• Korean Journal of Metals and Materials
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• v.46 no.5
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• pp.296-303
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• 2008

Hydrogen permeation through dense palladium-based membranes has attracted the attention of many scientists largely due to their unmatched potential as hydrogen-selective membranes for membrane reactor applications. Although it is well known that the permeation mechanism of hydrogen through Pd involves various processes such as dissociative adsorption, transitions to and from the bulk Pd, diffusion within Pd, and recombinative desorption, it is still unclear which process mainly limits hydrogen permeation at a given temperature and hydrogen partial pressure. In this study, we report an all-electron density-functional theory study of hydrogen permeation through Pd membrane (using VASP code). Especially, we focus on the variation of the energy barrier of the penetration process from the surface to the bulk with hydrogen coverage, which means the large reduction of the fracture stress in the brittle crack propagation considering Griffith's criterion. It is also found that the penetration energy barrier from the surface to the bulk largely decreases so that it almost vanishes at the coverage 1.25, which means that the penetration process cannot be the rate determining process.

• Journal of the Korean Society of Manufacturing Process Engineers
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• v.20 no.3
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• pp.24-32
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• 2021

The size of container ships is increasing to increase the cargo loading capacity. However, container ships are limited in terms of the hull longitudinal strength. To overcome this limitation, brittle crack arrest steel can be used. This study was aimed at examining the influence of the heat input on the welding procedures of flux cored arc welding and submerged arc welding. In the experiment, the crack tip opening displacement test, which pertains to a parameter of fracture mechanics, was performed, and a 3-point bending tester was adopted. Based on the results, the crack measurement method was presented, and the stress expansion coefficient value for the pre-fatigue crack length was derived according to the heat input after the pre-cracking length was measured. It was noted that the heat input affected the crack tip opening displacement of brittle crack arrest steel.

• Journal of the Korean Society of Manufacturing Process Engineers
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• v.20 no.7
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• pp.8-14
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• 2021

Even welds that have passed non-destructive testing in the case of brittle crack arrest steel materials will actually have very fine weld defects. Based on studies showing that these defects adversely affect the structure if subjected to a certain period of load, the following conclusions were obtained by conducting CTOD tests on welding joints of high-strength BCA materials, structures comprising the upper decks of a large container vessel. First of all, the fatigue pre-cracking in the weld metal and heat affected areas was tested and the behavior was identified. Both parts of the welding joint are allowable range for the class regulations. In addition, CTOD results showed that the CTOD value in the heat affected area was more than 0.5 times higher than in the weld metal area.

• Corrosion Science and Technology
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• v.20 no.6
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• pp.466-474
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• 2021

A wet type scrubber for merchant vessel uses super austenitic stainless steels with pitting resistance equivalent number (PREN) of 40 or higher for operation in a harsh corrosive environment. However, it is expensive due to a high nickel content. Thus, electrochemical behavior and cavitation erosion characteristics of UNS S32750 as an alternative material were investigated. Microstructure analysis revealed fractions of ferritic and austenitic phases of 48% and 52%, respectively, confirming the existence of ferritic matrix and austenitic island. Potentiodynamic polarization test revealed damage at the interface of the two phases because of galvanic corrosion due to different chemical compositions of ferritic and austenitic phases. After a cavitation test, a compressive residual stress was formed on the material surface due to impact pressure of cavity. Surface hardness was improved by water cavitation peening effect. Hardness value was the highest at 30 ㎛ amplitude. Scanning electron microscopy revealed wave patterns due to plastic deformation caused by impact pressure of the cavity. The depth of surface damage increased with amplitude. Cavitation test revealed larger damage caused by erosion in the ferritic phase due to brittle fracture derived from different strain rate sensitivity index of FCC and BCC structures.

• Korean Journal of Materials Research
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• v.31 no.5
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• pp.255-263
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• 2021

P91 steel has been a highly researched material because of its applicability for high-temperature applications. Considerable efforts have been made to produce experimental creep data and develop models for creep life prediction. As creep tests are expensive and difficult to conduct, it is vital to develop authenticated empirical methods from experimental results that can be utilized for better understanding of creep behavior and can be incorporated into computational models for reliable prediction of creep life. In this research, a series of creep rupture tests are performed on the P91 specimens within a stress range of 155 MPa to 200 MPa and temperature range of 640 ℃ (913 K) to 675 ℃ (948 K). The microstructure, hardness, and fracture surfaces of the specimens are investigated. To analyze the results of the creep rupture tests at a macro level, a parameter called creep work density is derived. Then, the relationships between various creep parameters such as strain, strain rate, time to rupture, creep damage tolerance factor, and creep work density are investigated, and various empirical equations are obtained.

• Journal of the Korean Society of Safety
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• v.37 no.4
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• pp.11-19
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• 2022

This paper presents the effects of high temperature and water absorption on the mechanical behaviors of carbon-aramid fiber composites, specifically their strength, elastic modulus, and fracture. These composites are used in industrial structures because of their high specific strength and toughness. Carbon fiber composites are vulnerable to the impact force of external objects despite their excellent properties. Aramid fibers have high elongation and impact absorption capabilities. Accordingly, a hybrid composite with the complementary properties and capabilities of carbon and aramid fibers is fabricated. However, the exposure of aramid fiber to water or heat typically deteriorates its mechanical properties. In view of this, tensile and flexural tests were conducted on a twill woven carbon-aramid fiber hybrid composite to investigate the effects of high temperature and water absorption. Moreover, a multiscale analysis of the stress behavior of the composite's microstructure was implemented. The results show that the elastic modulus of composites subjected to high temperature and water absorption treatments decreased by approximately 22% and 34%, respectively, compared with that of the composite under normal conditions. The crack behavior of the composites was well identified under the specimen conditions.

• Corrosion Science and Technology
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• v.22 no.4
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• pp.273-286
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• 2023

Rebar is embedded in concrete to create reinforced concrete (RC). Rebar carries most of the tensile stress and gives compressively loaded concrete fracture resistance. However, embedded steel corrosion is a significant cause of concern for RC composite structures worldwide. It is one of the biggest threats to concrete structures' longevity. Due to environmental factors, concrete decays and reinforced concrete buildings fail. The type and surface arrangement of the rebar, the cement used in the mortar, the dosing frequency of the concrete, its penetrability, gaps and cracks, humidity, and, most importantly, pollutants and aggressive species all affect rebar corrosion. Either carbonation or chlorides typically cause steel corrosion in concrete. Carbonation occurs when carbon dioxide in the atmosphere combines with calcium within the concrete. This indicates that the pH of the medium is falling, and the steel rebar is corroding. When chlorides pass through concrete to steel, corrosion rates skyrocket. Consideration must be given to concrete moisture. Owing to its excellent resistance, dry concrete has a low steel corrosion rate, whereas extremely wet concrete has a low rate owing to delayed O₂ transfer to steel surfaces. This paper examines rebar corrosion causes and mechanisms and describes corrosion evaluation and mitigation methods.

• Geomechanics and Engineering
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• v.29 no.4
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• pp.451-461
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• 2022

The roadways surrounded by rock and coal will lose their stability or even collapse under rock burst. Rock burst mainly involves an evolution of dynamic loading which behaves quite differently from static or quasi-static loading. To compare the dynamic response of coal and rocks with different static strengths, three different rocks and bituminous coal were selected for testing at three different dynamic loadings. It's found that the dynamic compression strength of rocks and bituminous coal is much greater than the static compression strength. The dynamic compression strength and dynamic increase factor of the rocks both increase linearly with the increase of the strain rate, while those of the bituminous coal are irregular due to the characteristics of multi-fracture and heterogeneity. Moreover, the absorbed energy of the rocks and bituminous coal both increase linearly with an increase in the strain rate. And the ratio of absorbed energy to the total energy of bituminous coal is greater than that of rocks. With the increase of dynamic loading, the failure degree of the sample increases, with the increase of the static compressive strength, the damage degree also increases. The static compassion strength of the bituminous coal is lower than that of rocks, so the number of small-scale fragments was the largest after bituminous coal rupture.

• Steel and Composite Structures
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• v.46 no.6
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• pp.745-757
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• 2023

In order to study the fatigue performance of the flat steel plate-lightweight aggregate concrete hollow composite bridge slab subjected to fatigue load, both static test on two specimens and fatigue test on six specimens were conducted. The effects of the arrangement of the steel pipes, the amplitude of the fatigue load and the upper limit as well as lower limit of fatigue load on failure performance were investigated. Besides, for specimens in fatigue test, strains of the concrete, residual deflection, bending stiffness, residual bearing capacity and dynamic response were analyzed. Test results showed that the specimens failed in the fracture of the bottom flat steel plate regardless of the arrangement of the steel pipes. Moreover, the fatigue loading cycles of composite slab were mainly controlled by the amplitude of the fatigue load, but the influences of upper limit and lower limit of fatigue load on fatigue life was slight. The fatigue life of the composite bridge slabs can be determined by the fatigue strength of bottom flat steel plate, which can be calculated by the method of allowable stress amplitude in steel structure design code.

• Geomechanics and Engineering
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• v.37 no.6
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• pp.555-563
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• 2024

The reasonable setting of coal pillar width plays a key role in guaranteeing the steadiness of surrounding rock of fully mechanized caving gateroad driving along the next goaf. Based on the engineering background of the Bayangaole mine, the discrete element method was used to simulate the fracture evolution of coal pillars with different pillar widths. The results show that the damage rate of the coal pillar increases with the decrease in the width of the coal pillar. Once the coal pillar width is smaller than 6 m, cracks run through the coal pillar, and the coal pillar is completely damaged. In the middle of the coal pillar, which has a width of 6 m and above, there is a relatively complete area with low damage. The results show that the pillar width of 6 m is the most appropriate. Field tests prove that the reserved width of a 6 m small coal pillar can effectively control the surrounding rock deformation, ensuring the overall steadiness of the gateroad in the thick coal seam. It is hoped that this study will offer some reference for the determination of the reasonable size of the coal pillar.