• Title/Summary/Keyword: Focus Particle

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A Study on the Compatibilization of Blends Based on Poly(phenylene ether) and Polyamide (Poly(phenylene ether)/Polyamide 블렌드의 상용화에 관한 연구)

  • 김형수;임종철
    • Polymer(Korea)
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    • v.25 no.3
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    • pp.441-449
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    • 2001
  • Compatibilization of blends based on poly(phenylene ether) (PPE) and polyamide (PA) has been practiced with the incorporation of a copolymer formed by grafting polystyrene onto polybutadiene latex (g-BS) which is further functionalized with maleic anhydride (MAH) (g-BS*) to impart reactivity with amine groups of PA. The major focus has been placed on the effect of the various structural factors in g-BS8 on the phase morphology and mechanical performance of the blends. For the balance of impact strength and heat resistance, it was important to locate g-BS n particles inside of the PPE phase, which was accomplished by the proper control of the molecular weight and amount of PS in g-BS*. For g-BS*'s having constant molecular weight and amount of PS, the reduction of MAH content or increase of rubber particle size in g-BS* resulted in the increase of domain size and consequently loss in mechanical properties. Based on the comparison made with the conventional PPE/PA blend comprising MAH grafted PPE as a compatibilizer, it was confirmed that the comparable level of mechanical performance can be achieved by an appropriate g-BS* type material with improved whiteness index.

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The Effect of Precipitated Calcium Carbonate Having a Small Particle Size on the Print Quality of an Inkjet-Grade Paper (초미립자탄산칼슘이 잉크제트 인쇄품질에 미치는 영향)

  • Lee Yong-Kyu;Lee Hee-Myung
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.37 no.2 s.110
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    • pp.38-46
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    • 2005
  • Experimental work was carried out in order to produce a novel grade of ink-jet paper that has both high print-out quality and price competitiveness. Usually, silica and PVOH has been used for ink-jet paper to design the coating layer that has a hydrophilic and micro-porous structure. However, poor rheological characteristics and low productivity of the silica-PVOH system make the price of the ink-jet paper high. The main focus of this study was replacing the conventional silica (coating pigment) PVOH (binder) coating system with the new PCC (coating pigment) cationic starch (binder) coating system, and optimizing thecoating technology associated with PPC-cationic starch system. In this study, ink-jet print quality of PCC-coated papers was compared with that of silica-coated paper. Two types of PCC were used: conventional type and colloid type. It turned out that PCC C, a conventional coating pigment, has not given a desirable result: it showed high dot reproduction, but it gave low optical density. In spite of low dot reproduction, the qualities of PCC A were comparable or superior to those of silica in optical density, color reproduction, and the uniformity of printing surface. It was also shown that the problems that are happened when the dosage level of cationic starch was too low were varied with ink-type used in each printer. However, in the case of low binder level, the produced image was widely spread resulting fromtoo low optical density of images, or from the lack of bonding ability to set ink into coating surface.

Reduction Leaching of Manganese Dioxide Ore Using Black Locust as Reductant in Sulfuric Acid Solution

  • Xue, Jianrong;Zhong, Hong;Wang, Shuai;Li, Changxin;Li, Jinzhong;Wu, Fangfang
    • Korean Chemical Engineering Research
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    • v.53 no.4
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    • pp.509-516
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    • 2015
  • We investigated the reduction leaching process of manganese dioxide ore using black locust as reductant in sulfuric acid solution. The effect of parameters on the leaching efficiency of manganese was the primary focus. Experimental results indicate that manganese leaching efficiency of 97.57% was achieved under the optimal conditions: weight ratio of black locust to manganese dioxide ore (WT) of 4:10, ore particle size of $63{\mu}m$, $1.7mol{\cdot}L^{-1}\;H_2SO_4$, liquid to solid ratio (L/S) of 5:1, leaching time of 8 h, leaching temperature of 368 K and agitation rate of $400r{\cdot}min^{-1}$. The leaching rate of manganese, based on the shrinking core model, was found to be controlled by inner diffusion through the ash/inert layer composed of associated minerals. The activation energy of reductive leaching is $17.81kJ{\cdot}mol^{-1}$. To conclude the reaction mechanism, XRD analysis of leached ore residue indicates manganese compounds disappear; FTIR characterization of leached residue of black locust sawdust shows hemicellulose and cellulose disappear after the leaching process.

Observation of long-term disappearance and reappearance of the outer radiation belt

  • Lee, Dae-Young;Shin, Dae-Kyu;Kim, Kyung-Chan;Kim, Jin-Hee;Cho, Jung-Hee;Park, Mi Young;Angelopoulos, Vassilis;Hwang, Junga;Lee, Yonghee;Kim, Thomas
    • The Bulletin of The Korean Astronomical Society
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    • v.37 no.2
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    • pp.115.2-115.2
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    • 2012
  • In this study we have used the data of various instruments onboard the THEMIS spacecraft to study the characteristics of the outer radiation belt during the ascending phase of solar cycle 24. The most astonishing result is that we discovered four long-term (a month or so) periods during which the belt has nearly disappeared. The first disappearance started late 2008, followed by reappearance in ~a month, and three more similar events repeated until early 2010 when the belt has reappeared. This is well revealed at 719 keV electrons, which is the currently available uppermost energy channel from the THEMIS SST observation, but also seen at even lower energies. Overall consistent features were confirmed using the NOAA-POES observations. The vanished belt periods are associated with extremely weak solar wind conditions, low geomagnetic disturbances (in terms of Kp and AE/AL), greatly suppressed wave (ULF and chorus) activities, greatly reduced storm and substorm activities (little source particle supply), and expanded plasmapause locations. The direct observations of such events shed light on the fundamental question of the origin of the radiation belt, which is the main focus of our presentation.

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Study of the Kinetic Effects on Relativistic Unmagnetized Shocks using 3D PIC Simulations

  • Choi, Eun Jin;Min, Kyoung W.;Choi, Cheongrim;Nishikawa, Ken-Ichi
    • The Bulletin of The Korean Astronomical Society
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    • v.37 no.2
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    • pp.101.2-101.2
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    • 2012
  • Shocks are ubiquitous in astrophysical plasmas: bow shocks are formed by the interaction of solar wind with planetary magnetic fields, and supernova explosions and jets produce shocks in interstellar and intergalactic spaces. The global morphologies of these shocks are usually described by a set of magnetohydrodynamic (MHD) equations which tacitly assumes local thermal equilibrium, and the resulting Rankine-Hugoniot shock jump conditions are applied to obtain the relationship between the upstream and downstream physical quantities. While thermal equilibrium can be achieved easily in collisional fluids, it is generally believed that collisions are infrequent in astrophysical settings. In fact, shock widths are much smaller than collisional mean free paths and a variety of kinetic phenomena are seen at the shock fronts according to in situ observations of planetary shocks. Hence, both the MHD and kinetic equations have been adopted in theoretical and numerical studies to describe different aspects of the physical phenomena associated with astrophysical shocks. In this paper, we present the results of 3D relativistic particle-in-cell (PIC) simulations for ion-electron plasmas, with focus on the shock structures: when a jet propagates into an unmagnetized ambient plasma, a shock forms in the nonlinear stage of the Weibel instability. As the shock shows the structures that resemble those predicted in MHD systems, we compare the results with those predicted in the MHD shocks. We also discuss the thermalization processes of the upstream flows based on the time evolutions of the phase space and the velocity distribution, as well as the wave spectra analyses.

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Improving the Accuracy of a Heliocentric Potential (HCP) Prediction Model for the Aviation Radiation Dose

  • Hwang, Junga;Yoon, Kyoung-Won;Jo, Gyeongbok;Noh, Sung-Jun
    • Journal of Astronomy and Space Sciences
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    • v.33 no.4
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    • pp.279-285
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    • 2016
  • The space radiation dose over air routes including polar routes should be carefully considered, especially when space weather shows sudden disturbances such as coronal mass ejections (CMEs), flares, and accompanying solar energetic particle events. We recently established a heliocentric potential (HCP) prediction model for real-time operation of the CARI-6 and CARI-6M programs. Specifically, the HCP value is used as a critical input value in the CARI-6/6M programs, which estimate the aviation route dose based on the effective dose rate. The CARI-6/6M approach is the most widely used technique, and the programs can be obtained from the U.S. Federal Aviation Administration (FAA). However, HCP values are given at a one month delay on the FAA official webpage, which makes it difficult to obtain real-time information on the aviation route dose. In order to overcome this critical limitation regarding the time delay for space weather customers, we developed a HCP prediction model based on sunspot number variations (Hwang et al. 2015). In this paper, we focus on improvements to our HCP prediction model and update it with neutron monitoring data. We found that the most accurate method to derive the HCP value involves (1) real-time daily sunspot assessments, (2) predictions of the daily HCP by our prediction algorithm, and (3) calculations of the resultant daily effective dose rate. Additionally, we also derived the HCP prediction algorithm in this paper by using ground neutron counts. With the compensation stemming from the use of ground neutron count data, the newly developed HCP prediction model was improved.

The Concessive Conjunctive Phrase todavía que in Some Areas of Latin America (라틴아메리카 일부 지역에서 사용되는 양보 접속사구 todavía que의 특성)

  • Kwak, Jae-Yong
    • Cross-Cultural Studies
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    • v.46
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    • pp.143-171
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    • 2017
  • In this paper, we present a morphosyntactic and semantic study of the concessive conjunctive phrase [todavía que] in the Andean and River Plate areas of Latin America. Real Academia $Espa{\tilde{n}}ola$(2009) describes that the adverb todavía occurs in a variety of focus-sensitive environments and specially, in the Andean and River Plate areas, the phrase [todavía que] participates in the concessive constructions and triggers an additive interpretation. It is well known that the Quechuan suffix '-raq' and the Aymaran suffix '-raki' have the meaning of todavía which is characterized as a additive particle. Due to the absence of the paratactic relationship between the mentioned Spanish adverb and those indigenous suffixes, the adverb todavía in [todavía que] is used as a additive focalizer. We assume that these morphosyntactic and semantic properties are derived from the language contact of Quechua-Spanish and Aymara Spanish. Based on this assumption, we will further assume that the etymological peculiarity of todavía as a universal quantifier is closely related to the reading of [todavía que] as a Scalar Additive Concessive Conjunctive Phrase.

Fe-Nanoparticle Amalgamation Using Lagenaria siceraria Leaf Aqueous Extract with Focus on Dye Removal and Antibacterial Efficacy

  • Kirti;Suantak Kamsonlian;Vishnu Agarwal;Ankur Gaur;Jin-Won Park
    • Korean Chemical Engineering Research
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    • v.61 no.2
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    • pp.287-295
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    • 2023
  • Iron nanoparticles (Fe-NPs) were synthesized employing Lagenaria siceraria (LS) leaf aqueous extract as a reducing and capping medium to remove methylene blue (MB) dye and have antibacterial properties against G-negative (Escherichia coli) and G-positive bacteria (Staphylococcus aureus). The formation of LS-Fe-NPs (Lagenaria-siceraria-iron-nanoparticles) was confirmed by a change in color from pale yellow to dark brown. Characterization techniques, such as particle size analysis (PSA), transmission electron microscopy (TEM) and scanning electron microscopy (SEM), were employed to prove nano spherical particles of size range between 80-100 nm. Phytochemicals and the presence of iron in LS-Fe-NPs nanoparticles were proved by UV-visible spectrophotometry. Further, Fourier transform infrared spectroscopy (FTIR) analysis results confirmed the existence of bioactive molecules in the plants. The magnetic property was analyzed using a vibrating sample magnetometer (VSM), which displayed that the synthesized nanoparticles were superparamagnetic and exhibiting a saturation magnetization of 12.5 emu/g. Synthesized magnetic nanoparticles were used in methylene blue (MB) dye removal through adsorption. About 83% of 100 mg/L MB dye was removed within 120 min at pH 6 with a maximum adsorption capacity of 246.8 mg/g. Antibacterial efficacy of LS-Fe-NPs was screened against G-negative (Escherichia coli) and G-positive bacteria (Staphylococcus aureus), respectively, and found that LS-Fe-NPs were effective against Staphylococcus aureus.

Virus-like particles expressing microneme-associated antigen of Plasmodium berghei confer better protection than those expressing apical membrane antigen 1

  • Min-Ju Kim;Ki Back Chu;Keon-Woong Yoon;Hae-Ji Kang;Dong-Hun Lee;Eun-Kyung Moon;Fu-Shi Quan
    • Parasites, Hosts and Diseases
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    • v.62 no.2
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    • pp.193-204
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    • 2024
  • Malaria is a global disease affecting a large portion of the world's population. Although vaccines have recently become available, their efficacies are suboptimal. We generated virus-like particles (VLPs) that expressed either apical membrane antigen 1 (AMA1) or microneme-associated antigen (MIC) of Plasmodium berghei and compared their efficacy in BALB/c mice. We found that immune sera acquired from AMA1 VLP- or MIC VLP-immunized mice specifically interacted with the antigen of choice and the whole P. berghei lysate antigen, indicating that the antibodies were highly parasite-specific. Both VLP vaccines significantly enhanced germinal center B cell frequencies in the inguinal lymph nodes of mice compared with the control, but only the mice that received MIC VLPs showed significantly enhanced CD4+ T cell responses in the blood following P. berghei challenge infection. AMA1 and MIC VLPs significantly suppressed TNF-α and interleukin-10 production but had a negligible effect on interferon-γ. Both VLPs prevented excessive parasitemia buildup in immunized mice, although parasite burden reduction induced by MIC VLPs was slightly more effective than that induced by AMA1. Both VLPs were equally effective at preventing body weight loss. Our findings demonstrated that the MIC VLP was an effective inducer of protection against murine experimental malaria and should be the focus of further development.

Electrochemical Properties of HNO3 Pre-treated $TiO_2$ Photoelectrode for Dye-SEnsitized Solar Cells (염료감응형 태양전지용 질산 전처리된 $TiO_2$ 광전극의 전기화학적 특성)

  • Park, Kyung-Hee;Jin, En-Mei;Gu, Hal-Bon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.06a
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    • pp.441-441
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    • 2009
  • Dye-sensitized solar cells (DSSCs) have been widely investigated as a next-generation solar cell because of their simple fabrication process and low coats. The cells use a porous nanocrystalline TiO2 matrix coated with a sensitizer dye that acts as the light-harvesting element. The photo-exited dye injects electrons into the $TiO_2$ particles, and the oxide dye reacts with I- in the electrolyte in regenerative cycle that is completed by the reduction of $I_3^-$ at a platinum-coated counter electrode. Since $TiO_2$ porous film plays a key role in the enhancement of photoelectric conversion efficiency of DSSC, many scientists focus their researches on it. Especially, a high light-to-electricity conversion efficiency results from particle size and crystallographic phase, film porosity, surface structure, charge and surface area to volume ratio of porous $TiO_2$ electrodes, on which the dye can be sufficiently adsorbed. Effective treatment of the photoanode is important to improve DSSC performance. In this paper, to obtain properties of surface and dispersion as nitric acid treated $TiO_2$ photoelectrode was investigate. The photovoltaic characteristics of DSSCs based the electrode fabricated by nitric acid pre-treatment $TiO_2$ materials gave better performances on both of short circuit current density and open circuit voltage. We compare dispersion of $TiO_2$ nanoparticles before and after nitric acid treatment and measured Ti oxidized state from XPS. Low charge transfer resistance was obtained in nitric acid treated sample than that of untreated sample. The dye-sensitized solar cell based on the nitric acid treatment had open-circuit voltage of 0.71 V, a short-circuit current of 15.2 mAcm-2 and an energy conversion efficiency of 6.6 % under light intensity of $100\;mWcm^{-2}$. About 14 % increases in efficiency obtained when the $TiO_2$ electrode was treated by nitric acid.

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