• Title/Summary/Keyword: Free silica

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Study of Water Diffusion in PE-SiO2 Nanocomposites by Dielectric Spectroscopy

  • Couderc, Hugues;David, Eric;Frechette, Michel
    • Transactions on Electrical and Electronic Materials
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    • v.15 no.6
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    • pp.291-296
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    • 2014
  • In recent years, researchers have extensively investigated polymers filled with inorganic nanoparticles because these materials present improved physical properties relative to those of conventional unfilled polymers. Oxides, silica in particular, are the most commonly used inorganic particles because they possess good properties and can be fabricated at a low cost. However, oxides are hydrophilic in nature, and this leads to the presence of water at the interface between the nanoparticles and the polymer matrix. Due to the predominance of particle-matrix interfaces in nanocomposites, the presence of water at the interlayer region can be problematic. Moreover, the hydrophobic nature of most polymers, particularly for polyolefins such as polyethylene, may make it difficult to remove this interfacial water. In this paper, as-received and moistened samples of agglomerated nanosilica/polyethylene were dried using an isothermal treatment at $60^{\circ}C$, and the efficacy of this treatment was studied using dielectric spectroscopy. The Maxwell-Wagner-Sillars relaxation peaks were observed to shift to lower frequencies by three decades, and this was linked to a modification of the water content, due to drying, at the interfaces between silica and polyethylene and at the interfaces within the nanosilica agglomerates. The evolution of the extracted retardation time is explained by the nanosilica hydrophily and the free volume introduced by the nanoparticles.

Studies on Xanthine Oxidase Inhibitor Produced from Aspergillus sp. F184 (Aspergillus sp. F184가 생산하는 Xanthine Oxidase 저해제에 관한 연구)

  • 박시형;윤상웅;박정민;옥승호;유주현;배동훈
    • Microbiology and Biotechnology Letters
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    • v.28 no.2
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    • pp.92-96
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    • 2000
  • Aspergillus sp. F184 was isolated from soil for the development of new xanthine oxidase inhibitor. This xanthine oxidase inhibitor was sequentially purified by filtration, HP-20 adsorption column chromatography, ethyl acetate extraction, silica gel column chromatography and crystallization, and was named as YUX 104. YUX 104 was identified to be 5,6-epoxy-2-hydroxy-3-methyl-2-cyclohexene-1,4-dione(terreic acid) by NMR and mass spectroscopic sudies.

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An experimental study on performance of concrete with constituent materials of shotcrete (숏크리트 구성 재료에 따른 콘크리트 성능에 관한 실험적 연구)

  • Kim, Sang-Myung;Shin, Jin-Yong;Ma, Sang-Jun;Nam, Kwan-Woo;Kim, Ki-Ho
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.10 no.1
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    • pp.59-68
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    • 2008
  • The experiment was carried out to investigate the influence of coarse aggregate, admixture, and accelerator on the properties of concrete. As the maximum size of coarse aggregate decreased from 13 mm to 8 mm, fluidity of fresh concrete declined but compressive strength and dynamic modulus of elasticity of hardened concrete increased remarkably. The mechanical properties of concrete substituted silica fume to the plain concrete improved, the compressive strength of that substituted blast furnace slag increased slightly. The hydration reaction and compressive strength of specimen with sodium luminate type accelerator were high at initial, but specimen with alkali free type accelerator improved largely in 28 days.

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Effects of nonionic surfactants on the partitioning of naphthalene in soil/water system (토양과 수용액상에서 나프탈렌의 분배에 관한 비이온성 계면활성제의 영향)

  • 하동현;고석오;신원식;김영훈;전영웅;송동익
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2002.09a
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    • pp.283-286
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    • 2002
  • Solubilization and partitioning of naphthalene was investigated in an aqueous system containing soils and surfactants. The environmental behavior of polycyclic aromatic hydrocarbons(PAHs) was mainly governed by their solubility and partitioning properties on soil media in a subsurface system. In surfactant-enhanced remediation systems, surfactants might be an additional variable. a natural soil ,silica and kaolinite were tested as soil media. two nonionic surfactants, Triton X-100 and Hydropropy1-$\beta$-cyclodextrin (HPCD) were employed for naphthalene solubilization. Naphthalene showed linear on natural soil while non-linear sorption on silica and kaolinite. Soils have higher sorption capacity for Triton X-100 than HPCD indicating Triton X-100 formed ad-micelle on the soil surface. Desorption study showed a hysterysis and reversible desorption. The partitioning coefficient(K$_{D}$) of naphthalene was increased as the concentration of surfactant was increased. (below CMC), however, the coefficient was decreased above CMC. This indicates that naphthalene is partitioned into the micelles and the partition occurs competitively on both ad-micelle and free micelles as surfactant concentration increases. Therefore, the target compounds to be dissolved into aqueous phase in a surfactant enhanced remediation system might be highly partitioned on to the ad-micelle resulting in an adverse effect rather increased solubilization would be achieved.d.

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Aging effect of annealed oxide CMP slurry (열처리된 산화막 CMP 슬러리의 노화 현상)

  • Lee, Woo-Sun;Shin, Jae-Wook;Choi, Kwon-Woo;Ko, Pil-Ju;Seo, Yong-Jin
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.07a
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    • pp.335-338
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    • 2003
  • Chemical mechanical polishing (CMP) process has been widely used to planarize dielectric layers, which can be applied to the integrated circuits for sub-micron technology. Despite the increased use of CMP process, it is difficult to accomplish the global planarization of in the defect-free inter-layer dielectrics (ILD). Especially, defects such as micro-scratch lead to severe circuit failure which affect yield. CMP slurries can contain particles exceeding $1\;{\mu}m$ in size, which could cause micro-scratch on the wafer surface. In this paper, we have studied aging effect the of CMP sin as a function of particle size. We prepared and compared the self-developed silica slurry by adding of abrasives before and after annealing. As our preliminary experiment results, we could be obtained the relatively stable slurry characteristics comparable to original silica slurry in the slurry aging effect.

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Characteristic of the femtosecond laser machining in glass (펨토초 레이어 기반 유리 내부가공 특성)

  • Yoo B.H.;Kim Y.M.;Cho S.H.;Chang W.S.;Kim J.G.;Whang K.H.;Lee D.J.
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2006.05a
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    • pp.239-240
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    • 2006
  • For longer than picosecond pulses, bulk damage inside defect-free dielectrics involves the heating and multiplication of spurious electrons by the incident laser beam and transfer of this energy to the lattice. The situation is quite different for femtosecond pulses which are shorter than the time scale for electron energy transfer to the lattice. Damage caused by these pulses is produced with smaller statistical uncertainty and is controllable on a microscopic scale. These properties can be exploited to produce laser devices such as arrays of damage dots for all optical memories with high data storage density or arrays of parallel grooves to form transmission gratings. In this work, we observed characteristic of the femtosecond laser machining in BK7 and fused silica.

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Aging Effect on CMP slurry (CMP 실리카 슬러리 입도분석특성)

  • Lee, Woo-Sun;Ko, Pil-Ju;Seo, Yong-Jin
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.08a
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    • pp.12-14
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    • 2003
  • As the integrated circuit device shrinks to the smaller dimension, the chemical mechanical polishing (CMP). process was required for the global planarization of inter-metal dielectric (IMD) layer with free-defect. However, as the IMD layer gets thinner, micro-scratches are becoming as major defects. Micro-scratches are generated by agglomerated slurry, solidified and attached slurry in pipe line of slurry supply system. It is well known that the presence of hard and larger size particles in the CMP slurries increases the defect density and surface roughness of the polished wafers. In this paper, we have studied. aging effect the of CMP slurry as a function of particle size. We prepared and compared the self-developed silica slurry by adding of abrasives before and after annealing. As our preliminary experiment results, we could be obtained the relatively stable slurry characteristics comparable to original silica slurry in the slurry aging effect.

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VOLATILE FLAVOR COMPONENTS OF FRESH GINSENG (수삼의 휘발성 향기 성분)

  • Kim Man-Wook;Choi Kang-Ju;Wee Jae-Joon
    • Proceedings of the Ginseng society Conference
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    • 1984.09a
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    • pp.185-190
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    • 1984
  • Volatile flavor components of fresh ginseng (Panax ginseng C.A. Meyer) were studied by a combination of SE-54 fused silica capillary gas chromatography and mass spectrometry. Steam distillate of fresh ginseng roots was extracted with oxygen-free diethylether and concentrated. This aroma concentrate was separated into neutral, acidic, phenolic, and basic fractions. The neutral fraction, containing over two hundred compounds, was aromatically the closest to fresh ginseng with the key-flavor components predominantly being monoterpenes and sesquiterpenes. The sesquiterpene compounds were identified as being azulenic, menthenic, and napthalenic with a mass of 204.

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CMP slurry aging effect by Particle Size analysis (입도 분석을 통한 CMP 슬러리 에이징 효과)

  • Shin, Jae-Wook;Lee, Woo-Sun;Choi, Kwon-Woo;Ko, Pil-Ju;Seo, Yong-Jin
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.05c
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    • pp.37-40
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    • 2003
  • As the integrated circuit device shrinks to the smaller dimension, the chemical mechanical polishing (CMP) process was required for the global planarization of inter-metal dielectric (IMD) layer with free-defect. However, as the IMD layer gets thinner, micro-scratches are becoming as major defects. Micro-scratches are generated by agglomerated slurry, solidified and attached slurry in pipe line of slurry supply system. It is well known that the presence of hard and larger size particles in the CMP slurries increases the defect density and surface roughness of the polished wafers. In this paper, we have studied aging effect the of CMP slurry as a function of particle size. We prepared and compared the self-developed silica slurry by adding of abrasives before and after annealing. As our preliminary experiment results, we could be obtained the relatively stable slurry characteristics comparable to original silica slurry in the slurry aging effect.

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Apple Virus Diagnosis Using Simplified RNA Extraction Method (사과바이러스 간편 진단을 위한 RNA추출법 개선)

  • Shin, Dong-Il;Park, Hee-Sung
    • Journal of agriculture & life science
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    • v.43 no.6
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    • pp.105-109
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    • 2009
  • Kyungsan nursery complex which has a vast area for the production of various species of fruit tree stocks is in a high demand of virus-free saplings. Apple tree stocks, the most important products, urgently need more rapid and reliable viral diagnosis. In this study, a bead beater was tested because of convenience in dealing with large number of samples. Also, industrial glass bead abrasive (0.4 mm in diameter) at very low cost was used in a disposable way. For bead beater-aided RNA extraction from apple stem tissues, the guanidine thiocyanate method was confirmed to be very reliable. Silca membrane filter tube in connection to vacuum filtering device was strongly suggested for simplifying RNA capture and washing steps. Apple virus detection was confirmed by RT-PCR.