and zinc ($419.527^{\cir}C$), two 3-zone furnaces which have 3 electric heaters were manufactured. Temperature gradient of the constructed furnaces were tested. Uncertainty caused by temperature gradient of furnace and immersion effect of SPRT in the sealed-type freezing point cells were evaluated 0.038 mK for tin freezing point and 0.036 mK for zinc freezing point.

응회암 풍화토의 동결특성에 관한 열역학적 연구-상재하중과 동결점 저하를 중심으로- (A Thermodynamic Study on Freezing Characteristics of Weathered Tuff Soil- Freezing Point Depression with the Variation of Overburden Pressure -)

  • 서상열
    • 한국지반공학회논문집
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    • 제15권6호
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    • pp.297-306
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    • 1999
  • 본 연구에서는 우란바톨(Ulanbator)에서 북경(Beijing)사이의 지역에서 샘플링한 응회암 풍화토의 동상 특성을 규명하기 위해 상재하중 변화에 따른 동결점 저하를 중심으로 양단면 온도 일정$(상단 5^{\circ}C,\; 하단 5^{\circ}C)$의 동상실험 실시하였다. 본 실험을 통해, 빙편 성장에 따른 체적 팽창과 동결면으로의 수분이동을 확인하였다. 그리고 상재하중과 온도와의 관계식을 제안하였다. 상재하중이 증가함에 따라 동상속도는 비례적으로 감소하였고 빙편발생온도의 절대치는 증가하였다. 또한 동결부분의 함수비가 미동결 부분보다 크게, 특히 동결부분에서도 빙정에 가까울수록 함수비는 증가하였다.

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어느점 내림 현상에 대한 교과서 내용 및 중등 과학 교사들의 개념 분석 (The Analysis of Textbook Contents and Science Teachers' Conceptions on Freezing Point Depression Phenomenon)

  • 하성자;김범기;백성혜
    • 한국과학교육학회지
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    • 제25권2호
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    • pp.88-97
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    • 2005
  • 이 연구에서는 어는점 내림에 대한 과학교과서의 설명 방식과 과학 교사들의 개념을 조사하였다. 분석한 교과서는 7차 교육과정에 근거하여 개발된 중학교 2학년 과학교과서 7종과 고등학교 화학 II 교과서 5종이었다. 교사들의 개념은 설문지를 통해 얻었으며, 연구 대상 교사의 수는 146명이었다. 교과서의 설명 유형은 '현상을 묘사' 하는 것과 '증기압 내림으로 설명' 하는 유형으로 구분하였다. 대부분의 중학교 교과서와 고등학교 교과서에서는 현상을 묘사하는 수준으로 어는점 내림을 설명하였으며, 이러한 현상이 일어나는 이유에 대한 설명은 없었다. 또한 어는점 내림을 설명하는 그래프의 내용도 교과서마다 달랐다. 교사들 역시 어는점 내림에 대해 제대로 이해하지 못하는 것으로 나타났다. 용질의 방해로 어는점 내림 현상을 이해하는 교사들도 많았다. 그러나 끓는점 오름 현상을 설명할 때 도입되는 이러한 개념이 어는점 내림에서는 어떻게 관련되는지 명확하게 설명하지 못하였다. 이 연구에서는 어는점 내림 현상을 설명하기 위하여 엔트로피의 개념을 도입할 필요성에 대해 주장하였다.

결빙구간의 교통사고 심각도 영향 요인 연구 (A Study on Factors that Influence Traffic Accident Severity in Road Surface Freezing)

  • 이상준
    • 한국안전학회지
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    • 제32권6호
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    • pp.150-156
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    • 2017
  • A frozen road surface increases traffic accidents during the winter season. Hence, information on easily-frozen road sections and their specificities are required to prevent traffic accidents. Frozen road surfaces are determined by equipment measuring road surface temperatures. However, there are limitations in investigating the entire road network. Therefore, it is imperative to develop new methods that effectively determine road surface freezing risks. Meteorologically, road surfaces are frozen when the actual temperature cools down to the dew point temperature. Under this condition, there is likely to be frost if relative humidity reaches 100% and frozen road surfaces as the temperature gets lower. Meteorological characteristics give us an alternative to a direct measurement road surface temperature to estimate risks of road surface freezing. Based on the clues, the relationship between severity of traffic accidents and temperature changes is empirically investigated using Paju weather data. The results reveal that as the temperature gets lower and changes in current temperature are relatively small, the severity of traffic accidents become higher. In addition, the same is true when the difference between current temperature and the dew point temperature is relatively small, as it increases possibilities of road surface freezing. Future studies must investigate how current temperature and the dew point temperature affect road surface freezing and thereby establish a time-space scope to estimate possible road surface freezing sections using only weather and road material type data. This would provide invaluable information for predicting and preventing frozen road accidents based on weather patterns.

도로 노면결빙 판정모델을 적용한 도로결빙 예측에 대한 연구 (A study on road ice prediction by applying road freezing evaluation model)

  • 임희섭;김상태
    • 한국응용과학기술학회지
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    • 제37권6호
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    • pp.1507-1516
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    • 2020
  • 본 연구는 도로 노면결빙 판정 알고리즘을 적용하여 도로결빙 구간에 대한 시나리오를 분석하였다. 도로결빙 알고리즘 적용을 위해서, 도로 결빙에 대한 영향인자를 검토하고, 분석을 위해서 목감IC, 정릉터널, 성산대교, 염창교 등 4지점의 관측자료를 활용하였다. 관측소는 모두 고속화도로에 설치되어 있으며, 도로 결빙 특성 분석을 위하여 분류하였다. 도로 결빙 판정 알고리즘의 노면온도-노점온도 차가 3℃ 이하일 때 도로결빙 발생 구간을 확인하고 결빙 구간의 노면상태와 수막두께 변화를 통해 도로 결빙 판정을 도출하였다.

'어는점 내림'에 대한 초등 예비교사들의 인식 조사 및 설명 모형 제안 (Elementary Pre-service Teachers' Conceptions on 'the Freezing Point Depression' and a Proposal of Explanatory Models)

  • 김한제;정용재;장명덕
    • 한국초등과학교육학회지:초등과학교육
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    • 제32권2호
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    • pp.206-224
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    • 2013
  • The purpose of this study is to investigate the elementary pre-service teachers' conceptions on 'the freezing point depression' focusing on the survey from a National University of Education. Eighteen pre-service teachers who had completed high school Chemistry II coursework were selected to participate in the study. Participants answered a four question survey to measure their scientific knowledge and conceptions of this phenomenon. Each answer was qualitatively analyzed to determine whether they have 'scientific conceptions' or 'quasi-scientific conceptions' or 'misconceptions'. The results from the study are as follows: First, it was showed that none of the eighteen participants had 'scientific conceptions', six had 'quasi-scientific conceptions' and eight had 'misconceptions' about the caused effect when $CaCl_2$ is scattered on the ice. Second, it was found that three participants had 'scientific conceptions', eight had 'quasi-scientific conceptions' and two had 'misconceptions' for the second survey question. Third, ten out of eighteen participants demonstrated 'scientific conceptions' about the phenomenon of salt water freezing. Fourth, only three of eighteen participants illustrated appropriate 'scientific conceptions' for the fourth survey question. Fifth, of all participants, none answered more than three questions correctly, and only three participants answered any combination of two questions correctly. Based on the findings of this study, five explanatory models were developed. And the models were proposed for pre-service teachers to enhance their understanding of the freezing point depression phenomenon.

식품의 동결중에 생성되는 빙결정에 미치는 동결조건의 영향 (Effect of Freezing Conditions on the Formation of Ice Crystals in Food during Freezing Process)

  • 공재열;김정한;김민용;배승권
    • 한국식품영양과학회지
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    • 제21권2호
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    • pp.213-218
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    • 1992
  • 식품의 동결중에 생성되는 빙결정의 크기에 미치는 동결조건의 영향을 조사하고 그 관계를 정량적으로 평가함과 아울러 동결조건과 빙결정 분산구조와의 관계를 이론해석에 의해 조사한 결과, 1. 동결이동속도 u는 생성빙결정의 평균경 d$_{p}$와 u .d$_{p}$/D~constant의 관계에 있음을 간단한 차원해석에 의해 예측이 가능하였다. 2. 2% 한천 겔, 5%한천 겔, 20% 젤라틴 겔, 돈육의 순서로 동결점에 도달하는 시간이 빨라지며 동결시간 및 최대빙결품 생성대의 통과시간은 냉매온도와 선형적인 관계를 나타내었다. 3. 대두 단백질 겔중에 생성되는 빙결정의 평균경 d$_{p}$와 동결계면 이동속도 u 는 반비례 관계를 나타내었으며, 이로부터 구해진 u .d$_{p}$의 값은 3.4$\times$$10^{-6}$ $\textrm{cm}^2$/sec로 예측 이론식이 유효한 것으로 사료되었다. 4. 동결보존중의 대두 단백질 겔 내부에 생성된 빙결정의 성장에 미치는 보존온도의 영향을 조사한 결과, 양자가 빙결정의 성장에 미치는 영향은 거의 없는 것으로 나타났다. 5. 동결조건과 동결계면구조와의 사이에 Moving velocity of freezing front= (Mass transfer rate of water at freezing front)$\times$ (Surface area of freezing front) 의 관계를 나타내었다.

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