• 제목/요약/키워드: Formation Parameters

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A Study on the Characteristics of Soot Formation and Oxidation in Free Fuel Droplet Array

  • Lee, Myung-Jun;Kim, Jong-Youl;Yeom, Jeong-Kuk;Ha, Jong-Yul;Chung, Sung-Sik
    • Journal of Mechanical Science and Technology
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    • v.16 no.6
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    • pp.851-860
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    • 2002
  • In this study, it was attempted to obtain the fundamental data for the formation and oxidation of soot from a diesel engine. Combustion of spray injected into a cylinder is complex phenomenon having physical and chemical processes, and these processes affect each other. There are many factors in the mechanism of the formation and oxidization of soot and it is necessary to observe spray combustion microscopically. In order to observe with that view, free fuel droplet array was used as an experimental object and the droplet array was injected into an atmospheric combustion chamber with high temperature. Ambient temperature of the combustion chamber, interdroplet spacing, and droplet diameter were selected as parameters, which affect the formation and oxidation of soot. In this study, it was found that the parameters also affect ignition delay of droplet. The ambient temperature especially affected the ignition delay of droplet as well as the flame temperature after self-ignition. As the interdroplet spacing that means the local equivalence ratio in a combustion chamber was narrow, formation of soot was increased. As diameter of droplet was large, surface area of the droplet was also broad, and hence evaporation of the droplet was more active than that of a droplet with relative small diameter.

Structural assessment of reactor pressure vessel under multi-layered corium formation conditions

  • Kim, Tae Hyun;Kim, Seung Hyun;Chang, Yoon-Suk
    • Nuclear Engineering and Technology
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    • v.47 no.3
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    • pp.351-361
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    • 2015
  • External reactor vessel cooling (ERVC) for in-vessel retention (IVR) has been considered one of the most useful strategies to mitigate severe accidents. However, reliability of this common idea is weakened because many studies were focused on critical heat flux whereas there were diverse uncertainties in structural behaviors as well as thermal-hydraulic phenomena. In the present study, several key factors related to molten corium behaviors and thermal characteristics were examined under multi-layered corium formation conditions. Thereafter, systematic finite element analyses and subsequent damage evaluation with varying parameters were performed on a representative reactor pressure vessel (RPV) to figure out the possibility of high temperature induced failures. From the sensitivity analyses, it was proven that the reactor cavity should be flooded up to the top of the metal layer at least for successful accomplishment of the IVR-ERVC strategy. The thermal flux due to corium formation and the relocation time were also identified as crucial parameters. Moreover, three-layered corium formation conditions led to higher maximum von Mises stress values and consequently shorter creep rupture times as well as higher damage factors of the RPV than those obtained from two-layered conditions.

Effect of Number and Location of Amine Groups on the Thermodynamic Parameters on the Acridine Derivatives to DNA

  • Kwon, Ji Hye;Park, Hee-Jin;Chitrapriya, Nataraj;Han, Sung Wook;Lee, Gil Jun;Lee, Dong Jin;Cho, Tae-Sub
    • Bulletin of the Korean Chemical Society
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    • v.34 no.3
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    • pp.810-814
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    • 2013
  • The thermodynamic parameters for the intercalative interaction of structurally related well known intercalators, 9-aminoacridine (9AA) and proflavine (PF) were determined by means of fluorescence quenching study. The fluorescence intensity of 9AA decreased upon intercalation to DNA, poly[$d(A-T)_2$] and poly[$d(G-C)_2$]. A van't Hoff plot was constructed from the temperature-dependence of slope of the ratio of the fluorophore in the absence and presence of a quencher molecule with respect to the quencher concentration, which is known as a Stern-Volmer plot. Consequently, the thermodynamic parameters, enthalpy and entropy change, for complex formation was calculated from the slope and y-intercept of the van't Hoff plot. The detailed thermodynamic profile has been elucidated the exothermic nature of complex formation. The complex formation of 9AA with DNA, poly[$d(A-T)_2$] and poly[$d(G-C)_2$] was energetically favorable with a similar negative Gibb's free energy. On the other hand, the entropy change appeared to be unfavorable for 9AA-poly[$d(G-C)_2$] complex formation, which was in contrast to that observed with native DNA and poly[$d(A-T)_2$] cases. The equilibrium constant for the intercalation of PF to poly[$d(G-C)_2$] was larger than that to DNA, and was the largest among sets tested despite the most unfavorable entropy change, which was compensated for by the largest favorable enthalpy. The favorable hydrogen bond contribution to the formation of the complexes was revealed from the analyzed thermodynamic data.

Hydrocarbon Enthalpies of Formation from ab initio Calculations Improved Through Bond Parameters (향상된 결합 파라미터를 도입한 순이론적 탄화수소 생성엔탈피 결정)

  • Duchowicz, P.;Castro, E.A.
    • Journal of the Korean Chemical Society
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    • v.43 no.6
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    • pp.621-627
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    • 1999
  • A new predictive scheme to calculate hydrocarbon enthalpies of formation from ab initio total energy calculations is described. The method improves a previous computation procedure (based on the total number of atoms) through the inclusion of bond parameters. Present results are good enough and the average absolute errors in the computed values of enthalpies of formation are lower than the experimental uncertainties. Some possible extensions are pointed out in order to reach definitive conclusions about the proposed methodology.

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PHOTOELECTRIC OBSERVATIONS OF EXTREMELY YOUNG OPEN CLUSTERS

  • Kwon, Suk-Minn;Lee, See-Woo
    • Journal of The Korean Astronomical Society
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    • v.16 no.1
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    • pp.7-17
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    • 1983
  • During the period between January and November in 1982, UBV photoelectric observations were made for 48 stars in NGC 2264, 66 stars in IC 1805 and 22 stars in IC 348. From these observations, various physical parameters such as distance, mean color excess, total-to-selective extinction ratio and mean age of the clusters were determined. Making use of these parameters, the star formation rates were examined for IC 348 and NGC 2264. The overall formation rate is found to be increase rapidly during the period of the active star formation. The age spread (ranging from $5\times10^6$ yrs to $10^7$ yrs) of stars in a given cluster appears to be real which occurs in the extremely young open clusters.

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Numerical Simulation of Soliton-like Pulse Formation in Diode-pumped Yb-doped Solid-state Lasers

  • Seong-Yeon, Lee;Byeong-Jun, Park;Seong-Hoon, Kwon;Ki-Ju, Yee
    • Current Optics and Photonics
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    • v.7 no.1
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    • pp.90-96
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    • 2023
  • We numerically solve the nonlinear Schrödinger equation for pulse propagation in a passively mode-locked Yb:KGW laser. The soliton-like pulse formation as a result of balanced negative group-delay dispersion (GDD) and nonlinear self-phase modulation is analyzed. The cavity design and optical parameters of a previously reported high-power Yb:KGW laser were adopted to compare the simulation results with experimental results. The pulse duration and energy obtained by varying the small-signal gain or GDD reproduce the overall tendency observed in the experiments, demonstrating the reliability and accuracy of the model simulation and the optical parameters.

The Influence of Fabrication Parameters on the Porosity Formation during Squeeze Infiltration Process (가압함침공정 중 기공 형성에 대한 제조 변수의 영향)

  • 서영호;이형국
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2001.05a
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    • pp.184-188
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    • 2001
  • The squeeze infiltration process is potentially of considerable industrial importance. The performance enhancements resulting from incorporation of short alumina fiber into aluminum are well documented. These are particularly significant for certain automobile components. But the solidification process gets complicated with manufacturing parameters and factors for porosity formation do not fully understand yet. In this study porosity defects were observed under several infiltrating conditions ; a kind of matrix, an initial temperature of melt, and a volume fraction of reinforcement. The desimetry and the microscopic image analysis were done to measure the amount of porosity. A correlation between manufacturing parameters and defects was investigated through these.

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Burr Classification Using Acoustic Emission (음향방출을 이용한 버 유형 분류)

  • Kim, Pil-Jae;Lee, Seoung-Hwan
    • Journal of the Korean Society for Precision Engineering
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    • v.19 no.2
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    • pp.133-139
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    • 2002
  • A number of experimental studies on burr formation in face milling operations have been pursued. They usually focus on machining parameters such as depth of cut, leed rate, spindle speed and in-plane exit angle. But it if difficult to set the correlation between burrs and the parameters on burr when such parameters are considered at the same time. Therefore, in this paper, acoustic emission (AE) is considered as an alternate way to predict burr types regardless of machining conditions. AE signals during face milling were sampled and processed, then fed into an artificial neural network to classify burr types \\\"on-line\\\".\\\".uot;.

Study on the Splat Formation of Ni-based Thermal Sprayed Coatings (니켈기 용사코팅의 스플랫 형성에 관한 연구)

  • Kim, K.T.;Lee, S.S.;Lee, D.H.;Kim, Y.S.
    • Journal of Power System Engineering
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    • v.16 no.2
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    • pp.49-53
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    • 2012
  • Thermal spray coatings developed by deposition of splats, it formed by impacting molten droplets on substrates during thermal spray process. In this study, the Ni-based coatings were fabricated by thermal spray process with two different process parameters, oxygen gas flow and acetylene gas flow, with three different levels of each parameters. The morphology of splats and microstructure were observed by optical microscope. Hardness test were performed on the Ni-based coatings. It was confirmed that process parameters of thermal spray process have effect in morphology of splats. These effects also have important implications on the deposit microstructure and properties of Ni-based coatings.

The Effect of Processing Parameters to Manufacture Self-healing Microcapsules for Composite Materials (복합재료의 자가 치료용 캡슐 제작시 공정 변수들의 영향)

  • Yoon, YoungKi;Yoon, HiSeak
    • Journal of the Korean Society for Precision Engineering
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    • v.18 no.4
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    • pp.135-141
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    • 2001
  • An experimental study to find the effect of processing parameters for self-healing microcapules is performed. These microcapsules can be applied to accomplish the healing of delamination damage in woven E-glass/epoxy composites. This paper introduces the self-healing concept and presents a method for solving the microcapsule size and shape. Additionally, processing parameters are varied during the formation of microcapsules and these capsules are observed through optical microscope. To obtain thermogravimetric(TG) curve for the manufactured microcapsules, TGA tests are executed. From these results, the best processing conditions for the formation of capsules are found as follows: (1) temperature of solution $ 50^{\circ}C$, (2) potential of hytdrogen(pH) 3.5ppm, and (3) agitation 500~600rpm.

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