• The Transactions of The Korean Institute of Electrical Engineers
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• v.60 no.4
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• pp.801-804
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• 2011

Electrical properties and microstructure were investigated on the effects of $MnO_2$ and the lead-free $(Na_{0.44}K_{0.52}Li_{0.04})(Nb_{0.83}Sb_{0.07}Ta_{0.1})O_3$ ceramics with the addition of $MnO_2$ were fabricated by a conventional mixed oxide method. A gradual change in the crystal and microstructure was observed with the increase of $MnO_2$ addition. For the NKN-LST-xmol%$MnO_2$ sintered at $1100^{\circ}C$, bulk density increased with the addition of $MnO_2$ and showed maximum value at addition 1.0mol% of $MnO_2$. Curie temperature of the NKN-LST ceramics slightly decreased with adding $MnO_2$. The dielectric constant, piezoelectric constant ($d_{33}$) and electromechanical coupling factor ($k_p$) increased below 0.25mol% of $MnO_2$ addition, which might be due to the increase in density. The high piezoelectric properties = 145 pC/N, electromechanical coupling factor = 0.421 and dielectric constant = 2883 were obtained for the NKN-LST-0.25mol%$MnO_2$ sintered at $1100^{\circ}C$ for 4h.

• Bulletin of the Korean Chemical Society
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• v.31 no.5
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• pp.1155-1158
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• 2010

Microwave-assisted Michael reaction between EMME and various amines such as diphenylamine, 4-methyl-N-phenylbenzenamine, N-phenylnaphthalen-1-amine, dihexylamine, diisopropylamine, and 4-nitrobenzenamine were described. Solvent-free conditions on alumina as solid support in the presence of $K_2CO_3$ catalysts gave moderate to good yields (55 - 93%) of diethylmalonate analogues having enamine moieties under focused microwave irradiation.

• BMB Reports
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• v.41 no.9
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• pp.635-639
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• 2008

Acrolein is a highly reactive by product of lipid peroxidation and individuals with neurodegenerative disorders have been shown to contain elevated concentrations of this molecule in the brain. In the present study, we examined the pattern of neurofilament-L (NF-L) modification elicited by acrolein. When NF-L was incubated with acrolein, protein aggregation occurred in a acrolein concentration-dependent manner. Exposure of NF-L to acrolein also led to the generation of protein carbonyl compounds. Through the addition of free radical scavengers we observed a significant decrease in acrolein-mediated NF-L aggregation. These results indicate that free radicals may be involved in the modification of NF-L by acrolein. In addition, dityrosine crosslink formation was observed in acrolein-mediated NF-L aggregates and these aggregates displayed thioflavin T reactivity, reminiscent of amyloid. This study suggests that acrolein-mediated NF-L aggregation might be closely related to oxidative reactions, thus these reactions may play a critical role in neuro-degenerative diseases.

• Journal of the Korean Society of Manufacturing Technology Engineers
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• v.21 no.5
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• pp.720-725
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• 2012

Sodium hypochlorite is used worldwide as a water disinfectant and in bleaching agent. Sodium hypochlorite applied to water initially undergoes hydrolysis to form free chlorine consisting of hypochlorous acid(HOCl) and hypochlorite ion($OCl^-$). For free chlorine determination, an electrochemical method is simple due to the electroactivity of free chlorine; it measures current and is free of most reagents. Amperometric free chlorine sensor has been developed with gold (Au)-based electrode. The 3-electrode free chlorine sensor whose working and counter electrodes were Pt exhibited excellent response to HClO at +400mV vs. Ag/AgCl/sat. KCl. In addition, the use of a pH error correction algorithm provided a reliable measurement of residual free chlorine in water sample without any pretreatment in the normal pH range(pH 6~8) of municipal water supply. The free chlorine sensor installed in on-line monitoring system could be used to continually monitor the level of residual free chlorine in real samples.

• The Journal of Asian Finance, Economics and Business
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• v.9 no.2
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• pp.15-27
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• 2022

The paper addresses the importance of redesigning strategies for resilient and sustainable regional economic development - by applying strategic approaches to free economic zones for the digital economy. The purpose of the paper is to provide a broad comparative perspective on developed versus developing country efforts to use free economic zone programs to enhance various economic and social objectives. First, the paper introduces the chronicle experiences of free economic zone programs in South Korea and mainland China - developed versus developing economies. The main results of the analysis indicate that (1) achieving the goals and objectives of free economic zones is challenging over time; (2) trying to upgrade the technical component, develop knowledge-based and eco-friendly new industries, or value-added to the economy through free economic zone policies is even challenging; and (3) incentives and other program-specific variables are highly context-specific and not structurally correlated with free economic zone performance. In addition, the paper shows that the initial conception of the role of free economic zones has undergone significant change as individual countries have tried to enhance the contributions and avoid damages from incorporating free economic zones into their development strategy respectively, over time.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.19 no.8
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• pp.717-723
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• 2006

Lead free $(Na_{0.5}K_{0.47}Cd_x)NbO_3$ ceramics (x=0.015-0.005) were prepared by the conventional mixed oxide route. The effects of CdO addition on the sintering, dielectric and piezoelectric properties of the samples were examined. The addition of CdO greatly enhanced the sinterability of ceramics and the sample has a lower dielectric loss. The $k_p\;and\;Q_m$ of the samples with 0.02 mol CdO addition are 0.35 and 125, respectively, The $(Na,K)NbO_3$ ceramics show a large degradation of $k_p$ due to the deliquescence when exposed to humidity, while the $(Na,K,Cd)NbO_3$ ceramics have no a significant degradation of it.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.28 no.2
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• pp.126-130
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• 2015

In this study, some materials are organized and experimented with variables to obtain the optimum mix proportion for the mechanical property of halogen free flame resistance compound with varying addition of nano clay. Tensile strength, density and stiffness are tested in the room temperature. In this study, unlike existing layered structure, nano clay with tabular structure is used and sufficient stiffness, strength, thermal stability and gas block capability can be achieved with small amount of addition. Tensile strength and elongation test show high rupture strength only in specimens with compatibilizing agents while density test shows average measurement in all the specimens except T-9. It was confirmed that the measurement value according to the additives in compatibilizing agent or in nano clay of hardness test represents similarly.

• Wind and Structures
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• v.13 no.1
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• pp.83-94
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• 2010

Wind tunnel measurements on T-shaped free-standing walls and inclined free-standing walls have been carried out. Mean net pressure coefficients have been derived and compared with previous research. It was observed that the high loads at the free ends are differently distributed than those derived from the pressure coefficients for free-standing walls in EN 1991-1-4. In addition net pressure coefficients based on extreme value analysis have been obtained. The lack of correlation of the wind induced pressures at windward and leeward side result in lower values for the net pressure coefficients when based on extreme value analysis. The results of this wind tunnel study have been included in Dutch guidelines for noise barriers.

• Transactions of Materials Processing
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• v.13 no.7
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• pp.614-622
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• 2004

A new approach for the automatic elimination of free edges in the finite element model for the analysis of sheet metal forming processes is presented. In general, the raw finite element model constructed from an automatic mesh generator is not well suited for the direct use in the downstream forming analysis due to the many free edges which requires tedious time consuming interactive graphic operations of the users. In the present study, a general method for the automatic elimination of free edges is proposed by introducing a CAD/CAE hybrid method. In the method a trimmed parametric surface is generated to fill the holes which are orginated from the free edges by using the one step elastic finite element analysis. In addition, mesh generation algorithm is suggested which can be used in the general trimmed surface. In order to verify the validity of the proposed method, various examples including actual automobile sheet metal parts are given and discussed.

• Bulletin of the Korean Chemical Society
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• v.28 no.7
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• pp.1167-1170
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• 2007

A simple and convenient method for the addition of TMSCN to carbonyl compounds is described. NbCl5 is found to possess a strong Lewis acid property to transform carbonyl compounds smoothly to the corresponding cyanosilylether in high yields (up to 99 %) in solvent- free conditions.