• Polymer(Korea)
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• v.29 no.1
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• pp.8-13
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• 2005

Polystyrene (PS) particles containing the phase change material (PCM) were synthesized by miniemulsion polymerization. The polymer particles prepared with different parameters were investigated in terms of average particle size, particle distribution, and latent heat storage of encapsulated paraffin wax (PW) as PCM. The morphology and particle features of PS particles were analyzed by scanning electron microscope and particle size analyzer, respectively. As a result, the diameters of PS particles were adjusted with manufacturing conditions. The stable and spherical PS particles of nanosize were obtained by miniemulsion polymerization, which could be attributed to the prevention of Ostwald ripening by cosurfactant. Thermal properties of PS particle containing PCM were studied by differential scanning calorimetry. From DSC freeze-thaw cycle, PCM coated with PS exhibited the thermal energy storage and release behaviors, and the latent heat was found to be a maximum 145 J/g. It was noted that PS particles containing PCM showed a good potential as a thermal energy storage medium.

• Journal of the Architectural Institute of Korea Structure & Construction
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• v.35 no.9
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• pp.199-206
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• 2019

Experimental study on the durability characteristics to examine the feasibility of concrete with high water-tightness and self-healing performance to minimize maintenance of concrete for artificial ground is as follows. 1) When blending agent, swelling agents, and curing accelerator were added on the ternary system cement with blast-furnace slag fine particles and fly ash to give a self-healing property, higher blending strengths by 82% at design standard strength of 24MPa and by 74% at design strength of 30MPa, respectively could be obtained. 2) The permeability test for the specimens having high water-tightness and no shrinkage showed that the permeability was reduced at maximum of 98%. However, the permeability was decreased as the design strength was increased, showing the reduction rate of 87% at the design strength of 50MPa. 3) The depth of carbonation of blast-furnace slag and fly ash was increased in all the specimens compared with those of OPC only. However, as the material age was increased, carbonation penetration depth was decreased compared with the reference blend. 4) Compared with the reference blending using only OPC, the freeze-thaw resistance was higher in the case of blending with 40% of blast-furnace slag and 10% of fly ash at the design standard strength of 50MPa. In addition, the freeze-thaw resistance in general was superior in the design standard strength of 50MPa with the lower water-binder ratio (W/B) as compared with the design standard strength of 24MPa and 30MPa with the high water-binder ratios.

• Journal of the Korea institute for structural maintenance and inspection
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• v.27 no.4
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• pp.78-85
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• 2023

In this study, synthetic fibers were applied to reduce shrinkage cracks that may occur in mortar produced by 3D printer. We used a biopolymer in powder form made from cactus stem (CS) as an admixture. The material properties of 3D printed mortar were experimentally evaluated. Replacing methylcellulose(MC) with 10% CS increases compressive strength by 9.84-23.92% regardless of the casting method. In addition, regardless of the casting method, shrinkage change, freeze-thaw resistance, and crack resistance are more effective than Plain. Incorporation of CS increases the polysaccharide macromolecular structure and improves durability. Mortars reinforced with synthetic fibers do not affect compressive strength and freeze-thaw. It is also effective for shrink deformation and crack resistance. Incorporating CS and fibers from 3D-printed mortar was found to be effective for durability and crack resistance.

• Journal of Microbiology
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• v.45 no.6
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• pp.510-514
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• 2007

Twenty-five bacterial strains that secrete mucous materials were isolated from sediment obtained from King George Island, Antarctica. Seven of these strains proved capable of producing cryoprotective exopolysaccharides. The strain KOPRI 21653 was selected for the further study of an anti-ice-nucleating polysaccharide (ANP), which originated from a polar region. KOPRI 21653 was identified as Pseudoalteromonas arctica as the result of 16S rRNA analysis. The exopolysaccharide, P-21653, was purified completely from the KOPRI 21653 cell culture via column chromatography and protease treatment. The principal sugar components of P-21653 were determined to be galactose and glucose, at a ratio of 1:1.5, via GC-MS analysis. The cryoprotective activity of P-21653 was characterized via an E. coli viability test. In the presence of 0.1% (w/v) P-21653, the survival ratio of E. coli cells was as high as 82.6% over three repeated freeze-thaw cycles. The survival ratio decreased drastically to 71.5 and 48.1 %, respectively, in five and seven repeated cycle conditions; however, the survival ratios were greater over three (96.6-92.1%) to seven (100.5-91.6%) freeze-thaw cycles in the presence of 0.5 and 1.0% (w/v) P-21653. In addition, at much lower concentrations (0.1-1.0%), P-21653 resulted in survival ratios (83.1-98.4%) similar to those of two commercially available cryoprotectants ($V_{EG}$ plus X-1000, 92.9% and $V_{M3}$, 95.3%), which were utilized at the recommended concentrations (90%). The biochemical characteristics of exopolysaccharide P-21653 reflect that this compound may be developed as a useful cryoprotectant for use in medical applications and in the food industry.

• International Journal of Highway Engineering
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• v.17 no.4
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• pp.77-87
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• 2015

PURPOSES: It is theoretically well known all over the world, that porous hot mixed asphalt (HMA) with hydrated Lime improves moisture and rutting resistance, and reduces pothole occurrence frequency, as well as the life cycle cost (LCC). METHODS : Addictive in the two different formations of the liquid anti-stripping Agent and powder Hydrated-Lime was applied in this investigation in order to obtain relatively clear results according to their types and conditions. Firstly, the moisture conditions were set, and applied to the porous HMA mixtures with hydrated lime (anti-stripping agent). Next, it was followed by a non-destructive test with the application of three freeze-thaw cycles, which were individually carried out thrice to compare the results of the dynamic moduli. Lastly, the hydrated lime effect related to moisture sensibility to porous HMA has been verified through the analysis of the modulus results regarding the change rate of dynamic modulus per n-cycle. RESULTS: It is clear from this investigation, that the dynamic modulus is inversely proportional to the change in temperature, as the graph representing the rigidity of the thermorheologically simple (TRS) material showed gradual decline of the dynamic modulus with the increase in temperature. CONCLUSIONS: The porous HMA mixture with the anti-stripping agent (hydrated Lime) has been found to be more moisture resistant to freezing and thawing than the normal porous HMA mixture. It is clear that the hydrated lime helps the HMA mixture to improve its fatigue resistance.

• Journal of the Korea Concrete Institute
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• v.19 no.6
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• pp.701-706
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• 2007

This study evaluated the durability of high-performance shotcrete mixed in the proper proportions using alkali-free and cement mineral accelerators as a permanent support that maintains its strength for the long term. Durability tests were performed the chloride permeability, repeated freezing and thawing, accelerated carbonation, and the effects of salt environments. Test results showed that all the shotcrete mixes included silica fume had low permeability. In addition, after 300 freeze/thaw cycles, the shotcrete mix had excellent freeze/thaw resistance more than the 85% relative dynamic modulus of elasticity. The accelerated carbonation test results were no effect of accelerator type but, the depth of carbonation was greater in the shotcrete mix containing silica fume. No damage was seen in a salt environments. Therefore, the high performance shotcrete mix proportions used in this study showed excellent durability.

• International Journal of Highway Engineering
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• v.17 no.2
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• pp.1-11
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• 2015

PURPOSES : This study set out to investigate the fundamental properties of alkali-activated concrete (AAC) using modified slag as the pavement maintenance material. METHODS: The material properties of modified slag based alkali-activated concrete (MSAAC) were analyzed and evaluated against those of alkali-activated slag concrete (AASC). Several mix formulations were considered, including one MSACC and four AASCs. The main variables considered in the study were slump, air content, compressive strength, rapid chloride permeability test, scaling resistance, freeze-thaw test, XRD, SEM, and EDS. RESULTS: MSAAC exhibits a compressive strength in excess of 21 MPa six hours after curing. Also, the charge passed of the MSACC was found to be less than 2000 coulombs after seven days and about 1000 coulombs after 28 days. The weight loss determined from a scaling test did not exceed $1kg/cm^2$ in the case of the MSACC, but that of the AASCs had already exceeded $1kg/cm^2$ at the 10th cycle. Based on the results of the freeze-thaw test, the relative dynamic modulus of every mix was found to be in excess of 90%. An energy dispersive spectroscopy(EDS) analysis found that the weight rate percentage of the calcium and aluminum in the MSAAC mix is twice that of the AASC mixes. CONCLUSIONS : It was found that the MSAAC mix exhibits significantly better performance than AASC mixes, based on various fundamental properties.

• Journal of Korea Soil Environment Society
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• v.1 no.1
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• pp.103-109
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• 1996

The cover liners at municipal and hazardous waste landfill is not emphasized as much as the bottom liners. However, one of the most effective reason of landfill destroy is the cover liner failure. The cover system at municipal and hazardous waste landfill, 1 perform the following functions, at minimum: promote surface runoff, impede infiltration, protect settlement in the landfill, and provide a buffer from surface exposure of the waste. This research was to expand the existing knowledge base of landfill cover liner behavior during period of freeze/thaw Also, the great Lysimeter was built in the laboratory to provide as much as same condition with the field and three designs were simulated by actual cover materials. The result of simulation indicated the clay was effected by freezing/thawing. The degradation of cover liners in the frost penetration affects the physical, engineering properties of clay. these factors may consider to design and construct of the landfill. This paper provides the description of testing cover liners, experimental results and a discussion of the results of the simulation.

• Proceedings of the Korea Concrete Institute Conference
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• 2008.04a
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• pp.529-532
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• 2008

Domestic area of most be happened chloride deicer damage. Because daily mean temperature is below 0$^{\circ}C$ from the area of domestic most. Use of deicing chemicals has been and will continue to be a major part of highway snow and ice control methods. Chloride-containing chemicals such as calcium chloride or rock salt are main deicers for the road. Extensive use of chloride deicers is, however, not only the source of substantial cost penalties due to their corrosive action and ability to deterioration roadway surface materials but also the source of environmental damages. Particularly, it has been recognized that chlorides present in deicing agents can significantly increase concrete surface scaling. In severe cases, scaling can result in dislodgement of coarse aggregate. This research estimates that pH and test of specific pollutants, dynamic modulus of elasticity for freeze-thaw test of concrete were higher than those NaCl, $CaCl_2$, and NaCl+$CaCl_2$(7:3, w/w), also weight losses for scaling test of concrete were much lower than those of NaCl, $CaCl_2$, and NaCl+$CaCl_2$(7:3, w/w).

• Resources Recycling
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• v.15 no.4 s.72
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• pp.52-59
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• 2006

The purpose of this study was to evaluate the effects of ground granulated blast-furnace slag on strength development and durability of ordinary portland cement concrete (OPC) with steam curing types. Main experimental variables were slag contents(0%, 10%, 30%, 50%, 70%) and curing types (standard, accelerated curing). It were performed to check the basic properties of concretes that compressive strength, rapid chloride ion permeability and chemical resistance. From the result, we have found that increasing the amount of blast-furnace slag produced concrete with increased compressive strength and permeability resistance. Rapid freezing-thawing test showed that they were good enough to protect the concrete structures and to carry out cyclic freezing and thawing. The freeze-thaw resistance of blast-furnace slag produced concretes maintained above 90% of relative dynamic modulus after 300 freezing-thawing cycles. Increasing the amount of blast-furnace slag produced concretes with increased chemical resistance.