• Title/Summary/Keyword: Formation loss

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Effect of Hydrogen Ratio and Tin Addition on the Coke Formation of Platinum Catalyst for Propane Dehydrogenation Reaction (프로판 탈수소화 반응용 백금촉매의 코크 생성에 미치는 수소비와 주석첨가의 영향)

  • Kim, Soo Young;Kim, Ga Hee;Koh, Hyoung Lim
    • Clean Technology
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    • v.22 no.2
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    • pp.82-88
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    • 2016
  • The loss of activity by coke is an important cause of catalyst deactivation during industrial operation. In this study, hydrogen ratio of reaction condition, which has influenced on coke formation over Pt-Sn catalyst, and regeneration of catalysts activity by coke burning, Pt sintering of coke burning as coke contents, effects of coke formation and deactivation with different Sn contents were confirmed. Pt-Sn-K catalyst supported on θ-alumina and γ-alumina was prepared progressively. Activity of regenerated catalyst for propane dehydrogenation was compared with fresh catalyst by coke burning, after propane dehydrogenation was carried out with different hydrogen ratio at 620 ℃ on fresh catalyst. Regenerated catalyst’s physical characterization such as BET, coke analysis and XRD was investigated. Through catalytic activity test and characterization, Sn contents of catalyst and hydrogen ratio in feed stream could affect coke formation on catalyst surface. Excessive coke makes loss of activity and Pt sintering during air regeneration process.

Radioprotective Effect of Panax ginseng against Giant Cell Formation in The Testis of Irradiated Mice

  • Kumar Madhu;Saxena Preeti S.
    • Proceedings of the Ginseng society Conference
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    • 2002.10a
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    • pp.385-391
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    • 2002
  • Panax ginseng (family- Araliaceae) is a native plant of Korea and has been used for past several years among oriental people. To evaluate the radioprotective potential of P. ginseng on the formation of giant cells in the testis of Swiss albino mice, the animals were divided into four groups: -(I)-Only vehicle was administered. (II)P. ginseng treated group: -The animals received 10 mg/kg body weight P. ginseng root extract (in DDW) i.p. continuously for 30 days. (III) Irradiated group: -The animals were exposed to 8 Gy gamma radiation at the dose rate of 1.69 Gy/min at the distance of 80 ems. (IV) Combined treatment group: -Animals were given P. ginseng extract for four days and on fourth day they were irradiated to 8 Gy gamma radiation after 30 minute of extract administration. The animals of these three groups were autopsied on day 1,3, 7, 14 and 30 days. In ginseng treated group, active spermatogenesis was observed without any toxic effect. Histopathological studies of irradiated group (II) revealed reduction in germ cell count, loss of sperms and formation of multinucleated giant cells on day 7th. These giant cells were formed by round nuclei of early or late spermatids. In combination group (III), although germinal epithelium was still disorganized with loss of cells in few tubules, but no giant cell formation was observed. In order to know the mechanism of radioprotection of ginseng, LPO and GSH were estimated. It was observed that pretreated irradiated animals showed inhibition of LPO and increase in GSH. Thus the present study suggests ginseng protects male gonads. This may be attributed to the inhibition of LPO and increase synthesis of GSH byginseng.

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Lessons Learnt from an 11-year Experience with Lymphatic Surgery and a Systematic Review of Reported Complications: Technical Considerations to Reduce Morbidity

  • Ciudad, Pedro;Escandon, Joseph M.;Manrique, Oscar J.;Bustos, Valeria P.
    • Archives of Plastic Surgery
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    • v.49 no.2
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    • pp.227-239
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    • 2022
  • Complications experienced during lymphatic surgery have not been ubiquitously reported, and little has been described regarding how to prevent them. We present a review of complications reported during the surgical management of lymphedema and our experience with technical considerations to reduce morbidity from lymphatic surgery. A comprehensive search across different databases was conducted through November 2020. Based on the complications identified, we discussed the best approach for reducing the incidence of complications during lymphatic surgery based on our experience. The most common complications reported following lymphovenous anastomosis were re-exploration of the anastomosis, venous reflux, and surgical site infection. The most common complications using groin vascularized lymph node transfer (VLNT), submental VLNT, lateral thoracic VLNT, and supraclavicular VLNT included delayed wound healing, seroma and hematoma formation, lymphatic fluid leakage, iatrogenic lymphedema, soft-tissue infection, venous congestion, marginal nerve pseudoparalysis, and partial flap loss. Regarding intra-abdominal lymph node flaps, incisional hernia, hematoma, lymphatic fluid leakage, and postoperative ileus were commonly reported. Following suction-assisted lipectomy, significant blood loss and transient paresthesia were frequently reported. The reported complications of excisional procedures included soft-tissue infections, seroma and hematoma formation, skin-graft loss, significant blood loss, and minor skin flap necrosis. Evidently, lymphedema continues to represent a challenging condition; however, thorough patient selection, compliance with physiotherapy, and an experienced surgeon with adequate understanding of the lymphatic system can help maximize the safety of lymphatic surgery.

Effect of cleansing methods on the bone resorption due to repeated dis/re-connection of implant abutment (지대주 풀림과 조임시 지대주 세척방법에 따른 임플란트 주변 골소실의 양에 대한 평가)

  • Yang, Seung-Min;Shin, Seung-Yun;Kye, Seung-Beom
    • Journal of Periodontal and Implant Science
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    • v.37 no.3
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    • pp.535-542
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    • 2007
  • Background : Repeated dis/re-connection of implant abutment caused bone loss around implant fixtures due to the new formation of biologic width of the mucosal-implant barrier. The aim of this clinical study was to evaluate whether the repeated dis/re-connection of implant abutment cause bone loss clinically and the effect of cleansing methods on a bone loss during the early healing period. Methods : A total 50 implants were installed in 20 patients and repeated dis/re-connection of abutment was performed at the time of surgery and once per week for 12 weeks. 0.9% normal saline solution as group1 and 0.1% chlorhexidine solution as group 2 was used to clean abutments. All patients had radiographs taken at the placement of implant and 4, 8, and 12 weeks postoperatively. The data for bone loss around implant were analyzed. Results: The marginal bone loss at 12 weeks were $1.28{\pm}0.51mm$, $1,32{\pm}0,57mm$ in the mesial and distal sides in group1, $1.94{\pm}0.75mm$, $1.81{\pm}0.84mm$ in group 2, respectively. In view of marginal bone loss, there was not a significant statistical difference between groups. Conclusions : Repeated dis/re-connection of implant abutment may not cause marginal bone loss around implant fixture although limited samples and short-term observation period. In spite of more bone loss in group 2, there was no statistical significant difference between groups. In context of those results, the clinical significance of the repeated dis/re-connection of implant abutment and the cleansing method of abutments is debatable when it comes to marginal bone loss during early healing period.

ULTRASTRUCTURAL STUDY ON THE EFFECT OF RADIATION IN THE RAT FETUS TONGUE. (방사선조사가 태내백서의 설조직에 미치는 영향에 관한 전자현미경적 연구)

  • Han Chang Geun
    • Journal of Korean Academy of Oral and Maxillofacial Radiology
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    • v.13 no.1
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    • pp.17-27
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    • 1983
  • The author observed the effects of /sup 60/Co irradiation on the development and subcellular structure of tongue tissue of the fetal rats. The lower left abdomen of mothers were exposed to radiation on 15½th day of gestation with 300R. The fetuses were removed on the 6hr, 14hr, 24hr, 48hr and 72hr after irradiation and the light microscopic and electron microscopic observations of the lingual epithelium, lamina propria and muscle layer were carried out. The results were as follows: 1. The irradiated fetuses showed the retardation of filiform papillae formation. 2. Epithelial cells revealed fusion and myelination of mitochondria, large autolysosomes, increased lipid droplets, retardation of tonofilaments and desmosome formation. 3. In the lamina propria, undifferentiated cells showed bleb formation of nuclear membrane, pyknosis and fragmentation of nucleus, edema of cytoplasm I and nucleus, increased auto-lysosomes, dilatation of cell membrane and cell necrosis. Also, collagenous fibril formation was inhibited by irradiation. 4. In the muscle layer, growth of myotubes was inhibited. Myotubes showed swelling of mitochondria, loss of mitochondrial cristae, autolysosomes, retardation of myofibril formation, and large vacuoles. Undifferentiated cells adjacent myotube contained pyknotic nucleus and autolysosomes. 5. Among the various tissues of tongue, it seems that mesenchymal cells were most radiosensitive.

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Flamelet Modelling of Soot Formation and Oxidation in a Laminar $CH_4-Air$ Diffusion Flame (화염편 모델을 이용한 층류확산화염장의 매연 생성 및 산화과정 해석)

  • Kim Gunhong;Kim Hoojoong;Kim Yongmo
    • Transactions of the Korean Society of Automotive Engineers
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    • v.13 no.1
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    • pp.68-75
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    • 2005
  • By utilizing a semi-empirical soot model, the applicability of the laminar flamelet concept fur simulating the formation and oxidation of soot in the laminar diffusion flame has been studied. The source terms for two transport equations of the soot formation and oxidation are calculated in the mixture fraction/scalar dissipation rate space for laminar flamelets and stored in a library. In this study, emphasis is given to the interaction associated with radiation and soot formation. The radiative heat loss is obtained by solving the radiative transfer equation using the unstructured grid finite volume method with the WSGGM. The calculated temperatures and soot volume fractions agree relatively well with the experimental data and the previous numerical results of Kaplan et al. using the detailed chemistry.

Wind flow modification by a jet roof for mitigation of snow cornice formation

  • Kumar, Ganesh;Gairola, Ajay;Vaid, Aditya
    • Wind and Structures
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    • v.32 no.2
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    • pp.115-126
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    • 2021
  • The snow cornice mass on the formation zone had triggered avalanches which led to the loss of human life and property. Snow cornice is formed due to flow separation on the leeward side. Effect of lee slope is more prominent in the formation of snow cornices as compared to the windward slope. The analysis of wind flow pattern has been carried out to evaluate the performance of a jet roof. Computational Fluid Dynamics (CFD) analysis of wind flow over a 2D hill model was carried out using RNG based k-∈ turbulence models available in ANSYS Fluent. Effect of varying leeward hill slope (1:2 to 1:6) on flow separation for the given windward slope was observed and a critical slope of 1:4 was found at which the separation zone ceased to exist. The modification of wind flow over a hill due to the installation of jet roof was simulated. It was observed that jet roof had significantly modified the wind flow pattern around hill ridgeline and ultimately snow cornice formation had mitigated. The results of the wind flow pattern were validated with the wind data collected at the experimental site, Banihal Top (Jammu and Kashmir, India). The wind flow simulation over the hill and mitigation of cornice formation by the jet roof has been explained in the present paper.

Risk Factors for Gallbladder Stone Formation after Gastric Cancer Surgery

  • Lee, Young-Won;Kim, Amy;Han, Minkyu;Yoo, Moon-Won
    • Journal of Gastric Cancer
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    • v.19 no.4
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    • pp.417-426
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    • 2019
  • Purpose: Although an increased incidence of gallbladder (GB) stone formation after gastrectomy has been reported, its etiology remains uncertain. The goal of this study was to explore the incidence of gallstone formation after gastrectomy in gastric cancer patients and investigate the risk factors therein. Materials and Methods: Medical records of patients who underwent curative gastrectomy, performed by a single surgeon between August 2012 and December 2015 at the Asan Medical Center, were retrospectively reviewed. Baseline characteristics and surgical outcomes, including GB stone gallstone formation after gastrectomy, were analyzed. Results: Of 561 patients included in the study, 36 presented with GB stone formation after gastrectomy for gastric cancer. The incidence of gallstone formation was 6.4%. The mean interval between gallstone formation and gastrectomy was 21.9 months. In multivariate analyses, the incidence of gallstone formation increased in patients 63 years or older, with greater than 6.2 kg weight loss in the first 6 months after the procedure, a preoperative serum total bilirubin level greater than 0.5 mg/dL, and in patients who did not receive adjuvant chemotherapy. Conclusions: This study presented risk factors for GB stone formation after gastric cancer surgery, and special attention should be afforded to patients with such risk factors.

Mechanism of Organogel Formation from Mixed-Ligand Silver (I) Carboxylates

  • Kim, Ji-Yeon;Park, Cheol-Hee;Kim, Sang-Ho;Yoon, Sung-Ho;Piao, Longhai
    • Bulletin of the Korean Chemical Society
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    • v.32 no.9
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    • pp.3267-3273
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    • 2011
  • Ag(I) carboxylate gelators with mixed-ligands were systemically investigated to understand the mechanism of the organic gel formation. The gelators constructed 3-D networks of nanometer-sized thin fibers which facilitated gel formation in various aromatic organic solvents, even at very low concentrations. The loss of reflection peaks in the X-ray diffraction data indicated the reduction of strong interactions between the long alkyl chains as the Ag(I) carboxylates formed gels by maximizing their interactions with the organic solvents. The gelation temperature ($T_{gel}$) was measured to explore the interaction between the gelator molecules and solvents depending on their composition and concentration. Based on the gelation phenomena, a dissociation/re-association mechanism was proposed.

THE DYNAMICS OF STELLAR WINDS: THEIR STRUCTURES AND [OIII] LINE FORMATION

  • CHA SEUNG-HOON;LEE YOUNG-JIN;CHOE SEUNG-URN
    • Journal of The Korean Astronomical Society
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    • v.29 no.spc1
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    • pp.253-254
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    • 1996
  • To understand the dynamical structures of stellar wind bubble, one and two-dimensional calculations has been performed. Using FCT Code with cooling effects and assuming constant mass loss rate and ambient medium density, we could divide stellar winds into the regime of slow and fast winds. The slow wind driven bubble shows initially radiative and becomes partially radiative bubble in which shocked stellar wind zone is still adiabatic. In contrast., the fast wind driven bubble shows initially fully adiabatic and becomes adiabatic bubbles with radiative outer shell. We also determine analytically the onset of thin-shell formation time in case of fast wind driven bubble with power-law energy injection and ambient density structure. We solve the line transfer problem with numerical results in order to calculate line profile of [OIII] forbidden line.

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