• 제목/요약/키워드: Freeze and thaw

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Manufacturing of Ultra-light Ceramsite from Slate Wastes in Shangri-la, China

  • Li, Zhen;Zhang, Haodong;Zhao, Pengshan;He, Xiaoyun;Duan, Xiaowei
    • Journal of the Korean Ceramic Society
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    • v.55 no.1
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    • pp.36-43
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    • 2018
  • The physical and chemical analyses of mineral waste such as moisture content, water absorption, freezing-thawing resisting sexual, chemical composition and crystal structure were investigated. In the technological process of crushing, screening, molding, drying, preheating, sintering and cooling, many parameters were changed to eliminate the influence of freeze thaw stability and the ball billets were processed into slate ceramsites eventually. Adopting orthogonal experiment and range analysis, the optimal technology parameters were confirmed as preheating temperature of $300^{\circ}C$ for 25 minutes and sintering temperature of $1230^{\circ}C$ for 20 minutes. Slate wastes in Shangri-la could foam and expand without any additive. The ultra-light ceramsite could be directly used as building aggregate, since the analysis results of its leaching toxicity were eligible. Besides, effects of sintering temperature on physical property and crystal phase were also explored in this study.

Assessing the long-term durability and degradation of rocks under freezing-thawing cycles

  • Seyed Zanyar Seyed Mousavi;Mohammad Rezaei
    • Geomechanics and Engineering
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    • v.34 no.1
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    • pp.51-67
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    • 2023
  • In this research, the degradation rate of physical properties of the Angouran pit bedrock (calc-schist) is first investigated under the specific numbers of freeze-thaw (F-T) cycles. Then, the durability of calc-schist specimens against the F-T cycle number (N) is examined considering the mechanical parameters, and using the decay function and half-time techniques. For this purpose, point load strength (IS(50)), second durability index (Id2), Brazilian tensile strength (BTS), and compressive (VP) and shear (VS) wave velocities of calc-schist specimens are measured after 0, 7, 15, 40, and 75 N. For comparing the degradation rate of mechanical properties of available rock types on the Angouran mine walls, these tests are also carried out on the limestone and amphibolite schist specimens beside the calc-schist. According to test results, the exponential regression models are developed between the mechanical parameters of rock specimen's and N variable. Also, the long-term durability of each rock type versus N is studied using the decay function and half-time techniques. Results indicated that the degradation rate differs for the above rock types in which amphibolite schist and calc-schist specimens have the highest and least resistance against the N, respectively. The obtained results from this study can play a key role in the optimal design of the mine's final walls.

CLSM [Confocal Laser Scanning Microscope] Observation of the Surface Roughness of Pressurized Rock Samples During Freeze/Thaw Cycling

  • Kim, Hye-jin;Choi, Junghae;Chae, Byung-gon;Kim, Gyo-won
    • The Journal of Engineering Geology
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    • v.25 no.2
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    • pp.165-178
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    • 2015
  • Physical and chemical weathering degrades rock, affecting its structural properties and thus the stability of stone buildings or other structures. Confocal laser scan microscopy (CLSM) is used here to observe temporal changes in the surface roughness of rock samples under simulated accelerated weathering. Samples were pressurized to 50, 55, or 70 MPa using a pressure frame, and subjected to freeze/thaw cycling controlled by a thermostat. The temperature was cycled from -20℃ to 40℃ and back. After each 20 cycles, CLSM was used to assess the change in surface roughness, and roughness factors were calculated to quantify the progression of the surface condition over time. Variations in cross-section line-roughness parameters and surface-roughness parameters were analyzed for specific parts of the sample surfaces at 5× and 50× magnification. The result reveals that the highest and lowest values of the roughness factors are changed according to elapsed time. Freezing/thawing at high pressure caused larger changes in the roughness factor than at low pressure.

Effect of Acetylated Rice Starch on Rheological Properties of Surimi Sol and Gel

  • Jung, Young-Hwa;Kim, Won-Woo;Yoo, Byoung-Seung
    • Food Science and Biotechnology
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    • v.16 no.5
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    • pp.817-821
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    • 2007
  • The effect of acetylated rice (AR) starch at different concentrations (0, 4, 6, and 8%) on rheological properties of surimi sols and gels was studied. Dynamic frequency sweeps of surimi-AR starch sols at $10^{\circ}C$ showed that the magnitudes of storage moduli (G') decreased with an increase in starch concentration while those of tan ${\delta}$ increased, indicating that the effect of AR starch on the viscoelastic properties of surimi sols depended on starch concentration. In general, the G' thermograms of surimi sols showed the similar sol-gel transition pattern and they were also influenced by the addition of AR starch. The presence of AR starch in the surimi gel system reduced the gel strength and expressible moisture content (EMC). Surimi-AR starch gels showed better freeze-thaw stability compared to the control (0% starch concentration). The effect of AR starch on the rheological properties of surimi sols and gels appeared to be related to the swelling ability of starch granules in the presence of limited water available for starch.

Optimal Conditions for the Distribution of Cryoprotectant into the Intact Fish Muscle of Oncorhynchus mykiss during Freeze/Thaw Cycling

  • Kong Chang Suk;Park Kun Young
    • Fisheries and Aquatic Sciences
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    • v.8 no.1
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    • pp.10-16
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    • 2005
  • Conditions for sufficient and rapid distribution of a cryoprotectant (sorbitol solution) into intact fish muscle (Oncorhynchus mykiss) were studied as changing in the residual Ca2+ ATPase activity during freeze/thaw cycling. Chunks of the fish muscle were immersed in 4 concentrations of sorbitol solutions ($20\%$, $30\%$, $45\%$, and $60\%$) by a shaker mechanism at 5$^${circ}C. Whole immersion samples (W) showed a higher value of the residual Ca2+ ATPase activity than those in the untreated controls (C), except in the treated controls (TC), while less effect of immersion concentration could be found. Comparing the extent of penetration of sorbitol into the surface layer to inner layer of immersed fish chunks, outer portion samples achieved excellent cryoprotection with $100\%$ of the residual ATPase activity values or more. For the inner portion samples, $30\%$ and $45\%$ sorbitol solution treatments indicated a higher ATPase activity than $60\%$ treatment. At high concentrations, mass transfer rates during osmotic dehydration might berapid and it causes faster surface drying by dewatering at surface solute layer. Periodically immersed and relaxed samples, W (5-3-1), led to good cryoprotection effect: W (5-3-1) indicated high residual Ca2+ ATPase activity values and the residual ATPase activity values excess $100\%$ in immersion of $30\%$ and $45\%$ sorbitol solutions.

Concrete bridge deck deterioration model using belief networks

  • Njardardottir, Hrodny;McCabe, Brenda;Thomas, Michael D.A.
    • Computers and Concrete
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    • v.2 no.6
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    • pp.439-454
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    • 2005
  • When deterioration of concrete is observed in a structure, it is highly desirable to determine the cause of such deterioration. Only by understanding the cause can an appropriate repair strategy be implemented to address both the cause and the symptom. In colder climates, bridge deck deterioration is often caused by chlorides from de-icing salts, which penetrate the concrete and depassivate the embedded reinforcement, causing corrosion. Bridge decks can also suffer from other deterioration mechanisms, such as alkali-silica reaction, freeze-thaw, and shrinkage. There is a need for a comprehensive and integrative system to help with the inspection and evaluation of concrete bridge deck deterioration before decisions are made on the best way to repair it. The purpose of this research was to develop a model to help with the diagnosis of concrete bridge deck deterioration that integrates the symptoms observed during an inspection, various deterioration mechanisms, and the probability of their occurrence given the available data. The model displays the diagnosis result as the probability that one of four deterioration mechanisms, namely shrinkage, corrosion of reinforcement, freeze-thaw and alkali-silica reaction, is at fault. Sensitivity analysis was performed to determine which probabilities in the model require refinement. Two case studies are included in this investigation.

Temperature and humidity effects on behavior of grouts

  • Farzampour, Alireza
    • Advances in concrete construction
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    • v.5 no.6
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    • pp.659-669
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    • 2017
  • Grouts compared to other material sources, could be highly sensitive to cold weather conditions, especially when the compressive strength is the matter of concern. Grout as one the substantial residential building material used in retaining walls, rebar fixation, sidewalks is in need of deeper investigation, especially in extreme weather condition. In this article, compressive strength development of four different commercial grouts at three temperatures and two humidity rates are evaluated. This experiment is aimed to assess the grout strength development over time and overall compressive strength when the material is cast at low temperatures. Results represent that reducing the curing temperature about 15 degrees could result in 20% reduction in ultimate strength; however, decreasing the humidity percentage by 50% could lead to 10% reduction in ultimate strength. The maturity test results represented the effect of various temperatures and humidity rates on maturity of the grouts. Additionally, the freeze-thaw cycle's effect on the grouts is conducted to investigate the durability factor. The results show that the lower temperatures could be significantly influential on the behavior of grouts compared to lower humidity rates. It is indicated that the maturity test could not be valid and precise in harsh temperature conditions.

Reconstitution of Sarcoplasmic Reticulum-$Ca^{2+}$ Release Channels into Phospholipid Vesicles : Investigation of Conditions for Functional Reconstitution

  • Yang, In-Sik;Lee, Hee-Bong
    • BMB Reports
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    • v.28 no.2
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    • pp.129-137
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    • 1995
  • The ryanodine-receptor $Ca^{2+}$ release channel protein in the sarcoplasmic reticulum membrane of rabbit skeletal muscle plays an important role in muscle exitation-contraction (E-C) coupling. Various types of detergents were tested, including Chaps, cholate, octylglucoside, Zwittergents, Mega-9, Lubrol PX, and Triton X-100 for solubilization of this protein. Among these, Chaps and Triton X-100 were found to optionally solubilize the channel complex. Optimum conditions for this solubilization were pH 7.4 with a salt concentration of 1 M. The addition of phospholipid in the solubilization step helped in stabilizing the protein. The purification of the receptor was performed using sucrose density gradient centrifugation. Various methods [dilution, freeze-thaw, adsorption (Biobeads), and dialysis] were investigated to incorporate the Chaps-solubilized and purified $Ca^{2+}$ release channel protein into liposomes made from different types of phospholipids. Of these, a combined method consisting of a dialysis, freeze-thaw and sonication steps yielded the best results. Reconstituted vesicles produced by this method with 95% phosphatidylcholine (from soybean extract) had good function.

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Long Term Stability of Slopes Excavated in Weathered Granite Rock Masses Subjected to Extreme Climatic Conditions (극한 기후 조건하에서 풍화된 화강암반 절취사면에 대한 장기적 안정성 연구)

  • Yang, Kwang-Yong;Park, Yeon-Jun;You, Kwang-Ho;Woo, Ik;Park, Chan
    • Proceedings of the Korean Geotechical Society Conference
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    • 2003.03a
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    • pp.655-662
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    • 2003
  • Slope stability is an important issue ill civil engineering works or in open pit mines where both economy and efficiency is required. These are the long-term stability problems which depend on the change of physical properties under a certain weather condition. These can also result in progress of weathering which can change mechanical or hydro-geological properties of rock mass considerably. In this study, weathering in nature was simulated by freeze-thaw test and Soxhlet test which represent mechanical and chemical weathering respectively. Measured were elastic wave velocities, absorption rate, volume change. Uniaxial compression strengths before and after the weathering tests were also measured. The change in weight and volume of the specimens were not clearly related to the weathering process, but P, S wave velocities were clearly decreased as weathering progresses. For some class of rocks, P-wave velocity was increased probably because of the saturation due to improved connectivity of the pre-existing pores. Based on the test results, stability of the slopes were analyzed using FLAC$\^$2D/. Due to the reduced strength parameters, the factors of safety were decreased for the selected sites.

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