• Title/Summary/Keyword: Freezing Solution

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Strength and Durability Properties of Recycled Polymer Concrete Using Unsaturated Polyester Resin and Recycled Aggregates (불포화폴리에스터 수지와 재생골재를 이용한 재생 폴리머 콘크리트의 강도 및 내구 특성)

  • Kim, Young-Ik;Sung, Chan-Yong
    • Journal of The Korean Society of Agricultural Engineers
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    • v.51 no.6
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    • pp.97-103
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    • 2009
  • This study was performed to evaluate the strength and durability properties of recycled polymer concrete using unsaturated polyester resin and recycled aggregates. Unsaturated polyester resin, natural and recycled aggregates and fly ash were used. The mix proportions were determined to satisfy the requirement for the workability and slump according to aggregate sizes (5-10 and 5-25 mm) and unit binder contents (10% and 12%). Tests for the compressive and flexural strength, freezing and thawing and durability for 20% sulfuric solution were performed. The compressive and flexural strength of recycled polymer concrete were in the range of 85~97 MPa and 17.9~20.8 MPa, respectively. The strengths of recycled polymer concrete using recycled aggregate have similar or slightly decreased compared to polymer concrete using natural aggregate. After 300 cycles of freezing and thawing, weight decrease ratio and durability factor of recycled polymer concrete were in the range of 0.13~1.42% and 94~99, respectively.

A Numerical Study on the Phase-change Heat transfer problem in Cryosurgery (냉동수술시 수반되는 상변화 열전달 문제에 대한 수치해석적 연구)

  • 김동혁
    • Journal of Advanced Marine Engineering and Technology
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    • v.20 no.3
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    • pp.162-170
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    • 1996
  • A numerical study on the Stefan problem occurred in cryosurgery is performed. Crank-Nicholson type finite difference algorithm based on the enthaly method is adapted to solve the phase change problem in this study. As it is a moving boundary problem, special emphasis is put on the estimation of the freezing front location. Two cases selected here are freezings of human tissue by disk type cryoprobe and by hemispherical one. In both cases, the heat flows are considered to be one dimensional. The calculated results using enthalpy method are compared with those using the program TRUMP and with Neumann's solution. These results agree guite well with each other. While it is pretty difficult to get accurate freezing front location by TRUMP due to the so- called "phase change knee" occured during the phase change, the algorithm based on the enthalpy method is proved to be very powerful to cope with this kind of problem.f problem.

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Numerical Investigation of Urea Freezing and Melting Characteristics Using Coolant Heater (냉각수 순환 가열 방식을 이용한 요소수의 동결 및 해동 특성에 관한 수치적 연구)

  • Lee, Seung Yeop;Kim, Nam Il;Park, Yun Beom;Kim, Man Young
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.37 no.8
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    • pp.717-724
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    • 2013
  • Urea-SCR technology is known as one of the powerful NOx reduction systems for vehicles as well as stationary applications. For its consistent and reliable operation in vehicle applications, however, the freezing and melting of the urea solution in cold environments have to be resolved. In this study, therefore, a numerical study of three-dimensional unsteady problems was analyzed to understand the urea freezing and heating phenomena and heat transfer characteristics in terms of urea liquid volume fraction, temperature profiles, and phase change behavior in urea solutions with time by using the commercial software Fluent 6.3. As a result, it was found that the freezing phenomenon proceeds with a phase change from the tank wall to the center, whereas the melting phenomenon occurs faster in the upper part of the storage tank by natural convection and in the adjacent part of the coolant pipe than in other parts. Furthermore, approximately 190 s were required to obtain 1L of urea solution using a 4-coiled coolant heater under conditions of $70^{\circ}C$ and 200 L/h.

Separation Performance and Application of Sericin Protein in Silk Degumming Solution(2) (실크 정련 세리신 단백질의 분리특성과 응용(2))

  • Cha, Chin-U;Park, In-Woo;Bae, Kie-Seo;Hong, Young-Ki;Lee, Seo-Hee;Kim, Yong-Duck
    • Textile Coloration and Finishing
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    • v.22 no.2
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    • pp.132-139
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    • 2010
  • Sericin pulverization process was applied by freezing-thawing of sericin protein concentration solution and physicochemical properties of sericin/chitosan blended films were investigated. In sericin pulverization process by freezing-thawing method, the refrigeration storage at $4^{\circ}C$ maximized gelling between sericin molecules, which increased 10% of recovery ratio from sericin concentration solution that using ultrafiltration procedure. In physicochemical properties of sericin/chitosan blended films, the maximum load of chitosan (6.7kgf) had higher than that of sericin (1.2kgf), and the elongation of sericin and chitosan had 96% and 34%, respectively. Also FT-IR analysis of sericin/chitosan blended films showed that both sericin and chitosan films had amide I peak (N-H bond) in $1,521cm^{-1}$ and amide II peak (C=O bond) in $1,630cm^{-1}$. In addition, it could confirm compatibility between both materials as indicated by the decrease in the amide I peak's absorption value as chitosan content increases.

An Experimental Study on Freezing Behavior of NaCl and Heavy Metal Aqueous Solution Using Freeze Concentration Method (동결농축법을 이용한 염수 및 중금속 수용액의 동결거동에 관한 실험 연구)

  • Kim, Jung-Sik;Lim, Seung-Taek;Oh, Cheol
    • Journal of Navigation and Port Research
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    • v.37 no.2
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    • pp.129-135
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    • 2013
  • Recently, waste water treatment system is developed in small and middle size to get more economic advantage. Freeze concentration system has high thermodynamic efficiency and low energy consumption, can re-use purified water and cold energy obtained from ice. This study was experimentally performed to investigate pollution containment in frozen layer by cooling wall temperature, air-bubble flow methods, initial ice-lining thickness of frozen layer in NaCl aqueous solution and the representative heavy metals, Pb and Cr aqueous solution. As the result, a decrease in the cooling wall temperature bring a higher growth rate of ice front and the more solute was involved in frozen layer. The method to inject directly air-bubble into ice-liquid interface through ring shape nozzle gave high purity of ice compared to indirect method. Ice lining in 5mm thickness resulted in frozen layer with higher purity than 1mm thickness.

Effect of Cryoprotectant Concentration and Equilibration Time on Volume Change and In Vitro Development of Intact and Bisected Mouse Embryos following Rapid Freezing (동결보호제의 농도와 평형시간이 생쥐의 정상배 및 분할배의 용적 변화와 체외 발달에 미치는 영향)

  • 이은봉;공일근;강대진;박충생
    • Korean Journal of Animal Reproduction
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    • v.16 no.1
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    • pp.47-53
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    • 1992
  • This study was carried out to investage the effect of cryoprotectant concentration and equilibration time on volume change and in vitro development of intact and bisected mouse embryos by rapid freezing. When compacted morulae were rapidly frozen in 3.0 to 4.0 glycerol or DMSO with 0.25M sucrose solution, the superior(P<0.05) post-thaw survival rate was obtained at the glycerol concentration of 4.0M(89.4%) than 3.0M(71.4%) or 5.0M(42.4%), but at the DMSO concentration of 3.0M(84.5%) than 4.0M(51.1%) or 5.0M(0.0%). The optimal equilibraton time for rapid freezing of ZP-free or bisected morulae in 4.0M glycerol with 0.25M sucrose was found tobe 3 minutes. The minimal volume of compacted morulaewhich corresponded with 61 to 62% of pre-equilibrated embryo volume was obtained from equilibration for 3 minutes in both 3.0 and 4.0M glycerol solutions with 0.25M sucrose.

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Short Term Storage and Cryopreservation of Trumpet Shell Charonia sauliae Sperm

  • Kang, Kyoung-Ho;Seon, Seung-Chun;Zhou, Bin
    • The Korean Journal of Malacology
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    • v.24 no.1
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    • pp.51-57
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    • 2008
  • With the purpose to estimate the possibility of short-term storage and cryopreservation for sperm of Charonia sauliae, which is a potential preparation for its artificial reproduction and further research, in this study, protocols for short-term storage and cryopreservation of trumpet shell sperm was optimized. The effects of different immobilizing solutions, dilution ratios were estimated for short-term storage. And the effects of different cryoprotectant extenders and freezing rates were estimated for cryopreservation in terms of motility and survival of sperm. The results indicated that the artificial sea water of 350 mOsmol/kg is a better immobilizing solution and sperm which was diluted at a ratio of 1:1 (v/v) had higher motility and survival rate during short-term storage. The effect of 5% dimethyl sulfoxide was significantly better than those of other cryoprotectant extenders. And a freezing rate of $-20^{\circ}C\;min^{-1}$ showed better effect than other freezing rates. In conclusion, this study optimized some key factors of the short-term and cryopreservation of C. sauliae sperm, which can provide valuable data for germ-plasm conservation and artificial propagation of C. sauliae.

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Basic Studies in Improvement of Freeze Concentration -(I) Measurements of Physical Properties for Concentrated Solution- (동결농축(凍結濃縮)의 개선(改善)을 위한 기초적(基礎的) 연구(硏究) -I. 농축시액(濃縮試液)의 물성측정(物性測定)-)

  • Kong, Jai-Yul
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.14 no.4
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    • pp.353-358
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    • 1985
  • Three kinds of aqueous solution of tobacco extracts are used as a new experimental material. It is measured how the operating condition, freezing point, viscosity as fundamental properties have the relation to concentration and temperature of the solution. The results of this study are obtained as follows. 1) The freezing point of the solution $(t_m)$ is presented; $t_m=-{\frac{18.6X}{170-{\frac{X}{100}}(170+18)}}$ 2) The correlation of the viscosity, the temperature and the concentration of the solution is followed; $log_{10{\mu}}={\frac{1585}{T}}+2.11{\frac{X}{100-X}}-5.50$ 3) The ice crystals whose circumference is a toothed wheel are made from high concentrated solution, and the thick plate shaped ones are done from the low concentrated solution.

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A Real Time Measurement of Ice Concentration of Ice Slurry in Pipe (배관내 흐르는 아이스슬러리의 실시간 얼음분율 측정)

  • Jung, Hae-Won;Peck, Jong-Hyeon;Kim, Yong-Chan;Kang, Chae-Dong;Hong, Hi-Ki
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.19 no.8
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    • pp.599-606
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    • 2007
  • An experimental study was performed to measure a ice concentration of ice slurry flowing in a pipe in a real time. In the present paper, we suggested a measuring method by a refractive index and compared it to other methods by a freezing point and a density. To measure the refractive index of the solution, ice particles in the ice slurry should be completely removed and a hydro-cyclone was introduced instead of a mesh. The measuring method through the refractive index coincided with the density method using the real-time solution density within ${\pm}5%$ error range, having the error range less than the other two methods. In the other hand, the measuring method through the density has a good resolution, but the result using the initial density of the solution was different more than 10% error from that using the real-time density. And it has an error range 1.5 times greater than the method through the refractive index.

Phase Relation Study Based on the Pyroelectric Properties and Relaxation Phenomena in $Pb(Mg _{1/3}Nb_{2/3})O_3-PbTiO_3$ Solid Solution System (초전특성 및 유전완화 거동을 통한 $Pb(Mg _{1/3}Nb_{2/3})O_3-PbTiO_3$ 고용계의 상평형 관계 연구)

  • 박재환;김병국;박재관
    • Korean Journal of Crystallography
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    • v.13 no.3_4
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    • pp.172-176
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    • 2002
  • Pyroelectric properties and relaxation phenomena in Pb(Mg /sub 1/3/Nb/sub 2/3/)O₃-PbTiO₃ solid solution system were studied to establish the phase relation of the solid solution system. The dielectric constants and the pyroelectric coefficients of (1-x)PMN-xPT (x = 0.1∼0.4) system were investigated in the phase transition temperature range of -40°C∼200°C. The freezing temperature was calculated by fitting the experimental data with the Vogel-Fulcher relation. With all the experimental data, a modified phase diagram of the (1-x)PMN-xPT system was suggested.