• 센서학회지
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• 제26권6호
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• pp.420-426
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• 2017

A colorimetric sensor was investigated to achieve a low-cost warning device for harmful gaseous formaldehyde (HCHO). The sensor is based on selective reactions between hydroxylamine sulfate and HCHO, leading to the production of sulfuric acid. The produced acid results in color-changing response through the acid-base reaction with dye molecules impregnated on a solid membrane substrate. For attaining this purpose, sensors were fabricated by drop-casting a dye solution prepared using different pH indicators on various commercially available polymer sheets, and their colorimetric responses were evaluated in terms of sensitivity and reliability. The colorimetric sensor using bromophenol blue (BPB) and nylon sheet was found to exhibit the best performance in HCHO detection. An initial bluish green of a sensor was changed to yellow when exposed to gaseous formaldehyde. The color change was recorded using an office scanner and further analyzed in term of RGB distance for quantifying sensor's response at different HCHO(g) concentrations. It exhibited a recognizable colorimetric response even at 50 ppb, being lower than WHO's standard of 80 ppb. In addition, the sensor was found to have quite good selectivity in HCHO detection under the presence of common volatile organic compounds such as ethanol, toluene, and hexane.

• 대한원격탐사학회지
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• 제35권4호
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• pp.503-516
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• 2019

We have estimated the vertical column density (VCD) of formaldehyde (HCHO) on a global scale using a multiple linear regression method (MRM) with Ozone Monitoring Instrument (OMI) and Moderate-Resolution Imaging Spectroradiometer (MODIS) data. HCHO VCDs were estimated in regions of biogenic, pyrogenic, and anthropogenic emissions using independent variables, including $NO_2$ VCD, land surface temperature (LST), an enhanced vegetation index (EVI), and the mean fire radiative power (MFRP), which are strongly correlated with HCHO. To evaluate the HCHO estimates obtained using the MRM, we compared estimates of HCHO VCD data measured by OMI ($HCHO_{OMI}$) with those estimated by multiple linear regression equations (MRE) ($HCHO_{MRE}$). Good MRM performances were found, having the average statistical values (R = 0.91, slope = 1.03, mean bias = $-0.12{\times}10^{15}molecules\;cm^{-2}$, percent difference = 11.27%) between $HCHO_{MRE}$ and $HCHO_{OMI}$ in our study regions where high HCHO levels are present. Our results demonstrate that the MRM can be a useful tool for estimating atmospheric HCHO levels.

• 한국방사선학회논문지
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• 제15권7호
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• pp.1057-1064
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• 2021

본 연구는 초음파 조직검사 시에 실내 공기 중 HCHO 농도변화를 관찰하고자 실제 조직검사와 동일한 환경조건을 모사하여 진행하였다. 초음파 검사실의 밀폐, 환기, 포르말린 용기 개봉, 포르말린 용기 밀봉, 재환기의 다섯 단계를 연속적으로 진행하며 실내의 HCHO 농도변화를 측정하였다. 측정한 HCHO 농도변화는 그래프를 이용하여 시각화하였다. 3회에 걸쳐 측정된 농도 변화값의 일치도를 급내상관계수를 이용하여 분석한 결과, 상관계수 값이 0.989로 통계적으로 유의한 결과를 나타내었다(p<0.05). 연구 결과를 토대로 영상의학적 검사 분야에서 HCHO의 노출 환경 내에 근무하고 있는 의료종사자들 스스로 업무 중 노출 관리 필요성에 대한 인식개선과 더불어 노출 관리를 위한 환경구축 및 대책 마련에 대하여 적극적인 논의가 이루어지길 바란다.

• 한국대기환경학회지
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• 제22권1호
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• pp.63-71
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• 2006

An automated carbonyl measurement system was constructed. Atmospheric carbonyl compounds were extracted onto DNPH containing collection solution while flowing through a glass coil. Each carbonyl species was separated on a HPLC column and quantified by UV absorption detector. Using this system, carbonyl compounds were continuously measured at the campus of Korea University in Seoul, Korea during June, 2005. Sampling resolution was 30 minutes and the detection limit of HCHO was 0.19 ppbv. Also, $\O_{3}$, it's precursors, and meteorological parameters were measured. The maximum, minimum, average, and median concentrations of HCHO during the whole experiment was 35.8 ppbv, 1.4 ppbv, 11.7 ppbv, and 9.3 ppbv respectively. Formaldehyde showed a distinct diurnal variation with a broad maximum around 13 $\sim$ 15, which was 1 $\sim$ 3 hours ahead of an ozone maximum. During a couple of days, however, HCHO concentrations were kept high through the night or increased concomitantly with NOx in the morning. These results imply that HCHO was mainly produced from the photochemical oxidation of VOCs, but local emission sources couldn't be ruled out. The differences between daily maximum and minimum of $O_{3}$ and HCHO were calculated for 11 days of June, when typical diurnal variations were observed for the two species. A strong positive correlation was found between $\Delta O_{3}$ and $\Delta HCHO$ and the average mole ratio of $\Delta HCHO$ to $\Delta O_{3}$ was 2.6. It indicates that formaldehyde played a key role in $\Delta O_{3}$ production as an indicator species in Metropolitan Seoul during June, 2005.

• KIEAE Journal
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• 제10권4호
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• pp.81-86
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• 2010

The main sources of the new house syndrome(sometimes it called sick building syndrome) are a concentration of formaldehyde (HCHO) and a concentration of total volatile organic compounds(TVOC). I had field measurements of indoor air quality in the apartment unit at medium-size cities(Y city, C city). I measured indoor air temperature, HCHO concentration in 16 units, TVOC concentration in 6 units and air tightness in 7 units. And I measured outdoor air quality, HCHO concentration and TVOC concentration. Mean concentration of HCHO was $357{\mu}g/m^3$(2006 standard=$120{\mu}g/m^3$), mean concentration of TVOC was $3,092{\mu}g/m^3$ and mean effective air leakage area was 193 cm2. There was a close relation between the indoor air temperature and HCHO concentration, between the indoor air temperature and TVOC concentration. Air tightness also had relation.

• 한국대기환경학회지
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• 제18권1호
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• pp.11-23
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• 2002

The concentrations of aldehydes were measured in downtown area of Buchun and Kwanghwamoon of Seoul from October 1997 to August 1998 using 2-series impingers. The data have been analysed to identify the seasonal pattern of aldehyde sources in metropolitan areas. The measured concentration (in ppbv) of aldehydes were 8.86 $\pm$ 7.28 HCHO (formaldehyde) and 7.79$\pm$7.29 $CH_3$CHO (acetaldehyde) in Buchun, while recording 10.13$\pm$8.58 (HCHO) and 7.64$\pm$6.65 ($CH_3$CHO) in Kwanghwamoon. Their diurnal variation patterns showed significant increase of HCHO and $CH_3$CHO concentration in early afternoon, indicating an increase in secondary sources. Their concentrations however decreased in the nighttime, regardless of seasons. The strength of correlations between certain pairs such as (1) HCHO and CO and (2) $CH_3$CHO and CO were generally high during the winter months (0.64< r < 0.84), suggesting the possibility of similar source processes for HCHO, $CH_3$CHO and CO. On the other hand during the summer months, their correlations are frequently lower than winter months. We suggested that the complexity of source/sink processes during the summer period may reduce the correlations between aldehyde and CO.

• 한국대기환경학회:학술대회논문집
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• 한국대기환경학회 2001년도 추계학술대회 논문집
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• pp.163-164
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• 2001

휘발성유기화합물(VOCs)과 포름알데히드(HCHO)의 발생원은 매우 다양할 뿐만아니라 주변환경과 인체에 미치는 영향이 매우 크다. VOCs와 포름알데히드의 발생원으로는 크게 인위적인 발생원, 자연적인 발생원, 실내에서의 발생원으로 구분할 수 있다. 현대인들의 하루생활 중 80%이상이 실내에서 이루어지고 있어 실내에서의 발생되는 오염물질에 대한 특성파악과 적절한 제어방안이 요구된다. VOCs와 포름알데히드의 발생원중에서 실내에서의 발생원으로는 여러 가지가 있으나, 신축건물과 리모델링에 사용되는 건축자재에서의 방출은 매우 크다고 할 수 있다. (중략)

• 한국염색가공학회지
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• 제2권1호
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• pp.14-20
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• 1990

The cotton fabrics were treated with formaldehyde in the presence of zinc nitrate catalyst and urea. The effects of HCHO concentration, urea concentration, catalyst ratio, cure time and cure temperature on the physical properties of fabrics were studied. Cotton fabric finished with HCHO and urea had the lower tensile strength and tear strength than untreated one. These strength losses resulted from tighter oxymethylene crosslinks. The enhanced wrinkle recovery for fabric treated with formaldehyde in the presence of urea was indicative of the formation of urea-formaldehyde polymer. These experimental conditions were set up according to table of orthogonal arrays.

• 센서학회지
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• 제17권3호
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• pp.183-187
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• 2008

A sub-ppm level MEMS gas sensor that can be used for the detection of formaldehyde (HCHO) is presented. It is realized by using a zinc oxide (ZnO) thin-film material with a Ni-seed layer as a sensing material and by bulk micromachining technology. To enhance sensitivity of the MEMS gas sensor with Ni-seed layer was embedded with ZnO sensing material and sensing electrodes. As experimental results, the changed sensor resistance ratio for HCHO gas was 9.65 % for 10 ppb, 18.06 % for 100 ppb, and 35.7 % for 1 ppm, respectively. In addition, the minimum detection level of the fabricated MEMS gas sensor was 10 ppb for the HCHO gas. And the measured output voltage was about 0.94 V for 10 ppb HCHO gas concentration. The noise level of the fabricated MEMS gas sensor was about 50 mV. The response and recovery times were 3 and 5 min, respectively. The consumption power of the Pt micro-heater under sensor testing was 184 mW and its operating temperature was $400^{\circ}C$.

• Environmental Analysis Health and Toxicology
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• 제19권2호
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• pp.177-182
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• 2004

Alcohol consumption and exposure to endocrine disruptors and industrial solvents have been implicated in impaired spermatogenesis, increase in the incidence of malformed sperm and decrease in the percentage of moving sperm. The aim of this study was to determine and compare the direct effects of some organic solvents(bisphenol A; BPA, dibutyl phthalate; DBP, formaldehyde; HCHO, dimethylsulphoxide; DMSO, ethanol) on mucus penetration distance, motility and survival rate of human sperm in vitro. Semen samples from 3 health subjects were prepared using swim-up method and 0.0005-0.5% organic solvents were added to the test medium. BPA, DBP, HCHO and DMSO produced significant decreases in the motility and survival rate with a different potency. The most potent inhibition of mucus penetration distance, motility and survival rate was observed after exposure to HCHO. A concentration of 0.0005% HCHO significantly inhibited sperm motility. When ethanol m.: added directly to sperm, at concentrations equivalent to that in serum after heavy drinking, these damaging effects were lowest compared with other solvents. Present study shows that each compound has different toxic potency to human sperm and we need special caution for the use of HCHO.